Volcano Watch — We're giving thanks for clean air, but what's that new smell?

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Since the sharp drop in Kīlauea's volcanic activity and gas emissions in early August 2018, there has been dramatic improvement in the island's air quality. The rest of the state can also take comfort in the low levels of volcanic gases, because wintertime southerly winds will have much less volcanic pollution to blow along the island chain.

The main culprit in the formation of volcanic air pollution, or vog, at Kīlauea Volcano is sulfur dioxide (SO₂). Since SO₂ is released when magma is at a shallow depth (less than 1 kilometer or 0.6 miles beneath the surface), the current lack of activity means that Kīlauea is releasing only a small amount of this familiar gas.

Currently, less than 200 tons of SO₂ are emitted from the volcano each day. This is more than 20 times less than average emissions during the 10 years of lava lake activity at Halema‘uma‘u, and at least 200 times less than peak emissions during the 2018 lower East Rift Zone eruption.

With these much lower emissions, many people have expressed surprise that a strong and slightly unfamiliar smell can be detected from Kīlauea during certain wind conditions. A change in the chemistry of emitted sulfur gases is responsible for this new aroma.

A small amount of hydrogen sulfide gas (H₂S), the smelly cousin of SO₂, is being produced. With the current volcanic conditions, deeper magma has led to cooler vent temperatures. Without shallow magma to boil off ground water, the sub-surface environment is also much wetter.

These cooler and wetter conditions cause a small amount of H₂S to form, in addition to the SO₂. H₂S is most commonly detected during interruptions in trade wind conditions and in locations downwind of Kīlauea's summit, Pu‘u ‘Ō‘ō, and the 2018 lower East Rift Zone fissure system.

Sulfur dioxide gas, which produces a sharp pungent aroma like that emitted when setting off fireworks or striking a kitchen match, is noticeable to most people at 0.3 to 1 parts per million (ppm)—0.3 to 1 parts gas in 1 million parts of air. In some sensitive asthmatics, lung function changes have been observed with SO₂ concentrations as low as 0.1 ppm, well below the level detected by most human noses.

On the other hand, people can usually smell the rotten egg odor of H₂S at lower concentrations ranging from 0.0005 to 0.3 ppm. H₂S is present at Kīlauea in tiny amounts, but that little bit can be quite noticeable.

The smell of H₂S is a familiar odor to people from hot spring or geothermal areas. It is also produced by decaying organic material (anaerobic digestion) and is released by sewers and swamps. Even the human body produces a small amount of H₂S.

The State of Hawaii has set a "nuisance level" for H₂S at 0.025 ppm, based on the odor threshold. Negative symptoms of H₂S exposure do not occur until concentrations are well above the odor threshold.

According to the Occupational Safety and Health Administration (OSHA), prolonged exposure to 2‒5 ppm may cause headaches, eye irritation, nausea or breathing problems in some asthmatics (https://www.osha.gov/SLTC/hydrogensulfide/hazards.html). Measured concentrations in populated areas around Kīlauea are less than 1 ppm.

Although H₂S can be detected by humans at very low concentrations, a person's sense of smell to the gas is lost at high concentrations. For instance, two to five minutes of exposure at 100 ppm can cause a sensory adaptation known as "olfactory fatigue." But concentrations of H₂S measured at Kīlauea, even directly at volcanic vents, are well below this level.

For those of us who have spent decades living with the familiar aroma of "classic" vog, the introduction of smelly H₂S can be curious or even disconcerting. As Kīlauea Volcano's next chapter of activity unfolds, when magma eventually rises toward the surface, we can expect a decrease in H₂S emissions and a return to the more familiar smell of the SO₂ and particle-dominated vog.
 

Volcano Activity Update

Kīlauea is not erupting. Low rates of seismicity, deformation, and gas release have not changed significantly over the past week.

Earthquakes continue to occur primarily at Kīlauea's summit area and south flank, with continued small aftershocks of the May 4, 2018, magnitude-6.9 quake. Seismicity remains low in the lower East Rift Zone (ERZ).

Deformation signals are consistent with magma refilling the middle ERZ. At the summit, tiltmeters showed little change this week, except for a small DI (deflation-inflation) sequence.

Last week, sulfur dioxide gas emissions averaged 25 tonnes/day at the summit and 75 tonnes/day at Pu‘u ‘Ō‘ō. No sulfur dioxide was detected by our instruments in the lower ERZ.

Hazardous conditions still exist at both the lower ERZ and summit. Residents in the lower Puna District and Kīlauea summit areas on the Island of Hawai‘i should stay informed and heed Hawai‘i County Civil Defense closures, warnings, and messages (http://www.hawaiicounty.gov/active-alerts).

The USGS Volcano Alert level for Mauna Loa remains at NORMAL.

No Hawaii earthquakes received three or more felt reports (minimum to be recounted here) this past week.