Advancements in Geochemistry and Geomicrobiology of Energy Resources (AGGER) Active
By Geology, Energy & Minerals Science Center
May 23, 2022
The AGGER project’s purpose is to advance the understanding of geologic energy sources, generation, composition, movement, and production potential, including resource recovery from energy wastes.
This purpose manifests in three broad objectives:
- Assessing subsurface microorganisms in order to stimulate or retard biogenic gas production;
- Linking macroscale geologic energy phenomena (e.g., petroleum recoverability or carbon sequestration) to nanoscale parameters (e.g., pore accessibility); and
- Developing standardized approaches to evaluate both the resource potential and environmental risks of energy related wastes.
Achieving these objectives relates to the DOI Strategic Objective 3.2 Current Energy Needs Are Met Through Balanced Resource Use, and informs Congress, State and Federal agencies, private organizations, and the public on the U.S. energy endowment.
The AGGER project is currently divided into 7 research tasks, detailed below, and funds three research laboratories.
- Controls on microbial methanogenesis in shale deposits and strategies for enhancement - Task leads: Elliott Barnhart and Matthew Varonka
- Structure and composition of energy materials - Task lead: Aaron Jubb
- NORM products, byproducts and wastes from energy resource life cycles - Task lead: Bonnie McDevitt
- Spectroscopic investigations of energy materials - Task lead: Aaron Jubb
- Remote sensing techniques to quantify energy resources in wastes at abandoned mines - Task lead: Bernard Hubbard
- Scoping innovative approaches in advanced field measurements and data analysis - Task lead: Elisha ‘Eli’ Moore
- Assessing critical minerals and contaminants in coal mine drainage - Task lead: Bonnie McDevitt
The following 3 laboratories are associated with the AGGER project:
- Eastern Energy and Environmental Laboratory (EEEL)
- Raman Spectroscopy Laboratory (RSL)
- Naturally Occurring Radioactive Material Laboratory (NORM)
The data releases listed below are associated with the AGGER project.
Filter Total Items: 16
Injection of Deuterium and Yeast Extract at USGS Birney Field Site, Powder River Basin, Montana, USA, 2016-2020
Subsurface microbial (biogenic) methane production is an important part of the global carbon cycle and has resulted in natural gas accumulations in many coal beds worldwide. Laboratory experiments indicate coal beds can act as natural geobioreactors and produce additional low carbon renewable natural gas with algal or yeast compounds, yet the effectiveness of these nutrients in situ are unknown. T
Input Files and Code for: Machine learning can accurately assign geologic basin to produced water samples using major geochemical parameters
As more hydrocarbon production from hydraulic fracturing and other methods produce large volumes of water, innovative methods must be explored for treatment and reuse of these waters. However, understanding the general water chemistry of these fluids is essential to providing the best treatment options optimized for each producing area. Machine learning algorithms can often be applied to datasets
Combined Occurrence Frequency of Wind Speeds and Precipitation Amounts Conducive to Dust Dispersion from Disturbed Mine and Mill Sites in the United States, 2007?16
Dispersion of dust depends on many complex factors related to the nature of the disturbed materials, climate, dust control measures, and localized weather patterns. This dataset presents wind speed and rainfall as climate factors that influence dust dispersion. These two basic factors were identified as a subset of the many factors that can lead to dust dispersion. Arpacioglu and Er (2003) reviewe
Nanoscale Molecular Composition of Solid Bitumen from the Eagle Ford Group Across a Natural Thermal Maturity Gradient
Solid bitumen is a petrographically-defined secondary organic matter residue produced during petroleum generation and subsequent oil transformation. The presence of solid bitumen impacts many shale reservoir properties including porosity, permeability, and hydrocarbon generation and storage, amongst others. Furthermore, solid bitumen reflectance is an important parameter for assessing the thermal
The publications listed below are associated with the AGGER project.
Filter Total Items: 44
Mapping ancient sedimentary organic matter molecular structure at nanoscales using optical photothermal infrared spectroscopy
Elucidating the molecular structure of sedimentary organic matter (SOM) is key to understanding petroleum generation processes, as well as ancient sedimentary environments. SOM structure is primarily controlled by biogenic source material (e.g., marine vs. terrigenous), depositional conditions, and subsurface thermal history. Additional factors, e.g., strain, may also impact the molecular structur
Authors
Aaron M. Jubb, Martha (Rebecca) Stokes, Ryan J. McAleer, Paul C. Hackley, Eoghan Dillion, Jing Qu
A global perspective on bacterial diversity in the terrestrial deep subsurface
While recent efforts to catalogue Earth’s microbial diversity have focused upon surface and marine habitats, 12–20 % of Earth’s biomass is suggested to exist in the terrestrial deep subsurface, compared to ~1.8 % in the deep subseafloor. Metagenomic studies of the terrestrial deep subsurface have yielded a trove of divergent and functionally important microbiomes from a range of localities. Howeve
Authors
A. Soares, A. L. Edwards, A. Bagnoud, J. Bradley, Elliott Barnhart, M. Bomberger Brown, K. Budwill, S. M. Caffrey, M. Fields, J. Gralnick., V. Kadnikov, L. Momper, M. Osburn, A. Mu, J.W. Moreau, D. Moser, L. Purkamo, S. M. Rassner, C. S. Sheik, B. Sherwood Lollar, B. M. Toner, G. Voordouw, K. Wouters, A. C. Mitchell
Assessment of resource potential from mine tailings using geostatistical modeling for compositions: A methodology and application to Katherine Mine site, Arizona, USA
The mining industry, in most cases, targets a specific valuable commodity that is present in small quantities within large volumes of extracted material. After milling and processing, most of the extracted material and the effluents are stored as waste (tailings) in impoundments, such as dams or waste dumps, or are backfilled into underground mines. In time, tailing materials may become an issue o
Authors
C. Özgen Karacan, Oktay Erten, Josep Antoni Martín-Fernández
Relating systematic compositional variability to the textural occurrence of solid bitumen in shales
This study presents Raman spectroscopic data paired with scanning electron microscopy (SEM) images to assess solid bitumen composition as a function of solid bitumen texture and association with minerals. A series of hydrous pyrolysis experiments (1–103 days, 300–370 °C) using a low maturity (0.25% solid bitumen reflectance, BRo), high total organic carbon [(TOC), 14.0 wt%] New Albany Shale sample
Authors
Martha (Rebecca) Stokes, Brett J. Valentine, Aaron M. Jubb, Paul C. Hackley
Geoenvironmental model for roll-type uranium deposits in the Texas Gulf Coast
Geoenvironmental models were formulated by the U.S. Geological Survey in the 1990s to describe potential environmental effects of extracting different types of ore deposits in different geologic and climatic regions. This paper presents a geoenvironmental model for roll-front (roll-type) uranium deposits in the Texas Coastal Plain. The model reviews descriptive and quantitative information derived
Authors
Katherine Walton-Day, Johanna Blake, Robert R. Seal, Tanya J. Gallegos, Jean Dupree, Kent D Becher
Maturation study of vitrinite in carbonaceous shales and coals: Insights from hydrous pyrolysis
The presence of vitrinite in sedimentary rocks of post-Silurian age allows its reflectance to be used to estimate the thermal maturation of organic matter in petroleum systems. Increasing reflectance of vitrinite, which is primarily driven by aromaticity, depends primarily on the time and temperature attributes of its evolutionary pathway. This study evaluated carbonaceous shales proximal to coal
Authors
Divya K. Mishra, Paul C. Hackley, Aaron M. Jubb, Margaret M. Sanders, Shailesh Agrawal, Atul K. Varma
A novel method for conducting a geoenvironmental assessment of undiscovered ISR-amenable uranium Resources: Proof-of-concept in the Texas Coastal Plain
A geoenvironmental assessment methodology was developed to estimate waste quantities and disturbances that could be associated with the extraction of undiscovered uranium resources and identify areas on the landscape where uranium and other constituents of potential concern (COPCs) that may co-occur with uranium deposits in this region are likely to persist, if introduced into the environment. Pri
Authors
Tanya J. Gallegos, Victoria G. Stengel, Katherine Walton-Day, Johanna Blake, Andrew Teeple, Delbert G Humberson, Steven M. Cahan, Douglas Yager, Kent D Becher
Dissolved organic matter within oil and gas associated wastewaters from U.S. unconventional petroleum plays: Comparisons and consequences for disposal and reuse
Wastewater generated during petroleum extraction (produced water) may contain high concentrations of dissolved organics due to their intimate association with organic-rich source rocks, expelled petroleum, and organic additives to fluids used for hydraulic fracturing of unconventional (e.g., shale) reservoirs. Dissolved organic matter (DOM) within produced water represents a challenge for treatmen
Authors
Bonnie McDevitt, Aaron M. Jubb, Matthew S. Varonka, Madalyn S. Blondes, Mark A Engle, Tanya J. Gallegos, Jenna L. Shelton
Evaluating aromatization of solid bitumen generated in the presence and absence of water: Implications for solid bitumen reflectance as a thermal proxy
Geological models for petroleum generation suggest thermal conversion of oil-prone sedimentary organic matter in the presence of water promotes increased liquid saturate yield, whereas absence of water causes formation of an aromatic, cross-linked solid bitumen residue. To test the influence of hydrogen from water, organic-rich (22 wt% total organic carbon, TOC) mudrock samples from the Eocene lac
Authors
Paul C. Hackley, Aaron M. Jubb, Patrick L. Smith, Ryan J. McAleer, Brett J. Valentine, Javin J. Hatcherian, Palma J. Botterell, Justin E. Birdwell
Methanogenic archaea in subsurface coal seams are biogeographically distinct: An analysis of metagenomically-derived mcrA sequences
The production of methane as an end-product of organic matter degradation in the absence of other terminal electron acceptors is common, and has often been studied in environments such as animal guts, soils, and wetlands due to its potency as a greenhouse gas. To date however, the study of the biogeographic distribution of methanogens across coal seam environments has been minimal. Here, we show t
Authors
Bronwyn C Campbell, Paul Greenfield, Se Gong, Elliott Barnhart, David J. Midgley, Ian T. Paulsen, Simon C. George
A methodology to assess the historical environmental footprint of in-situ recovery (ISR) of uranium: A demonstration in the Goliad Sand in the Texas Coastal Plain, USA
In-situ recovery (ISR) has been the only technique used to extract uranium from sandstone-hosted uranium deposits in the Pliocene Goliad Sand in the Texas Coastal Plain. Water plays a crucial role throughout the ISR lifecycle of production and groundwater restoration yet neither the water use nor other environmental footprints have been well documented. The goal of this study is to examine histori
Authors
Tanya J. Gallegos, Annie Scott, Victoria G. Stengel, Andrew Teeple
Subsurface hydrocarbon degradation strategies in low- and high-sulfate coal seam communities identified with activity-based metagenomics
Environmentally relevant metagenomes and BONCAT-FACS derived translationally active metagenomes from Powder River Basin coal seams were investigated to elucidate potential genes and functional groups involved in hydrocarbon degradation to methane in coal seams with high- and low-sulfate levels. An advanced subsurface environmental sampler allowed the establishment of coal-associated microbial comm
Authors
Hannah S. Schweitzer, Heidi J. Smith, Elliott Barnhart, Luke J. McKay, Robin Gerlach, Alfred B. Cunningham, Rex R. Malmstrom, Danielle Goudeau, Matthew W. Fields
The AGGER project’s purpose is to advance the understanding of geologic energy sources, generation, composition, movement, and production potential, including resource recovery from energy wastes.
This purpose manifests in three broad objectives:
- Assessing subsurface microorganisms in order to stimulate or retard biogenic gas production;
- Linking macroscale geologic energy phenomena (e.g., petroleum recoverability or carbon sequestration) to nanoscale parameters (e.g., pore accessibility); and
- Developing standardized approaches to evaluate both the resource potential and environmental risks of energy related wastes.
Achieving these objectives relates to the DOI Strategic Objective 3.2 Current Energy Needs Are Met Through Balanced Resource Use, and informs Congress, State and Federal agencies, private organizations, and the public on the U.S. energy endowment.
The AGGER project is currently divided into 7 research tasks, detailed below, and funds three research laboratories.
- Controls on microbial methanogenesis in shale deposits and strategies for enhancement - Task leads: Elliott Barnhart and Matthew Varonka
- Structure and composition of energy materials - Task lead: Aaron Jubb
- NORM products, byproducts and wastes from energy resource life cycles - Task lead: Bonnie McDevitt
- Spectroscopic investigations of energy materials - Task lead: Aaron Jubb
- Remote sensing techniques to quantify energy resources in wastes at abandoned mines - Task lead: Bernard Hubbard
- Scoping innovative approaches in advanced field measurements and data analysis - Task lead: Elisha ‘Eli’ Moore
- Assessing critical minerals and contaminants in coal mine drainage - Task lead: Bonnie McDevitt
The following 3 laboratories are associated with the AGGER project:
- Eastern Energy and Environmental Laboratory (EEEL)
- Raman Spectroscopy Laboratory (RSL)
- Naturally Occurring Radioactive Material Laboratory (NORM)
The data releases listed below are associated with the AGGER project.
Filter Total Items: 16
Injection of Deuterium and Yeast Extract at USGS Birney Field Site, Powder River Basin, Montana, USA, 2016-2020
Subsurface microbial (biogenic) methane production is an important part of the global carbon cycle and has resulted in natural gas accumulations in many coal beds worldwide. Laboratory experiments indicate coal beds can act as natural geobioreactors and produce additional low carbon renewable natural gas with algal or yeast compounds, yet the effectiveness of these nutrients in situ are unknown. T
Input Files and Code for: Machine learning can accurately assign geologic basin to produced water samples using major geochemical parameters
As more hydrocarbon production from hydraulic fracturing and other methods produce large volumes of water, innovative methods must be explored for treatment and reuse of these waters. However, understanding the general water chemistry of these fluids is essential to providing the best treatment options optimized for each producing area. Machine learning algorithms can often be applied to datasets
Combined Occurrence Frequency of Wind Speeds and Precipitation Amounts Conducive to Dust Dispersion from Disturbed Mine and Mill Sites in the United States, 2007?16
Dispersion of dust depends on many complex factors related to the nature of the disturbed materials, climate, dust control measures, and localized weather patterns. This dataset presents wind speed and rainfall as climate factors that influence dust dispersion. These two basic factors were identified as a subset of the many factors that can lead to dust dispersion. Arpacioglu and Er (2003) reviewe
Nanoscale Molecular Composition of Solid Bitumen from the Eagle Ford Group Across a Natural Thermal Maturity Gradient
Solid bitumen is a petrographically-defined secondary organic matter residue produced during petroleum generation and subsequent oil transformation. The presence of solid bitumen impacts many shale reservoir properties including porosity, permeability, and hydrocarbon generation and storage, amongst others. Furthermore, solid bitumen reflectance is an important parameter for assessing the thermal
The publications listed below are associated with the AGGER project.
Filter Total Items: 44
Mapping ancient sedimentary organic matter molecular structure at nanoscales using optical photothermal infrared spectroscopy
Elucidating the molecular structure of sedimentary organic matter (SOM) is key to understanding petroleum generation processes, as well as ancient sedimentary environments. SOM structure is primarily controlled by biogenic source material (e.g., marine vs. terrigenous), depositional conditions, and subsurface thermal history. Additional factors, e.g., strain, may also impact the molecular structur
Authors
Aaron M. Jubb, Martha (Rebecca) Stokes, Ryan J. McAleer, Paul C. Hackley, Eoghan Dillion, Jing Qu
A global perspective on bacterial diversity in the terrestrial deep subsurface
While recent efforts to catalogue Earth’s microbial diversity have focused upon surface and marine habitats, 12–20 % of Earth’s biomass is suggested to exist in the terrestrial deep subsurface, compared to ~1.8 % in the deep subseafloor. Metagenomic studies of the terrestrial deep subsurface have yielded a trove of divergent and functionally important microbiomes from a range of localities. Howeve
Authors
A. Soares, A. L. Edwards, A. Bagnoud, J. Bradley, Elliott Barnhart, M. Bomberger Brown, K. Budwill, S. M. Caffrey, M. Fields, J. Gralnick., V. Kadnikov, L. Momper, M. Osburn, A. Mu, J.W. Moreau, D. Moser, L. Purkamo, S. M. Rassner, C. S. Sheik, B. Sherwood Lollar, B. M. Toner, G. Voordouw, K. Wouters, A. C. Mitchell
Assessment of resource potential from mine tailings using geostatistical modeling for compositions: A methodology and application to Katherine Mine site, Arizona, USA
The mining industry, in most cases, targets a specific valuable commodity that is present in small quantities within large volumes of extracted material. After milling and processing, most of the extracted material and the effluents are stored as waste (tailings) in impoundments, such as dams or waste dumps, or are backfilled into underground mines. In time, tailing materials may become an issue o
Authors
C. Özgen Karacan, Oktay Erten, Josep Antoni Martín-Fernández
Relating systematic compositional variability to the textural occurrence of solid bitumen in shales
This study presents Raman spectroscopic data paired with scanning electron microscopy (SEM) images to assess solid bitumen composition as a function of solid bitumen texture and association with minerals. A series of hydrous pyrolysis experiments (1–103 days, 300–370 °C) using a low maturity (0.25% solid bitumen reflectance, BRo), high total organic carbon [(TOC), 14.0 wt%] New Albany Shale sample
Authors
Martha (Rebecca) Stokes, Brett J. Valentine, Aaron M. Jubb, Paul C. Hackley
Geoenvironmental model for roll-type uranium deposits in the Texas Gulf Coast
Geoenvironmental models were formulated by the U.S. Geological Survey in the 1990s to describe potential environmental effects of extracting different types of ore deposits in different geologic and climatic regions. This paper presents a geoenvironmental model for roll-front (roll-type) uranium deposits in the Texas Coastal Plain. The model reviews descriptive and quantitative information derived
Authors
Katherine Walton-Day, Johanna Blake, Robert R. Seal, Tanya J. Gallegos, Jean Dupree, Kent D Becher
Maturation study of vitrinite in carbonaceous shales and coals: Insights from hydrous pyrolysis
The presence of vitrinite in sedimentary rocks of post-Silurian age allows its reflectance to be used to estimate the thermal maturation of organic matter in petroleum systems. Increasing reflectance of vitrinite, which is primarily driven by aromaticity, depends primarily on the time and temperature attributes of its evolutionary pathway. This study evaluated carbonaceous shales proximal to coal
Authors
Divya K. Mishra, Paul C. Hackley, Aaron M. Jubb, Margaret M. Sanders, Shailesh Agrawal, Atul K. Varma
A novel method for conducting a geoenvironmental assessment of undiscovered ISR-amenable uranium Resources: Proof-of-concept in the Texas Coastal Plain
A geoenvironmental assessment methodology was developed to estimate waste quantities and disturbances that could be associated with the extraction of undiscovered uranium resources and identify areas on the landscape where uranium and other constituents of potential concern (COPCs) that may co-occur with uranium deposits in this region are likely to persist, if introduced into the environment. Pri
Authors
Tanya J. Gallegos, Victoria G. Stengel, Katherine Walton-Day, Johanna Blake, Andrew Teeple, Delbert G Humberson, Steven M. Cahan, Douglas Yager, Kent D Becher
Dissolved organic matter within oil and gas associated wastewaters from U.S. unconventional petroleum plays: Comparisons and consequences for disposal and reuse
Wastewater generated during petroleum extraction (produced water) may contain high concentrations of dissolved organics due to their intimate association with organic-rich source rocks, expelled petroleum, and organic additives to fluids used for hydraulic fracturing of unconventional (e.g., shale) reservoirs. Dissolved organic matter (DOM) within produced water represents a challenge for treatmen
Authors
Bonnie McDevitt, Aaron M. Jubb, Matthew S. Varonka, Madalyn S. Blondes, Mark A Engle, Tanya J. Gallegos, Jenna L. Shelton
Evaluating aromatization of solid bitumen generated in the presence and absence of water: Implications for solid bitumen reflectance as a thermal proxy
Geological models for petroleum generation suggest thermal conversion of oil-prone sedimentary organic matter in the presence of water promotes increased liquid saturate yield, whereas absence of water causes formation of an aromatic, cross-linked solid bitumen residue. To test the influence of hydrogen from water, organic-rich (22 wt% total organic carbon, TOC) mudrock samples from the Eocene lac
Authors
Paul C. Hackley, Aaron M. Jubb, Patrick L. Smith, Ryan J. McAleer, Brett J. Valentine, Javin J. Hatcherian, Palma J. Botterell, Justin E. Birdwell
Methanogenic archaea in subsurface coal seams are biogeographically distinct: An analysis of metagenomically-derived mcrA sequences
The production of methane as an end-product of organic matter degradation in the absence of other terminal electron acceptors is common, and has often been studied in environments such as animal guts, soils, and wetlands due to its potency as a greenhouse gas. To date however, the study of the biogeographic distribution of methanogens across coal seam environments has been minimal. Here, we show t
Authors
Bronwyn C Campbell, Paul Greenfield, Se Gong, Elliott Barnhart, David J. Midgley, Ian T. Paulsen, Simon C. George
A methodology to assess the historical environmental footprint of in-situ recovery (ISR) of uranium: A demonstration in the Goliad Sand in the Texas Coastal Plain, USA
In-situ recovery (ISR) has been the only technique used to extract uranium from sandstone-hosted uranium deposits in the Pliocene Goliad Sand in the Texas Coastal Plain. Water plays a crucial role throughout the ISR lifecycle of production and groundwater restoration yet neither the water use nor other environmental footprints have been well documented. The goal of this study is to examine histori
Authors
Tanya J. Gallegos, Annie Scott, Victoria G. Stengel, Andrew Teeple
Subsurface hydrocarbon degradation strategies in low- and high-sulfate coal seam communities identified with activity-based metagenomics
Environmentally relevant metagenomes and BONCAT-FACS derived translationally active metagenomes from Powder River Basin coal seams were investigated to elucidate potential genes and functional groups involved in hydrocarbon degradation to methane in coal seams with high- and low-sulfate levels. An advanced subsurface environmental sampler allowed the establishment of coal-associated microbial comm
Authors
Hannah S. Schweitzer, Heidi J. Smith, Elliott Barnhart, Luke J. McKay, Robin Gerlach, Alfred B. Cunningham, Rex R. Malmstrom, Danielle Goudeau, Matthew W. Fields