Analytical Capabilities, Sample Requirements, and Instrumentation Active
Organic Geochemistry Research Lab
(OGRL)
OGRL works independently or collaboratively to pair fate and transport with biological
experiments and effects. OGRL has three main focuses:
1. Development and modification of robust analytical methods needed for analysis of
compounds in multiple matrices to address relevant environmental health issues.
2. Conduct independent and collaborative lab to national based studies to provide new
knowledge on source to receptor pathways for potential environmental relevant organic
contaminants.
3. Conduct collaborative research to study correlations between individual compound
and environmental mixture and environmental health effects.
Hot Topics
- A team of scientists from the USGS and the Agroscope Reckenholz-Tanikon Research Station, Switzerland, found that some mycotoxins are common in U.S. stream waters. (more)
- Measuring POEA, a Surfactant Mixture in Herbicide Formulations. (more)
- Groundwater microbial community composition affected during 30-day exposure to sub mg/L concentrations of the antibiotic, sulfamethoxazole.
- Two microbial communities from a sandy aquifer, one acclimated historically to wastewater with sulfamethoxazole and the other unacclimated were exposed to in situ 240-520 μg/L sulfamethoxazole using filter chambers suspended ambient groundwater for 30 days. The unacclimated microbial community displayed greater changes in mortality and impairment, sensitivity to sulfamethoxazole, and community composition than the unacclimated microbial community. The study shows that microbial communities can be affected by concentrations 2-3 orders of magnitude less than those used in clinical applications.
Sample Processing
Samples will be collected using protocols for the collection of pesticide analysis in Shelton, (1994) http://water.usgs.gov/nawqa/pnsp/pubs/ofr94-455/sw-t.html
- Preclean all equipment with a Liquinox/tap-water solution, rinsed with tap water, deonized water, and then methanol, and then air dry.
- Filter sample water through a 0.7-µm pore-size baked glass-fiber filter after a 100 ml rinse of the filter with sample water, into 125-ml (4 oz) baked amber glass bottles (If filtering is not possible, then it can be done upon request at a rate of $30 persample).
- Upon collection, all samples will be kept chilled until shipped to the lab.
Shipping Instructions
Label bottles clearly with waterproof marker or preprinted labels (a paper label completely covered with clear packing tape is preferred). Information required on the bottle is shown:
- -Project code:
- -station id
- -stream/well name/location
- -date and time
- -initials of collector
- -lab method code
Example:
Project code: To be assigned by Julie Dietze
station id: Lake Houston North End, Texas
stream/well name/location: 40305060
date and time: 5-18-06 @ 1015
initials of collector: JD
lab method code: LCGY
Bottle Requirements
Method Required Bottles
LCPD 3-4oz (125mL) amber glass with teflon lined caps
LCAB 3-4oz (125mL) amber glass with teflon lined caps
LCEA 3-4oz (125mL) amber glass with teflon lined caps
LCGY 3-4oz (125mL) amber glass with teflon lined caps
IMA 3-4oz (125mL) amber glass with teflon lined caps
IMB 3-4oz (125mL) amber glass with teflon lined caps
IMNT/IMND *1- 8 oz (250mL) HDPE with polypropylene closure
IMYT/IMYD *1- 8 oz (250mL) HDPE with polypropylene closure
IMXT/IMXD *1- 8 oz (250mL) HDPE with polypropylene closure
Custom Methods Contact Julie Dietze for bottles requirements
*When submitting samples for total analysis (IMNT, IMYT, and IMXT) only fill the bottles half-way to ensure that they do not break when frozen.
The following information form an ASR is required for transfer from the lab database to NWIS batch files/QWDX.
- USGS station ID
- Phone Number
- E-mail Contact
- User Code
- Project Account Number
- Collection Date
- Collection Time
- Sample Medium Code
- Sample Type
A copy of an ASR may be made and enclosed in a watertight bag if sample is also being sent to NWQL. Please make sure the lab methods and any other information specific to our lab is on the ASR sent to Kansas.
Data can be uploaded to the QWDX site upon request with the exception of immunoassay and soils/solids/bed sediment methods.
Glass bottles to be placed in foam sleeves to help prevent breakage. The bottles from each site will then be placed in a ZIPLOCK-type bag, which will help keep them dry in the coolers and keep all bottles from the same site together. All samples will be kept chilled and shipped on ice. Permanently mark the inside lid of the cooler with return address and telephone number. If this is not possible, make certain samples are kept cool until they are shipped to the OGRL.
Coolers will be returned at your project's expense. The three options for cooler return are listed below.
- A. Enclose a return mailing label and correct postage metered for return of cooler by parcel post mail
- B. Return a completed Federal Express shipping label identifying your USGS internal cost code or Federal Express account number.
- C. Enclose a mailing label and internal USGS cost code to have the cooler returned by Federal Express Ground shipping.
The coolers must be sent Monday-Thursday by overnight delivery. The laboratory is not open on Saturday or Sunday. The laboratory is also closed on federal holidays; therefore, coolers should not be sent the day before a holiday.
If you have questions or need to set up a new project, please call Julie Dietze at the following number and use the following address when shipping samples:
OGRL
USGS KS WSC
4821 Quail Crest Place
Lawrence, KS 66049
785/832-3564
Organic Geochemistry Research Group
Links
Below are other science projects associated with this project.
OGRL Algal Toxins Methods of Analysis
Below are multimedia items associated with this project.
Below are publications associated with this project.
Degradates provide insight to spatial and temporal trends of herbicides in ground water
Urban contribution of pharmaceuticals and other organic wastewater contaminants to streams during differing flow conditions
Acetamide herbicides and their degradation products in ground water and surface water of the United States, 1993-2003
Persistence of pharmaceutical compounds and other organic wastewater contaminants in a conventional drinking-water-treatment plant
Is septic waste affecting drinking water from shallow domestic wells along the Platte River in eastern Nebraska?
Water-quality assessment of the eastern Iowa Basins: Selected pesticides and pesticide degradates in streams, 1996-98
Reconnaissance data for glyphosate, other selected herbicides, their degradation products, and antibiotics in 51 streams in nine midwestern states, 2002
Work plan for determining the occurrence of glyphosate, its transformation product AMPA, other herbicide compounds, and antibiotics in midwestern United States streams, 2002
Methods of analysis by the U.S. Geological Survey Organic Geochemistry Research Group: Determination of acetamide herbicides and their degradation products in water using online solid-phase extraction and liquid chromatography/mass spectrometry
Determination of antibiotic residues in manure, soil, and surface waters
Herbicides and transformation products in surface waters of the Midwestern United States
Herbicides and herbicide degradation products in upper midwest agricultural streams during august base-flow conditions
- Overview
OGRL works independently or collaboratively to pair fate and transport with biological
experiments and effects. OGRL has three main focuses:
1. Development and modification of robust analytical methods needed for analysis of
compounds in multiple matrices to address relevant environmental health issues.
2. Conduct independent and collaborative lab to national based studies to provide new
knowledge on source to receptor pathways for potential environmental relevant organic
contaminants.
3. Conduct collaborative research to study correlations between individual compound
and environmental mixture and environmental health effects.Hot Topics
- A team of scientists from the USGS and the Agroscope Reckenholz-Tanikon Research Station, Switzerland, found that some mycotoxins are common in U.S. stream waters. (more)
- Measuring POEA, a Surfactant Mixture in Herbicide Formulations. (more)
- Groundwater microbial community composition affected during 30-day exposure to sub mg/L concentrations of the antibiotic, sulfamethoxazole.
- Two microbial communities from a sandy aquifer, one acclimated historically to wastewater with sulfamethoxazole and the other unacclimated were exposed to in situ 240-520 μg/L sulfamethoxazole using filter chambers suspended ambient groundwater for 30 days. The unacclimated microbial community displayed greater changes in mortality and impairment, sensitivity to sulfamethoxazole, and community composition than the unacclimated microbial community. The study shows that microbial communities can be affected by concentrations 2-3 orders of magnitude less than those used in clinical applications.
Sample Processing
Samples will be collected using protocols for the collection of pesticide analysis in Shelton, (1994) http://water.usgs.gov/nawqa/pnsp/pubs/ofr94-455/sw-t.html
- Preclean all equipment with a Liquinox/tap-water solution, rinsed with tap water, deonized water, and then methanol, and then air dry.
- Filter sample water through a 0.7-µm pore-size baked glass-fiber filter after a 100 ml rinse of the filter with sample water, into 125-ml (4 oz) baked amber glass bottles (If filtering is not possible, then it can be done upon request at a rate of $30 persample).
- Upon collection, all samples will be kept chilled until shipped to the lab.
Shipping Instructions
Label bottles clearly with waterproof marker or preprinted labels (a paper label completely covered with clear packing tape is preferred). Information required on the bottle is shown:
- -Project code:
- -station id
- -stream/well name/location
- -date and time
- -initials of collector
- -lab method code
Example:
Project code: To be assigned by Julie Dietze
station id: Lake Houston North End, Texas
stream/well name/location: 40305060
date and time: 5-18-06 @ 1015
initials of collector: JD
lab method code: LCGY
Bottle Requirements
Method Required Bottles
LCPD 3-4oz (125mL) amber glass with teflon lined caps
LCAB 3-4oz (125mL) amber glass with teflon lined caps
LCEA 3-4oz (125mL) amber glass with teflon lined caps
LCGY 3-4oz (125mL) amber glass with teflon lined caps
IMA 3-4oz (125mL) amber glass with teflon lined caps
IMB 3-4oz (125mL) amber glass with teflon lined caps
IMNT/IMND *1- 8 oz (250mL) HDPE with polypropylene closure
IMYT/IMYD *1- 8 oz (250mL) HDPE with polypropylene closure
IMXT/IMXD *1- 8 oz (250mL) HDPE with polypropylene closure
Custom Methods Contact Julie Dietze for bottles requirements
*When submitting samples for total analysis (IMNT, IMYT, and IMXT) only fill the bottles half-way to ensure that they do not break when frozen.
The following information form an ASR is required for transfer from the lab database to NWIS batch files/QWDX.
- USGS station ID
- Phone Number
- E-mail Contact
- User Code
- Project Account Number
- Collection Date
- Collection Time
- Sample Medium Code
- Sample Type
A copy of an ASR may be made and enclosed in a watertight bag if sample is also being sent to NWQL. Please make sure the lab methods and any other information specific to our lab is on the ASR sent to Kansas.
Data can be uploaded to the QWDX site upon request with the exception of immunoassay and soils/solids/bed sediment methods.
Glass bottles to be placed in foam sleeves to help prevent breakage. The bottles from each site will then be placed in a ZIPLOCK-type bag, which will help keep them dry in the coolers and keep all bottles from the same site together. All samples will be kept chilled and shipped on ice. Permanently mark the inside lid of the cooler with return address and telephone number. If this is not possible, make certain samples are kept cool until they are shipped to the OGRL.
Coolers will be returned at your project's expense. The three options for cooler return are listed below.
- A. Enclose a return mailing label and correct postage metered for return of cooler by parcel post mail
- B. Return a completed Federal Express shipping label identifying your USGS internal cost code or Federal Express account number.
- C. Enclose a mailing label and internal USGS cost code to have the cooler returned by Federal Express Ground shipping.
The coolers must be sent Monday-Thursday by overnight delivery. The laboratory is not open on Saturday or Sunday. The laboratory is also closed on federal holidays; therefore, coolers should not be sent the day before a holiday.
If you have questions or need to set up a new project, please call Julie Dietze at the following number and use the following address when shipping samples:
OGRLUSGS KS WSC
4821 Quail Crest Place
Lawrence, KS 66049
785/832-3564
Organic Geochemistry Research Group
Links - Science
Below are other science projects associated with this project.
OGRL Algal Toxins Methods of Analysis
Algal toxins are a group of toxic compounds produced by a range of photosynthetic freshwater and marine plankton. These toxins have the ability to cause sickness in animals and humans and in severe cases lead to death. OGRL has the ability to evaluate and conduct occurrence, fate, transport, effects, and treatability studies methods. - Multimedia
Below are multimedia items associated with this project.
- Publications
Below are publications associated with this project.
Filter Total Items: 107Degradates provide insight to spatial and temporal trends of herbicides in ground water
Since 1995, a network of municipal wells in Iowa, representing all major aquifer types (alluvial, bedrock/karst region, glacial drift, bedrock/nonkarst region), has been repeatedly sampled for a broad suite of herbicide compounds yielding one of the most comprehensive statewide databases of such compounds currently available in the United States. This dataset is ideal for documenting the insight tAuthorsD.W. Kolpin, D.J. Schnoebelen, E. M. ThurmanUrban contribution of pharmaceuticals and other organic wastewater contaminants to streams during differing flow conditions
During 2001, 76 water samples were collected upstream and downstream of select towns and cities in Iowa during high-, normal- and low-flow conditions to determine the contribution of urban centers to concentrations of pharmaceuticals and other organic wastewater contaminants (OWCs) in streams under varying flow conditions. The towns ranged in population from approximately 2000 to 200 000. Overall,AuthorsD.W. Kolpin, M. Skopec, M. T. Meyer, E. T. Furlong, S.D. ZauggAcetamide herbicides and their degradation products in ground water and surface water of the United States, 1993-2003
During 1993 through 2003, the U.S. Geological Survey conducted a number of studies to investigate and document the occurrence, fate, and transport of acetamide herbicides and their degradation products in ground and surface water. As part of these studies, approximately 5,100 water samples were collected and analyzed for the acetamide parent herbicides acetochlor, alachlor, dimethenamid, flufenaceAuthorsElisabeth A. Scribner, Julie E. Dietze, Michael ThurmanPersistence of pharmaceutical compounds and other organic wastewater contaminants in a conventional drinking-water-treatment plant
In a study conducted by the US Geological Survey and the Centers for Disease Control and Prevention, 24 water samples were collected at selected locations within a drinking-water-treatment (DWT) facility and from the two streams that serve the facility to evaluate the potential for wastewater-related organic contaminants to survive a conventional treatment process and persist in potable-water suppAuthorsP. E. Stackelberg, E. T. Furlong, M. T. Meyer, S.D. Zaugg, A.K. Henderson, D.B. ReissmanIs septic waste affecting drinking water from shallow domestic wells along the Platte River in eastern Nebraska?
No abstract available.AuthorsIngrid M. Verstraeten, Greg S. Fetterman, Sonja K. Sebree, Michael T. Meyer, Thomas D. BullenWater-quality assessment of the eastern Iowa Basins: Selected pesticides and pesticide degradates in streams, 1996-98
Water samples were collected in streams of the Eastern Iowa Basins study unit from 1996 to 1998 as part of the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Program. More than 350 samples were collected to document the occurrence, distribution, and transport of pesticides and pesticide degradates. The Eastern Iowa Basins study unit encompasses about 50,500 square kilometers (1AuthorsDouglas J. Schnoebelen, Stephen J. Kalkhoff, Kent Becher, E. M. ThurmanReconnaissance data for glyphosate, other selected herbicides, their degradation products, and antibiotics in 51 streams in nine midwestern states, 2002
Since 1989, the U.S. Geological Survey has conducted periodic reconnaissance studies of streams in the Midwestern United States to determine the geographic and seasonal distribution of herbicide compounds. These studies have documented that large amounts of acetochlor, alachlor, atrazine, cyanazine, metolachlor, and their degradation products are flushed into streams during post-application runoffAuthorsElisabeth A. Scribner, William A. Battaglin, Julie E. Dietze, E. M. ThurmanWork plan for determining the occurrence of glyphosate, its transformation product AMPA, other herbicide compounds, and antibiotics in midwestern United States streams, 2002
Changes in herbicide use in the Midwestern United States have been substantial over the last 5 years. Most significant is a tripling in the use of glyphosate (N-[phosphonomethyl]glycin). Over this same time period (19972001), atrazine use increased by 20 percent and acetochlor use increased by 10 percent, while cyanazine use decreased by 99 percent, alachlor use decreased by 70 percent, and metolAuthorsW.A. Battaglin, E. M. Thurman, D.W. Kolpin, E.A. Scribner, Mark W. Sandstrom, K.M. KuivilaMethods of analysis by the U.S. Geological Survey Organic Geochemistry Research Group: Determination of acetamide herbicides and their degradation products in water using online solid-phase extraction and liquid chromatography/mass spectrometry
An analytical method for the determination of 6 acetamide herbicides (acetochlor, alachlor, dimethenamid, flufenacet, metolachlor, and propachlor) and 16 of their degradation products in natural water samples using solid-phase extraction and liquid chromatography/mass spectrometry is described in this report. Special consideration was given during the development of the method to prevent the formaAuthorsE.A. Lee, A.P. StrahanDetermination of antibiotic residues in manure, soil, and surface waters
In the last years more and more often detections of antimicrobially active compounds (“antibiotics”) in surface waters have been reported. As a possible input pathway in most cases municipal sewage has been discussed. But as an input from the realm of agriculture is conceivable as well, in this study it should be investigated if an input can occur via the pathway application of liquid manure on fiAuthorsT. Christian, R.J. Schneider, H.A. Farber, D. Skutlarek, M. T. Meyer, H.E. GoldbachHerbicides and transformation products in surface waters of the Midwestern United States
Most herbicides applied to crops are adsorbed by plants or transformed (degraded) in the soil, but small fractions are lost from fields and either move to streams in overland runoff, near surface flow, or subsurface drains, or they infiltrate slowly to ground water. Herbicide transformation products (TPs) can be more or less mobile and more or less toxic in the environment than their source herbicAuthorsW.A. Battaglin, E. M. Thurman, S. J. Kalkhoff, S. D. PorterHerbicides and herbicide degradation products in upper midwest agricultural streams during august base-flow conditions
Herbicide concentrations in streams of the U.S. Midwest have been shown to decrease through the growing season due to a variety of chemical and physical factors. The occurrence of herbicide degradation products at the end of the growing season is not well known. This study was conducted to document the occurrence of commonly used herbicides and their degradation products in Illinois, Iowa, and MinAuthorsS. J. Kalkhoff, K. E. Lee, S. D. Porter, P. J. Terrio, E. M. Thurman