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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3740

A mini drivepoint sampler for measuring pore water solute concentrations in the hyporheic zone of sand-bottom streams

A new method for collecting pore-water samples in sand and gravel streambeds is presented. We developed a mini drivepoint solution sampling (MINIPOINT) technique to collect pore-water samples at 2.5-cm vertical resolution. The sampler consisted of six small-diameter stainless steel drivepoints arranged in a 10-cm-diameter circular array. In a simple procedure, the sampler was installed in the stre
Authors
John H. Duff, Fred Murphy, Christopher C. Fuller, F. Triska, Judson W. Harvey, Alan P. Jackman

Investigation of anion-exchange and immunoaffinity particle-loaded membranes for the isolation of charged organic analytes from water

Anion-exchange and immunoaffinity particle loaded membranes (PLMs) were investigated as a mechanism for the isolation of charged organic analytes from water. Kinetic properties determined theoretically included dynamic capacity, pressure drop (ΔP), residence and diffusion times (Tr, Td), and total membrane porosity (εT). These properties were confirmed through experimental evaluation, and the PLM
Authors
T. R. Dombrowski, G.S. Wilson, E. M. Thurman

Effect of enhanced manganese oxidation in the hyporheic zone on basin-scale geochemical mass balance

We determined the role of the hyporheic zone (the subsurface zone where stream water and shallow groundwater mix) in enhancing microbially mediated oxidation of dissolved manganese (to form manganese precipitates) in a drainage basin contaminated by copper mining. The fate of manganese is of overall importance to water quality in Pinal Creek Basin, Arizona, because manganese reactions affect the t
Authors
Judson W. Harvey, Christopher C. Fuller

Estimating formation properties from early-time recovery in wells subject to turbulent head losses

A mathematical model is developed to interpret the early-time recovering water level following the termination of pumping in wells subject to turbulent head losses. The model assumes that turbulent head losses dissipate immediately when pumping ends. In wells subject to both borehole storage and turbulent head losses, the early-time recovery exhibits a slope equal to 1/2 on log-log plots of the re
Authors
A.M. Shapiro, D.S. Oki, E.A. Greene

Benthic sulfate reduction along the Chesapeake Bay central channel. I. Spatial trends and controls

Factors controlling the spatial distribution of benthic sulfate reduction (SR) were investigated at 3 stations [upper (UB), mid (MB) and lower bay (LB)] along the Chesapeake Bay (eastern USA) central channel from early spring through late fall, 1989 to 1994. Annual rates of 0 to 12 cm depth-integrated SR were 0.96, 9.62 and 6.33 mol S m-2 yr-1 for UB, MB and LB, respectively, as calculated from 35
Authors
M. C. Marvin-DiPasquale, D.G. Capone

Reductive dissolution and reactive solute transport in a sewage-contaminated glacial outwash aquifer

Contamination of shallow ground water by sewage effluent typically contains reduced chemical species that consume dissolved oxygen, developing either a low oxygen geochemical environment or an anaerobic geochemical environment. Based on the load of reduced chemical species discharged to shallow ground water and the amounts of reactants in the aquifer matrix, it should be possible to determine chem
Authors
R. W. Lee, P.C. Bennett

Humic substances as a mediator for microbially catalyzed metal reduction

The potential for humic substances to serve as a terminal electron acceptor in microbial respiration and to function as an electron shuttle between Fe(III)‐reducing microorganisms and insoluble Fe(III) oxides was investigated. The Fe(III)‐reducing microorganism Geobacter metallireducens conserved energy to support growth from electron transport to humics as evidenced by continued oxidation of acet
Authors
D. R. Lovley, J.L. Fraga, E. L. Blunt-Harris, L.A. Hayes, E. J. P. Phillips, J.D. Coates

AIRSLUG: A fortran program for the computation of type curves to estimate transmissivity and storativity from prematurely terminated air-pressurized slug tests

The Fortran code AIRSLUG can be used to generate the type curves needed to analyze the recovery data from prematurely terminated air-pressurized slug tests. These type curves, when used with a graphical software package, enable the engineer or scientist to analyze field tests to estimate transmissivity and storativity. Prematurely terminating the slug test can significantly reduce the overall time
Authors
E.A. Greene, A.M. Shapiro

Simulation of variable-density flow and transport of reactive and nonreactive solutes during a tracer test at Cape Cod, Massachusetts

A multispecies numerical code was developed to simulate flow and mass transport with kinetic adsorption in variable-density flow systems. The two-dimensional code simulated the transport of bromide (Br−), a nonreactive tracer, and lithium (Li+), a reactive tracer, in a large-scale tracer test performed in a sand-and-gravel aquifer at Cape Cod, Massachusetts. A two-fraction kinetic adsorption model
Authors
Hubao Zhang, Frank W. Schwartz, Warren W. Wood, S. P. Garabedian, D.R. LeBlanc

Simulated effects of irrigation on salinity in the Arkansas River Valley in Colorado

Agricultural irrigation has a substantial impact on water quantity and quality in the lower Arkansas River valley of southeastern Colorado. A two-dimensional flow and solute transport model was used to evaluate the potential effects of changes in irrigation on the quantity and quality of water in the alluvial aquifer and in the Arkansas River along an 17.7 km reach of the fiver. The model was cali
Authors
K. Goff, M.E. Lewis, M.A. Person, Leonard F. Konikow

How good are estimates of transmissivity from slug tests in fractured rock?

Slug tests in fractured rock usually are interpreted with models that assume homogeneous formation properties, even though hydraulic properties of fractures can vary by many orders of magnitude over the length of boreholes. To investigate the impact of heterogeneity on the interpretation of slug tests in fractured rock, slug tests were conducted over large intervals of boreholes in crystalline roc
Authors
A.M. Shapiro, P. A. Hsieh

Deviations from sorption linearity on soils of polar and nonpolar organic compounds at low relative concentrations

A series of single-solute and binary-solute sorption data have been obtained on representative samples of polar compounds (substituted ureas and phenolic compounds) and of nonpolar compounds (e.g., EDB and TCE) on a peat soil and a mineral (Woodburn) soil; the data extend to low relative solute concentrations (C(e)/S(w)). At relatively low C(e)/S(w), both the nonpolar and the polar solutes exhibit
Authors
C. T. Chiou, D. E. Kile