From Outcrop to Ions: development and application of in-situ isotope ratio measurements to solve geologic problems Active
Project objectives are to (1) develop innovative analytical techniques for isotope geochemistry and U-Pb geochronology using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), and (2) apply these techniques to collaborative research projects of high priority to the Mineral Resources Program, including studies related to the formation of "critical mineral" deposits, and studies related to Alaska and U.S. midcontinent regions.
Scientific Issue and Relevance
The Plasma Laboratory houses a new double-focusing multiple-collector plasma ionization mass spectrometer (MC-ICPMS), a Nu Plasma II, and a new 193 nm laser ablation system (RESOlution-SE). This LA-MC-ICPMS is designed to perform in-situ high-precision measurements of radiogenic and stable isotopes of trace elements. The other instrumentation in the Plasma Laboratory includes double-focusing single-collector lasma ionization mass spectrometer (SC-ICPMS), a Nu AttoM ES, and a new Agilent 7900 quadruple (Q) ICPMS. The latter two instruments are primarily used to perform rapid in situ measurements of Pb isotope ratios (i.e., common Pb for tracer studies or radiogenic Pb for U-Pb dating) and trace element abundances.
This project will allow us to (1) develop innovative in-situ analytical techniques for isotope geochemistry and U-Pb geochronology using plasma ionization mass spectrometry and (2) apply our new analytical techniques to collaborative research projects of high priority to the
Mineral Resources Program (MRP), including studies related to the U.S. midcontinent region and Alaska, and/or processes related to the formation of critical mineral deposits.
Methods to Address Issue
Our next major tasks are to refine our existing techniques and establish a series of new methods for isotopic and geochronological research using a philosophy of innovation through collaboration.
Innovation: Our goal is to improve the precision and accuracy of each technique to reach or surpass the cutting edge, while increasing efficiency (i.e., reducing the time and cost per analysis). We are following a phased approach of establishing or refining the analytical techniques from the basics (e.g., in situ U-Pb dating of zircon, apatite, titanite, and rutile, Hf isotopes in zircon; Nd isotopes in monazite) to those with higher risk and greater impact (e.g., St isotopes in apatite, feldspars, carbonates, and barite; Pb isotopes in feldspar and tourmaline; Li isotopes in tourmaline; Nd isotopes in bastnaesite or scheelite; Sn isotopes in cassiterite, or in situ U-Pb dating of ore-related minerals, such as bastnaesite, columbite, cassiterite, or scheelite).
Collaboration: The closely related fields of isotope geochemistry and geochronology are the power tools in the Geologist's tool chest. A major goal of this project is to increase the usage of these tools within the USGS through collaboration with other scientists on current and future MRP projects. We will involve USGS scientists in research with isotopes through a series of case studies related to high-priority Mineral Resources Program projects.
Project tasks are focused on the following activities:
- In-situ Isotope analysis of critical mineral isotope systems for geologic applications
- In-situ U-Pb geochronology of ore-forming and ore-related minerals applied to geologic processes
- In-situ U-Pb geochronology and trace element geochemistry of ore minerals and ore-forming processes
Return to: Mineral Resources Program | Geology, Geophysics, and Geochemistry Science Center
Below are other science projects associated with this project.
Metallogeny and Tectonics of the Lake Clark and Neacola Mountains Region, South-central Alaska
Rare Earth Element Deposits in the Southeast Mojave Desert
Development and Validation of Hyperspectral Imager for Field and Lab Scanning
Geologic Map of Alaska
Cenozoic Landscape Evolution of the Southern Rocky Mountains
Below are data releases associated with this project.
Below are publications associated with this project.
Explosive summit collapse of Kīlauea Volcano in 1924 preceded by a decade of crustal contamination and anomalous Pb isotope ratios
Petrographic, geochemical, and geochronologic data for cenozoic volcanic rocks of the Tonopah, Divide, and Goldfield Mining Districts, Nevada
U-Pb geochronology of tin deposits associated with the Cornubian Batholith of southwest England: Direct dating of cassiterite by in situ LA-ICPMS
A stratigraphic approach to inferring depositional ages from detrital geochronology data
Structural evolution of a gold-bearing transtensional zone within the Archean Porcupine-Destor deformation zone, southern Abitibi greenstone belt, eastern Ontario, Canada
Processes and facies relationships in a Lower(?) Devonian rocky shoreline depositional environment, East Lime Creek Conglomerate, south‐western Colorado, USA
In situ LA-ICPMS U–Pb dating of cassiterite without a known-age matrix-matched reference material: Examples from worldwide tin deposits spanning the Proterozoic to the Tertiary
Detrital zircon geochronology of quartzose metasedimentary rocks from parautochthonous North America, east-central Alaska
Evaluation of laser ablation double-focusing SC-ICPMS for “common” lead isotopic measurements in silicate glasses and mineral
- Overview
Project objectives are to (1) develop innovative analytical techniques for isotope geochemistry and U-Pb geochronology using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), and (2) apply these techniques to collaborative research projects of high priority to the Mineral Resources Program, including studies related to the formation of "critical mineral" deposits, and studies related to Alaska and U.S. midcontinent regions.
Scientific Issue and Relevance
The Plasma Laboratory houses a new double-focusing multiple-collector plasma ionization mass spectrometer (MC-ICPMS), a Nu Plasma II, and a new 193 nm laser ablation system (RESOlution-SE). This LA-MC-ICPMS is designed to perform in-situ high-precision measurements of radiogenic and stable isotopes of trace elements. The other instrumentation in the Plasma Laboratory includes double-focusing single-collector lasma ionization mass spectrometer (SC-ICPMS), a Nu AttoM ES, and a new Agilent 7900 quadruple (Q) ICPMS. The latter two instruments are primarily used to perform rapid in situ measurements of Pb isotope ratios (i.e., common Pb for tracer studies or radiogenic Pb for U-Pb dating) and trace element abundances.
This project will allow us to (1) develop innovative in-situ analytical techniques for isotope geochemistry and U-Pb geochronology using plasma ionization mass spectrometry and (2) apply our new analytical techniques to collaborative research projects of high priority to the
Mineral Resources Program (MRP), including studies related to the U.S. midcontinent region and Alaska, and/or processes related to the formation of critical mineral deposits.Methods to Address Issue
Our next major tasks are to refine our existing techniques and establish a series of new methods for isotopic and geochronological research using a philosophy of innovation through collaboration.
Innovation: Our goal is to improve the precision and accuracy of each technique to reach or surpass the cutting edge, while increasing efficiency (i.e., reducing the time and cost per analysis). We are following a phased approach of establishing or refining the analytical techniques from the basics (e.g., in situ U-Pb dating of zircon, apatite, titanite, and rutile, Hf isotopes in zircon; Nd isotopes in monazite) to those with higher risk and greater impact (e.g., St isotopes in apatite, feldspars, carbonates, and barite; Pb isotopes in feldspar and tourmaline; Li isotopes in tourmaline; Nd isotopes in bastnaesite or scheelite; Sn isotopes in cassiterite, or in situ U-Pb dating of ore-related minerals, such as bastnaesite, columbite, cassiterite, or scheelite).
Collaboration: The closely related fields of isotope geochemistry and geochronology are the power tools in the Geologist's tool chest. A major goal of this project is to increase the usage of these tools within the USGS through collaboration with other scientists on current and future MRP projects. We will involve USGS scientists in research with isotopes through a series of case studies related to high-priority Mineral Resources Program projects.
Project tasks are focused on the following activities:
- In-situ Isotope analysis of critical mineral isotope systems for geologic applications
- In-situ U-Pb geochronology of ore-forming and ore-related minerals applied to geologic processes
- In-situ U-Pb geochronology and trace element geochemistry of ore minerals and ore-forming processes
Return to: Mineral Resources Program | Geology, Geophysics, and Geochemistry Science Center
- Science
Below are other science projects associated with this project.
Filter Total Items: 17Metallogeny and Tectonics of the Lake Clark and Neacola Mountains Region, South-central Alaska
Alaska hosts a well-documented belt of ore deposits that lies roughly parallel to the Alaska Range, beginning at the Alaska Peninsula in the southwest, continuing up through the Fairbanks Mining District in the north, and curving back into the Tintina Gold Belt on its eastern end. Known mineral prospects and occurrences include porphyry copper, intrusion-related gold, volcanogenic massive sulfides...Rare Earth Element Deposits in the Southeast Mojave Desert
In an effort to better understand domestic resource potential, the USGS is investigating the genetic relationship between rare earth element deposits at Mountain Pass, California and Music Valley (Pinto Mountains, California) and extend these studies across a 130-km long belt of alkaline Proterozoic rocks in the southeast Mojave Desert. Such a combined study would significantly improve our...Development and Validation of Hyperspectral Imager for Field and Lab Scanning
The Mineral Resources Program has advanced methods of imaging spectroscopy (hyperspectral remote sensing) that are now used routinely by the earth science and remote sensing communities for mineral mapping, soil quality mapping, hazard mitigation, and other terrestrial and planetary applications. The USGS is highly qualified to advance this technology based on its world class expertise in mineral...Geologic Map of Alaska
In January 2016, the U.S. Geological Survey released the first ever digital geologic map of Alaska. This map reflects more than a century of work and provides a visual context for the abundant mineral and energy resources found throughout the state. The map also is available to use in three different formats: a professional GIS database, a public interactive version via a web browser, and an...Cenozoic Landscape Evolution of the Southern Rocky Mountains
The Cenozoic Landscape Evolution of the Southern Rocky Mountains Project is a multi-year investigation funded by the National Cooperative Geologic Mapping Program. This project utilizes a combination of geologic mapping, geophysical surveys, basin modeling, and structural, neotectonic, geomorphic, volcanic, stratigraphic, and geochronologic studies to better understand the geologic landscape of... - Data
Below are data releases associated with this project.
- Publications
Below are publications associated with this project.
Filter Total Items: 21Explosive summit collapse of Kīlauea Volcano in 1924 preceded by a decade of crustal contamination and anomalous Pb isotope ratios
A geochemical time-series analysis of lavas from frequently active basaltic volcanoes has the potential to reveal the enigmatic mantle controls on volcanic behavior and hazards. In May 1924, the century-long lava lake within Halemaʻumaʻu pit crater at the summit of Kīlauea Volcano drained and the floor of Halemaʻumaʻu collapsed, triggering ∼3 weeks of phreatic explosions due to the interaction ofAuthorsAaron Pietruszka, Daniel E. Heaton, Michael O Garcia, Jared P. MarskePetrographic, geochemical, and geochronologic data for cenozoic volcanic rocks of the Tonopah, Divide, and Goldfield Mining Districts, Nevada
The purpose of this report is to summarize geochemical, petrographic, and geochronologic data for samples, principally those of unmineralized Tertiary volcanic rocks, from the Tonopah, Divide, and Goldfield mining districts of west-central Nevada (fig. 1). Much of the data presented here for the Tonopah and Divide districts are for samples collected by Bonham and Garside (1979) during geologic mapAuthorsEdward A. du Bray, David John, Peter G. Vikre, Joseph Colgan, Michael A. Cosca, Leah E. Morgan, Robert J. Fleck, Wayne R. Premo, Christopher S. Holm-DenomaU-Pb geochronology of tin deposits associated with the Cornubian Batholith of southwest England: Direct dating of cassiterite by in situ LA-ICPMS
The Cornwall and Devon vein- and greisen-type copper and tin deposits of southwest England are spatially and genetically related to shallow-seated granitic intrusions. These late Variscan intrusions, collectively known as the Cornubian Batholith, extend over 200 km and form a continuous granitic spine from the Isles of Scilly Granite in the west to the Dartmoor Granite in the east. The granitic plAuthorsRichard J. Moscati, Leonid A. NeymarkA stratigraphic approach to inferring depositional ages from detrital geochronology data
With the increasing use of detrital geochronology data for provenance analyses, we have also developed new constraints on the age of otherwise undateable sedimentary deposits. Because a deposit can be no older than its youngest mineral constituent, the youngest defensible detrital mineral age defines the maximum depositional age of the sampled bed. Defining the youngest `defensible' age in the facAuthorsSamuel Johnstone, Theresa M. Schwartz, Christopher S. Holm-DenomaStructural evolution of a gold-bearing transtensional zone within the Archean Porcupine-Destor deformation zone, southern Abitibi greenstone belt, eastern Ontario, Canada
The Garrison camp comprises four structurally distinct orogenic gold deposits that formed in different host lithologies during progressive deformation. Detailed field mapping, drill core logging, and geochronological constraints suggest that the 2678 ± 2 Ma Garrison granitic stock played a fundamental rheological role in the location of the four deposits. Initial local shear movement occurred alonAuthorsMiguel T. Nassif, Yvette D. Kuiper, Richard J. Goldfarb, Thomas Monecke, Christopher S. Holm-DenomaProcesses and facies relationships in a Lower(?) Devonian rocky shoreline depositional environment, East Lime Creek Conglomerate, south‐western Colorado, USA
Rocky shorelines are relatively common features along modern coastlines, but few have been recognized in the geological record. The hard substrates of rocky shorelines telescope the width of offshore marine environments, thus the diagnostic deposits observed in such settings today have a low preservation potential due to small accommodation space and high‐energy conditions. This study recognized pAuthorsJames E. Evans, Christopher S. Holm-DenomaIn situ LA-ICPMS U–Pb dating of cassiterite without a known-age matrix-matched reference material: Examples from worldwide tin deposits spanning the Proterozoic to the Tertiary
Cassiterite (SnO2), a main ore mineral in tin deposits, is suitable for U–Pb isotopic dating because of its relatively high U/Pb ratios and typically low common Pb. We report a LA-ICPMS analytical procedure for U–Pb dating of this mineral with no need for an independently dated matrix-matched cassiterite standard. LA-ICPMS U-Th-Pb data were acquired while using NIST 612 glass as a primary non-matrAuthorsLeonid A. Neymark, Christopher S. Holm-Denoma, Richard J. MoscatiDetrital zircon geochronology of quartzose metasedimentary rocks from parautochthonous North America, east-central Alaska
We report eight new U-Pb detrital zircon ages for quartzose metasedimentary rocks from four lithotectonic units of parautochthonous North America in east-central Alaska: the Healy schist, Keevy Peak Formation, and Sheep Creek Member of the Totatlanika Schist in the northern Alaska Range, and the Butte assemblage in the northwestern Yukon-Tanana Upland. Excepting 1 of 3 samples from the Healy schisAuthorsCynthia Dusel-Bacon, Christopher S. Holm-Denoma, James V. Jones, John N. Aleinikoff, James K. MortensenEvaluation of laser ablation double-focusing SC-ICPMS for “common” lead isotopic measurements in silicate glasses and mineral
An analytical method for the in situ measurement of “common” Pb isotope ratios in silicate glasses and minerals using a 193-nm excimer laser ablation (LA) system with a double-focusing single-collector (SC)-ICPMS is presented and evaluated as a possible alternative to multiple-collector (MC)-ICPMS. This LA-SC-ICPMS technique employs fast-scanning ion deflectors to sequentially place a series of flAuthorsAaron J. Pietruszka, Leonid A. Neymark