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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3740

Biodegradation of the surfactant linear alkylbenzenesulfonate in sewage-contaminated groundwater: A comparison of column experiments and field tracer tests

Transport and biodegradation of linear alkylbenzenesulfonate (LAS) in sewage-contaminated groundwater were investigated for a range of dissolved oxygen concentrations. Both laboratory column and an 80-day continuous injection tracer test field experiments were conducted. The rates of LAS biodegradation increased with increasing dissolved oxygen concentrations and indicated the preferential biodegr
Authors
C.J. Krueger, K.M. Radakovich, T.E. Sawyer, L. B. Barber, R. L. Smith, J.A. Field

Bacterial methylmercury degradation in Florida Everglades peat sediment

Methylmercury (MeHg) degradation was investigated along an eutrophication gradient in the Florida Everglades by quantifying 14CH4 and 14CO2 production after incubation of anaerobic sediments with [14C]MeHg. Degradation rate constants (k) were consistently ≤0.1 d-1 and decreased with sediment depth. Higher k values were observed when shorter incubation times and lower MeHg amendment levels were use
Authors
M. C. Marvin-DiPasquale, R.S. Oremland

Microbial diversity in a hydrocarbon- and chlorinated-solvent- contaminated aquifer undergoing intrinsic bioremediation

A culture-independent molecular phylogenetic approach was used to survey constituents of microbial communities associated with an aquifer contaminated with hydrocarbons (mainly jet fuel) and chlorinated solvents undergoing intrinsic bioremediation. Samples were obtained from three redox zones: methanogenic, methanogenic-sulfate reducing, and iron or sulfate reducing. Small-subunit rRNA genes were
Authors
M.A. Dojka, P. Hugenholtz, S.K. Haack, N.R. Pace

Regression models of herbicide concentrations in outflow from reservoirs in the midwestern USA, 1992-1993

Reservoirs are used to store water for public water supply, flood control, irrigation, recreation, hydropower, and wildlife habitat, but also often store undesirable substances such as herbicides. The outflow from 76 reservoirs in the midwestern USA, was sampled four times in 1992 and four times in 1993. At least one herbicide was detected in 82.6 percent of all samples, and atrazine was detected
Authors
W.A. Battaglin, D. A. Goolsby

Flow of river water into a karstic limestone aquifer: 2. Dating the young fraction in groundwater mixtures in the Upper Floridan aquifer near Valdosta, Georgia

Tritium/helium-3 (3H/3He) and chlorofluorocarbon (CFCs, CFC–11, CFC–12, CFC–113) data are used to date the young fraction in groundwater mixtures from a karstic limestone aquifer near Valdosta, Georgia, where regional paleowater in the Upper Floridan aquifer receives recharge from two young sources—the flow of Withlacoochee River water through sinkholes in the river bed, and leakage of infiltratio
Authors
Niel Plummer, E. Busenberg, S. Drenkard, P. Schlosser, B. Ekwurzel, R. Weppernig, J. B. McConnell, R. L. Michel

Evaluating the source and residence times of groundwater seepage to streams, New Jersey Coastal Plain

A conceptual model of the patterns and residence times of groundwater seepage to gaining streams indicates that groundwater seepage originates from sources that are both near and far from the stream. Consequently, the age of groundwater seepage across a stream-channel transect increases from its banks to its center and becomes progressively older with distance downstream. A groundwater flow model
Authors
E. Modica, H. T. Buxton, Niel Plummer

Changes in production and respiration during a spring phytoplankton bloom in San Francisco Bay, California, USA: Implications for net ecosystem metabolism

We present results of an intensive sampling program designed to measure weekly changes in ecosystem respiration (oxygen consumption in the water column and sediments) around the 1996 spring bloom in South San Francisco Bay, California, USA. Measurements were made at a shallow site (2 m, where mean photic depth was 60% of the water column height) and a deep site (15 m, mean photic depth was only 20
Authors
J.M. Caffrey, J. E. Cloern, C. Grenz

Degradation of chloroacetanilide herbicides: The prevalence of sulfonic and oxanilic acid metabolites in Iowa groundwaters and surface waters

Water samples were collected from 88 municipal wells throughout Iowa during the summer and were collected monthly at 12 stream sites in eastern Iowa from March to December 1996 to study the occurrence of the sulfonic and oxanilic metabolites of acetochlor, alachlor, and metolachlor. The sulfonic and oxanilic metabolites were present in almost 75% of the groundwater samples and were generally prese
Authors
Stephen J. Kalkhoff, Dana W. Kolpin, E. M. Thurman, I. Ferrer, D. Barcelo

Development and testing of a compartmentalized reaction network model for redox zones in contaminated aquifers

The work reported here is the first part of a larger effort focused on efficient numerical simulation of redox zone development in contaminated aquifers. The sequential use of various electron acceptors, which is governed by the energy yield of each reaction, gives rise to redox zones. The large difference in energy yields between the various redox reactions leads to systems of equations that are
Authors
Robert H. Abrams, Keith Loague, Douglas B. Kent

Preferential flow and transport of nitrate and bromide in claypan soil

The in situ measurement of water flow and chemical transport through clay pan soils is crucial to understanding potential water contamination from agricultural sources. It is important due to the large areal extent of these soils in agricultural regions of the midwestern United States and because of preferential flow paths caused by desiccation cracks, worms burrowing, and root development. A stud
Authors
B. P. Kelly, M.L. Pomes

Microbial oxidation of elemental selenium in soil slurries and bacterial cultures

The microbial oxidation of elemental selenium [Se(O)] was studied by employing 75Se(O) as a tracer. Live, oxic soil slurries demonstrated a linear production of mostly Se(IV), with the formation of smaller quantities of Se(VI). Production of both Se(IV) and Se(VI) was inhibited by autoclaving, formalin, antibiotics, azide, and 2,4-dinitrophenol, thereby indicating the involvement of microbes. Oxid
Authors
P.R. Dowdle, R.S. Oremland