Madalyn S. Blondes, Ph.D.
Madalyn Blondes is a Research Geologist at the USGS Geology, Energy & Minerals (GEM) Science Center in Reston, VA.
Madalyn is the co-Chief of the Oil & Gas Waters Project and also works on the Utilization of Carbon and other Energy Gases Project. Her current research focuses on the geochemistry of water associated with oil and gas production (produced waters), geologic CO2 storage through mineralization, compositional data analysis (CoDa) in the earth sciences, development of probabilistic assessment methodologies for CO2 storage and enhanced oil recovery (EOR) in geologic reservoirs, and using geochemistry to understand CO2 flow in natural systems. Madalyn obtained her B.A. from the Pomona College Geology Department in 2003 and her Ph.D. from the Yale University Department of Geology & Geophysics in 2008. She did postdoctoral research at the University of Maryland before joining the USGS in 2010.
Professional Experience
2008 - 2010: Postdoctoral Associate, University of Maryland, College Park, MD
Education and Certifications
Ph.D. Geology & Geophysics, Yale University, 2008
M.Phil. Geology & Geophysics, Yale University, 2005
B.A. Geology, Pomona College, 2003
Science and Products
Oil and Gas Waters Project
The primary objective of this project is to provide information on the volume, quality, impacts, and possible uses of water produced during generation and development of energy resources (particularly hydrocarbons) as well as related fluids injected into reservoirs for energy development and associated waste disposal. The purpose of this work is to address scientific and societal questions...
Characterization and Reuse of Oil and Gas Waters
In the “Characterization and Reuse of Oil and Gas Waters” task of the Oil and Gas Waters Project, we collect new water samples from conventional and hydraulically fractured unconventional plays in high priority oil and gas basins and use the geochemistry of water produced along with oil and gas (a) as a tool to interpret deep basin fluid flow and to fingerprint brines from specific reservoirs, (b)...
Filter Total Items: 15
Lithium observations, machine-learning predictions, and mass estimates from the Smackover Formation brines in southern Arkansas
Global demand for lithium, the primary component of lithium-ion batteries, greatly exceeds known supplies and this imbalance is expected to increase as the world transitions away from fossil fuel energy sources. The goal of this work was to calculate the total lithium mass in brines of the Reynolds oolite unit of the Smackover Formation in southern Arkansas using predicted lithium concentrations f
Carbon Dioxide Storage Resources - Appalachian Basin, Black Warrior Basin, Illinois Basin, and Michigan Basin: Chapter P, Spatial Data
The storage assessment unit (SAU) is the fundamental unit used in the National Assessment of Geologic Carbon Dioxide Storage Resources project for the assessment of geologic CO2 storage resources. The SAU is shown here as a geographic boundary interpreted, defined, and mapped by the geologist responsible for the assessment interval. Individual SAUs are defined on the basis of common geologic and h
Utica Shale and Point Pleasant Formation Isotopic Compositions
This release contains isotopic composition (δ7Li, δ11B, δ138Ba) data of produced water and core samples taken from the Utica Shale and Point Pleasant Formation.
Carbon Dioxide Storage Resources-Wind River Basin: Chapter O, Spatial Data
The storage assessment unit (SAU) is the fundamental unit used in the National Assessment of Geologic Carbon Dioxide Storage Resources project for the assessment of geologic CO2 storage resources. The SAU is shown here as a geographic boundary interpreted, defined, and mapped by the geologist responsible for the assessment interval. Individual SAUs are defined on the basis of common geologic and h
U.S. Geological Survey National Produced Waters Geochemical Database (ver. 3.0, December 2023)
During hydrocarbon production, water is typically co-produced from the geologic formations producing oil and gas. Understanding the composition of these produced waters is important to help investigate the regional hydrogeology, the source of the water, the efficacy of water treatment and disposal plans, potential economic benefits of mineral commodities in the fluids, and the safety of potential
Absorbance and Fluorescence Excitation-Emission Matrix Data for Produced Waters from Oil and Gas Producing Basins in the United States
Waters co-produced during petroleum extraction are normally considered wastes but are also possible resources, especially in water-stressed regions. Produced waters can be chemically complex. High salinity, naturally occurring radioactive materials, and organic substances derived from the producing formation can complicate treatment processes. Rapid screening methods to characterize produced water
National assessment of carbon dioxide enhanced oil recovery and associated carbon dioxide retention resources - data release
In 2020, the U.S. Geological Survey (USGS) completed a probabilistic assessment of the volume of technically recoverable oil resources available if current carbon dioxide enhanced oil recovery (CO2-EOR) technologies were applied in amenable oil reservoirs underlying the onshore and State waters area of the conterminous United States. The assessment also includes estimates of the magnitude of CO2 s
Geologic formations and mine locations for potential CO2 mineralization
This geodatabase contains geologic unit boundaries and asbestos site locations shown in "Carbon dioxide mineralization feasibility in the United States" (Blondes and others, 2019). Data was compiled from source material at a scale range of 1:100,000 to 1:5,000,000 and is not intended for any greater detail.
Microbiology of the Utica Shale
In order to determine the innate microbial community of shale gas reservoirs and how they are impacted by hydraulic fracturing, this study analyzed biomass collected from produced water and rock from hydraulically fractured wells in the Utica Shale. The samples include rock chips from a drill core from one Utica well, produced water from that same Utica well, and produced water from 12 different U
Input Files and Code for: Machine learning can accurately assign geologic basin to produced water samples using major geochemical parameters
As more hydrocarbon production from hydraulic fracturing and other methods produce large volumes of water, innovative methods must be explored for treatment and reuse of these waters. However, understanding the general water chemistry of these fluids is essential to providing the best treatment options optimized for each producing area. Machine learning algorithms can often be applied to datasets
Model of groundwater flow, gas migration, and reactive transport in the Virgin River Basin, SW Utah
To better understand the possible risks posed to shallow groundwater resources by geologic carbon sequestration (GCS), a multi-scale numerical modeling approach was invoked using the TOUGHREACT code from Lawrence Berkeley National Laboratory. The code solves coupled equations representing conservation of mass and energy on a finite difference grid to simulate multiphase, multicomponent, non-isothe
Geochemistry of Utica Shale Play and other Appalachian produced waters
Citation Note: These data were collected as part of a research study published in Environmental Science and Technology. Please reference the following paper when citing these data. Blondes, M.S., Shelton, J.L., Engle, M.A., Trembly, J.P., Doolan, C.A., Jubb, A.M., Chenault, J.M., Rowan, E.L., Haefner, R.J., and Mailot, B.E., 2020, Utica Shale Play Oil and Gas Brines: Geochemistry and Factors Infl
Filter Total Items: 39
Utica/Point Pleasant brine isotopic compositions (δ7Li, δ11B, δ138Ba) elucidate mechanisms of lithium enrichment in the Appalachian Basin
Global Li production will require a ~500 % increase to meet 2050 projected energy storage demands. One potential source is oil and gas wastewater (i.e., produced water or brine), which naturally has high total dissolved solids (TDS) concentrations, that can also be enriched in Li (>100 mg/L). Understanding the sources and mechanisms responsible for high naturally-occurring Li concentrations can ai
Authors
Bonnie McDevitt, Travis L. Tasker, Rachel Coyte, Madalyn S. Blondes, Brian W. Stewart, Rosemary C Capo, J. Alexandra Hakala, Avner Vengosh, William D Burgos, Nathaniel R. Warner
Ion exchange processes for CO2 mineralization using industrial waste streams: Pilot plant demonstration and life cycle assessment
An attractive technique for removing CO2 from the environment is sequestration within stable carbonate solids (e. g., calcite). However, continuous addition of alkalinity is required to achieve favorable conditions for carbonate precipitation (pH>8) from aqueous streams containing dissolved CO2 (pH<4.5) and Ca2+ ions. In this study, a pH-swing process using ion exchange was demonstrated to process
Authors
Steven Bustillos, Mario Christofides, Bonnie McDevitt, Madalyn S. Blondes, Ryan J. McAleer, Aaron M. Jubb, Bu Wang, Gaurav Sant, Dante Simonetti
Geologic carbon management options for the North Atlantic-Appalachian Region
IntroductionThe U.S. Geological Survey (USGS) North Atlantic-Appalachian Region is developing the regionwide capacity to provide timely science support for decision-makers attempting to enhance carbon removal, sequestration, and emissions mitigation to meet national atmospheric carbon reduction goals. The U.S. Environmental Protection Agency (EPA) reported that in 2021, the fourteen States and the
Authors
Peter D. Warwick, Madalyn S. Blondes, Sean T. Brennan, Steven M. Cahan, C. Özgen Karacan, Kevin D. Kroeger, Matthew D. Merrill
Dissolved organic matter within oil and gas associated wastewaters from U.S. unconventional petroleum plays: Comparisons and consequences for disposal and reuse
Wastewater generated during petroleum extraction (produced water) may contain high concentrations of dissolved organics due to their intimate association with organic-rich source rocks, expelled petroleum, and organic additives to fluids used for hydraulic fracturing of unconventional (e.g., shale) reservoirs. Dissolved organic matter (DOM) within produced water represents a challenge for treatmen
Authors
Bonnie McDevitt, Aaron M. Jubb, Matthew S. Varonka, Madalyn S. Blondes, Mark A Engle, Tanya J. Gallegos, Jenna L. Shelton
National assessment of carbon dioxide enhanced oil recovery and associated carbon dioxide retention resources — Results
In 2020, the U.S. Geological Survey (USGS) completed a probabilistic assessment of the volume of technically recoverable oil resources available if current carbon dioxide enhanced oil recovery (CO2-EOR) technologies were applied to amenable oil reservoirs underlying the onshore and State waters areas of the conterminous United States. The assessment also includes estimates of the mass of CO2 that
Authors
Peter D. Warwick, Emil D. Attanasi, Madalyn S. Blondes, Sean T. Brennan, Marc L. Buursink, Steven M. Cahan, Colin A. Doolan, Philip A. Freeman, C. Özgen Karacan, Celeste D. Lohr, Matthew D. Merrill, Ricardo A. Olea, Jenna L. Shelton, Ernie R. Slucher, Brian A. Varela
National assessment of carbon dioxide enhanced oil recovery and associated carbon dioxide retention resources — Summary
IntroductionIn 2020, the U.S. Geological Survey (USGS) completed a probabilistic assessment of the volume of technically recoverable oil resources that might be produced by using current carbon dioxide enhanced oil recovery (CO2-EOR) technologies in amenable conventional oil reservoirs underlying the onshore and State waters areas of the conterminous United States. The assessment also includes est
Authors
Peter D. Warwick, Emil D. Attanasi, Madalyn S. Blondes, Sean T. Brennan, Marc L. Buursink, Steven M. Cahan, Colin A. Doolan, Philip A. Freeman, C. Özgen Karacan, Celeste D. Lohr, Matthew D. Merrill, Ricardo A. Olea, Jenna L. Shelton, Ernie R. Slucher, Brian A. Varela
Machine learning can assign geologic basin to produced water samples using major ion geochemistry
Understanding the geochemistry of waters produced during petroleum extraction is essential to informing the best treatment and reuse options, which can potentially be optimized for a given geologic basin. Here, we used the US Geological Survey’s National Produced Waters Geochemical Database (PWGD) to determine if major ion chemistry could be used to classify accurately a produced water sample to a
Authors
Jenna L. Shelton, Aaron M. Jubb, Samuel Saxe, Emil D. Attanasi, Alexei Milkov, Mark A Engle, Philip A. Freeman, Christopher Shaffer, Madalyn S. Blondes
Potential Pb+2 mobilization, transport, and sequestration in shallow aquifers impacted by multiphase CO2 leakage: A natural analogue study from the Virgin River Basin in Southwest Utah
Geological carbon sequestration (GCS) is necessary to help meet emissions reduction goals, but groundwater contamination may occur if CO2 and/or brine were to leak out of deep storage formations into the shallow subsurface. For this study, a natural analogue was investigated: in the Virgin River Basin of southwest Utah, water with moderate salinity and high CO2 concentrations is leaking upward int
Authors
Michelle R. Plampin, Madalyn S. Blondes, Eric Sonnenthal, William H. Craddock
Utica shale play oil and gas brines: Geochemistry and factors influencing wastewater management
The Utica and Marcellus Shale Plays in the Appalachian Basin are the fourth and first largest natural gas producing plays in the United States, respectively. Hydrocarbon production generates large volumes of brine (“produced water”) that must be disposed of, treated, or reused. Though Marcellus brines have been studied extensively, there are few studies from the Utica Shale Play. This study presen
Authors
Madalyn S. Blondes, Jenna L. Shelton, Mark A Engle, Jason Trembly, Colin A. Doolan, Aaron M. Jubb, Jessica Chenault, Elisabeth L. Rowan, Ralph J. Haefner, Brian E. Mailot
Four-dimensional thermal evolution of the East African Orogen: Accessory phase petrochronology of crustal profiles through the Tanzanian Craton and Mozambique Belt, northeastern Tanzania
U–Pb petrochronology of deep crustal xenoliths and outcrops across northeastern Tanzania track the thermal evolution of the Mozambique Belt and Tanzanian Craton following the Neoproterozoic East African Orogeny (EAO) and subsequent Neogene rifting. At the craton margin, the upper–middle crust record thermal quiescence since the Archean (2.8–2.5 Ga zircon, rutile, and apatite in granite and amphibo
Authors
Francisco E. Apen, Roberta L. Rudnick, John M. Cottle, Andrew R.C. Kylander-Clark, Madalyn S. Blondes, Phil Piccoli, Gareth Seward
Repetitive sampling and control threshold improve 16S rRNA results from produced waters associated with hydraulically fractured shales
Sequencing microbial DNA from deep subsurface environments is complicated by a number of issues ranging from contamination to non-reproducible results. Many samples obtained from these environments - which are of great interest due to the potential to stimulate microbial methane generation - contain low biomass. Therefore, samples from these environments are difficult to study as sequencing result
Authors
Jenna L. Shelton, Elliott Barnhart, Leslie F. Ruppert, Aaron M. Jubb, Madalyn S. Blondes, Christina A. DeVera
Modeling geologic sequestration of carbon dioxide in a deep saline carbonate reservoir with TOUGH2–ChemPlugin, a new tool for reactive transport modeling
This paper outlines the development and demonstration of a new tool, TOUGH2–ChemPlugin (T2CPI) for predicting rock–water–CO2 interaction following injection of supercritical CO2 into a heterogeneous carbonate system. Specifically, modeling capabilities of TOUGH2, which examines multiphase flow and supercritical CO2 behavior, were combined with the geochemical modeling capabilities of The Geochemis
Authors
Tina L. Roberts-Ashby, Peter M. Berger, Jeffrey A. Cunningham, Ram Kumar, Madalyn S. Blondes
Non-USGS Publications**
Blondes, M.S., Brandon, M.T., Reiners, P.W., Kita, N.T., Page, F.Z., 2012. Generation of forsteritic olivine (Fo99.8) by subsolidus oxidation in basaltic flows: Journal of Petrology, v. 53, p. 971-984.
Blondes, M.S., 2008. Single Eruption Temporal-Compositional Variation in Basalts: Ph.D. Thesis, Yale University.
Blondes, M.S., Reiners, P.W., Ducea, M.N., Singer, B.S., Chesley, J., 2008. Temporal-compositional trends over short and long time-scales in basalts of the Big Pine Volcanic Field, CA: Earth and Planetary Science Letters, v. 269, p. 140-154.
Blondes, M.S., Reiners, P.W., Edwards, B.R., Biscontini, A., 2007. Dating young basalt eruptions by (U-Th)/He on xenolithic zircons: Geology, v. 35, no. 1, p. 17-20.
**Disclaimer: The views expressed in Non-USGS publications are those of the author and do not represent the views of the USGS, Department of the Interior, or the U.S. Government.
U.S. Geological Survey National Produced Waters Geochemical Database (ver. 3.0, December 2023) Viewer
The U.S. Geological Survey National Produced Waters Geochemical Database Viewer (ver. 3.0) provides access to an updated compilation of geochemical and related information for water from oil and gas wells in the United States. The information includes identification and location information, well descriptions, dates, rock properties, physical properties of the water, organic chemistry and more.
CO2assessment R package
The CO2assessment package provides R functions and a Shiny application for CO2 storage resource assessment using 2013 USGS National Assessment of Geologic Carbon Dioxide Storage Resources methodology. Tools to facilitate estimation of CO2 storage resources in geologic formations include volumetric and thermodynamic equations and Monte Carlo simulation. The set of input parameters define probabilit
Science and Products
Oil and Gas Waters Project
The primary objective of this project is to provide information on the volume, quality, impacts, and possible uses of water produced during generation and development of energy resources (particularly hydrocarbons) as well as related fluids injected into reservoirs for energy development and associated waste disposal. The purpose of this work is to address scientific and societal questions...
Characterization and Reuse of Oil and Gas Waters
In the “Characterization and Reuse of Oil and Gas Waters” task of the Oil and Gas Waters Project, we collect new water samples from conventional and hydraulically fractured unconventional plays in high priority oil and gas basins and use the geochemistry of water produced along with oil and gas (a) as a tool to interpret deep basin fluid flow and to fingerprint brines from specific reservoirs, (b)...
Filter Total Items: 15
Lithium observations, machine-learning predictions, and mass estimates from the Smackover Formation brines in southern Arkansas
Global demand for lithium, the primary component of lithium-ion batteries, greatly exceeds known supplies and this imbalance is expected to increase as the world transitions away from fossil fuel energy sources. The goal of this work was to calculate the total lithium mass in brines of the Reynolds oolite unit of the Smackover Formation in southern Arkansas using predicted lithium concentrations f
Carbon Dioxide Storage Resources - Appalachian Basin, Black Warrior Basin, Illinois Basin, and Michigan Basin: Chapter P, Spatial Data
The storage assessment unit (SAU) is the fundamental unit used in the National Assessment of Geologic Carbon Dioxide Storage Resources project for the assessment of geologic CO2 storage resources. The SAU is shown here as a geographic boundary interpreted, defined, and mapped by the geologist responsible for the assessment interval. Individual SAUs are defined on the basis of common geologic and h
Utica Shale and Point Pleasant Formation Isotopic Compositions
This release contains isotopic composition (δ7Li, δ11B, δ138Ba) data of produced water and core samples taken from the Utica Shale and Point Pleasant Formation.
Carbon Dioxide Storage Resources-Wind River Basin: Chapter O, Spatial Data
The storage assessment unit (SAU) is the fundamental unit used in the National Assessment of Geologic Carbon Dioxide Storage Resources project for the assessment of geologic CO2 storage resources. The SAU is shown here as a geographic boundary interpreted, defined, and mapped by the geologist responsible for the assessment interval. Individual SAUs are defined on the basis of common geologic and h
U.S. Geological Survey National Produced Waters Geochemical Database (ver. 3.0, December 2023)
During hydrocarbon production, water is typically co-produced from the geologic formations producing oil and gas. Understanding the composition of these produced waters is important to help investigate the regional hydrogeology, the source of the water, the efficacy of water treatment and disposal plans, potential economic benefits of mineral commodities in the fluids, and the safety of potential
Absorbance and Fluorescence Excitation-Emission Matrix Data for Produced Waters from Oil and Gas Producing Basins in the United States
Waters co-produced during petroleum extraction are normally considered wastes but are also possible resources, especially in water-stressed regions. Produced waters can be chemically complex. High salinity, naturally occurring radioactive materials, and organic substances derived from the producing formation can complicate treatment processes. Rapid screening methods to characterize produced water
National assessment of carbon dioxide enhanced oil recovery and associated carbon dioxide retention resources - data release
In 2020, the U.S. Geological Survey (USGS) completed a probabilistic assessment of the volume of technically recoverable oil resources available if current carbon dioxide enhanced oil recovery (CO2-EOR) technologies were applied in amenable oil reservoirs underlying the onshore and State waters area of the conterminous United States. The assessment also includes estimates of the magnitude of CO2 s
Geologic formations and mine locations for potential CO2 mineralization
This geodatabase contains geologic unit boundaries and asbestos site locations shown in "Carbon dioxide mineralization feasibility in the United States" (Blondes and others, 2019). Data was compiled from source material at a scale range of 1:100,000 to 1:5,000,000 and is not intended for any greater detail.
Microbiology of the Utica Shale
In order to determine the innate microbial community of shale gas reservoirs and how they are impacted by hydraulic fracturing, this study analyzed biomass collected from produced water and rock from hydraulically fractured wells in the Utica Shale. The samples include rock chips from a drill core from one Utica well, produced water from that same Utica well, and produced water from 12 different U
Input Files and Code for: Machine learning can accurately assign geologic basin to produced water samples using major geochemical parameters
As more hydrocarbon production from hydraulic fracturing and other methods produce large volumes of water, innovative methods must be explored for treatment and reuse of these waters. However, understanding the general water chemistry of these fluids is essential to providing the best treatment options optimized for each producing area. Machine learning algorithms can often be applied to datasets
Model of groundwater flow, gas migration, and reactive transport in the Virgin River Basin, SW Utah
To better understand the possible risks posed to shallow groundwater resources by geologic carbon sequestration (GCS), a multi-scale numerical modeling approach was invoked using the TOUGHREACT code from Lawrence Berkeley National Laboratory. The code solves coupled equations representing conservation of mass and energy on a finite difference grid to simulate multiphase, multicomponent, non-isothe
Geochemistry of Utica Shale Play and other Appalachian produced waters
Citation Note: These data were collected as part of a research study published in Environmental Science and Technology. Please reference the following paper when citing these data. Blondes, M.S., Shelton, J.L., Engle, M.A., Trembly, J.P., Doolan, C.A., Jubb, A.M., Chenault, J.M., Rowan, E.L., Haefner, R.J., and Mailot, B.E., 2020, Utica Shale Play Oil and Gas Brines: Geochemistry and Factors Infl
Filter Total Items: 39
Utica/Point Pleasant brine isotopic compositions (δ7Li, δ11B, δ138Ba) elucidate mechanisms of lithium enrichment in the Appalachian Basin
Global Li production will require a ~500 % increase to meet 2050 projected energy storage demands. One potential source is oil and gas wastewater (i.e., produced water or brine), which naturally has high total dissolved solids (TDS) concentrations, that can also be enriched in Li (>100 mg/L). Understanding the sources and mechanisms responsible for high naturally-occurring Li concentrations can ai
Authors
Bonnie McDevitt, Travis L. Tasker, Rachel Coyte, Madalyn S. Blondes, Brian W. Stewart, Rosemary C Capo, J. Alexandra Hakala, Avner Vengosh, William D Burgos, Nathaniel R. Warner
Ion exchange processes for CO2 mineralization using industrial waste streams: Pilot plant demonstration and life cycle assessment
An attractive technique for removing CO2 from the environment is sequestration within stable carbonate solids (e. g., calcite). However, continuous addition of alkalinity is required to achieve favorable conditions for carbonate precipitation (pH>8) from aqueous streams containing dissolved CO2 (pH<4.5) and Ca2+ ions. In this study, a pH-swing process using ion exchange was demonstrated to process
Authors
Steven Bustillos, Mario Christofides, Bonnie McDevitt, Madalyn S. Blondes, Ryan J. McAleer, Aaron M. Jubb, Bu Wang, Gaurav Sant, Dante Simonetti
Geologic carbon management options for the North Atlantic-Appalachian Region
IntroductionThe U.S. Geological Survey (USGS) North Atlantic-Appalachian Region is developing the regionwide capacity to provide timely science support for decision-makers attempting to enhance carbon removal, sequestration, and emissions mitigation to meet national atmospheric carbon reduction goals. The U.S. Environmental Protection Agency (EPA) reported that in 2021, the fourteen States and the
Authors
Peter D. Warwick, Madalyn S. Blondes, Sean T. Brennan, Steven M. Cahan, C. Özgen Karacan, Kevin D. Kroeger, Matthew D. Merrill
Dissolved organic matter within oil and gas associated wastewaters from U.S. unconventional petroleum plays: Comparisons and consequences for disposal and reuse
Wastewater generated during petroleum extraction (produced water) may contain high concentrations of dissolved organics due to their intimate association with organic-rich source rocks, expelled petroleum, and organic additives to fluids used for hydraulic fracturing of unconventional (e.g., shale) reservoirs. Dissolved organic matter (DOM) within produced water represents a challenge for treatmen
Authors
Bonnie McDevitt, Aaron M. Jubb, Matthew S. Varonka, Madalyn S. Blondes, Mark A Engle, Tanya J. Gallegos, Jenna L. Shelton
National assessment of carbon dioxide enhanced oil recovery and associated carbon dioxide retention resources — Results
In 2020, the U.S. Geological Survey (USGS) completed a probabilistic assessment of the volume of technically recoverable oil resources available if current carbon dioxide enhanced oil recovery (CO2-EOR) technologies were applied to amenable oil reservoirs underlying the onshore and State waters areas of the conterminous United States. The assessment also includes estimates of the mass of CO2 that
Authors
Peter D. Warwick, Emil D. Attanasi, Madalyn S. Blondes, Sean T. Brennan, Marc L. Buursink, Steven M. Cahan, Colin A. Doolan, Philip A. Freeman, C. Özgen Karacan, Celeste D. Lohr, Matthew D. Merrill, Ricardo A. Olea, Jenna L. Shelton, Ernie R. Slucher, Brian A. Varela
National assessment of carbon dioxide enhanced oil recovery and associated carbon dioxide retention resources — Summary
IntroductionIn 2020, the U.S. Geological Survey (USGS) completed a probabilistic assessment of the volume of technically recoverable oil resources that might be produced by using current carbon dioxide enhanced oil recovery (CO2-EOR) technologies in amenable conventional oil reservoirs underlying the onshore and State waters areas of the conterminous United States. The assessment also includes est
Authors
Peter D. Warwick, Emil D. Attanasi, Madalyn S. Blondes, Sean T. Brennan, Marc L. Buursink, Steven M. Cahan, Colin A. Doolan, Philip A. Freeman, C. Özgen Karacan, Celeste D. Lohr, Matthew D. Merrill, Ricardo A. Olea, Jenna L. Shelton, Ernie R. Slucher, Brian A. Varela
Machine learning can assign geologic basin to produced water samples using major ion geochemistry
Understanding the geochemistry of waters produced during petroleum extraction is essential to informing the best treatment and reuse options, which can potentially be optimized for a given geologic basin. Here, we used the US Geological Survey’s National Produced Waters Geochemical Database (PWGD) to determine if major ion chemistry could be used to classify accurately a produced water sample to a
Authors
Jenna L. Shelton, Aaron M. Jubb, Samuel Saxe, Emil D. Attanasi, Alexei Milkov, Mark A Engle, Philip A. Freeman, Christopher Shaffer, Madalyn S. Blondes
Potential Pb+2 mobilization, transport, and sequestration in shallow aquifers impacted by multiphase CO2 leakage: A natural analogue study from the Virgin River Basin in Southwest Utah
Geological carbon sequestration (GCS) is necessary to help meet emissions reduction goals, but groundwater contamination may occur if CO2 and/or brine were to leak out of deep storage formations into the shallow subsurface. For this study, a natural analogue was investigated: in the Virgin River Basin of southwest Utah, water with moderate salinity and high CO2 concentrations is leaking upward int
Authors
Michelle R. Plampin, Madalyn S. Blondes, Eric Sonnenthal, William H. Craddock
Utica shale play oil and gas brines: Geochemistry and factors influencing wastewater management
The Utica and Marcellus Shale Plays in the Appalachian Basin are the fourth and first largest natural gas producing plays in the United States, respectively. Hydrocarbon production generates large volumes of brine (“produced water”) that must be disposed of, treated, or reused. Though Marcellus brines have been studied extensively, there are few studies from the Utica Shale Play. This study presen
Authors
Madalyn S. Blondes, Jenna L. Shelton, Mark A Engle, Jason Trembly, Colin A. Doolan, Aaron M. Jubb, Jessica Chenault, Elisabeth L. Rowan, Ralph J. Haefner, Brian E. Mailot
Four-dimensional thermal evolution of the East African Orogen: Accessory phase petrochronology of crustal profiles through the Tanzanian Craton and Mozambique Belt, northeastern Tanzania
U–Pb petrochronology of deep crustal xenoliths and outcrops across northeastern Tanzania track the thermal evolution of the Mozambique Belt and Tanzanian Craton following the Neoproterozoic East African Orogeny (EAO) and subsequent Neogene rifting. At the craton margin, the upper–middle crust record thermal quiescence since the Archean (2.8–2.5 Ga zircon, rutile, and apatite in granite and amphibo
Authors
Francisco E. Apen, Roberta L. Rudnick, John M. Cottle, Andrew R.C. Kylander-Clark, Madalyn S. Blondes, Phil Piccoli, Gareth Seward
Repetitive sampling and control threshold improve 16S rRNA results from produced waters associated with hydraulically fractured shales
Sequencing microbial DNA from deep subsurface environments is complicated by a number of issues ranging from contamination to non-reproducible results. Many samples obtained from these environments - which are of great interest due to the potential to stimulate microbial methane generation - contain low biomass. Therefore, samples from these environments are difficult to study as sequencing result
Authors
Jenna L. Shelton, Elliott Barnhart, Leslie F. Ruppert, Aaron M. Jubb, Madalyn S. Blondes, Christina A. DeVera
Modeling geologic sequestration of carbon dioxide in a deep saline carbonate reservoir with TOUGH2–ChemPlugin, a new tool for reactive transport modeling
This paper outlines the development and demonstration of a new tool, TOUGH2–ChemPlugin (T2CPI) for predicting rock–water–CO2 interaction following injection of supercritical CO2 into a heterogeneous carbonate system. Specifically, modeling capabilities of TOUGH2, which examines multiphase flow and supercritical CO2 behavior, were combined with the geochemical modeling capabilities of The Geochemis
Authors
Tina L. Roberts-Ashby, Peter M. Berger, Jeffrey A. Cunningham, Ram Kumar, Madalyn S. Blondes
Non-USGS Publications**
Blondes, M.S., Brandon, M.T., Reiners, P.W., Kita, N.T., Page, F.Z., 2012. Generation of forsteritic olivine (Fo99.8) by subsolidus oxidation in basaltic flows: Journal of Petrology, v. 53, p. 971-984.
Blondes, M.S., 2008. Single Eruption Temporal-Compositional Variation in Basalts: Ph.D. Thesis, Yale University.
Blondes, M.S., Reiners, P.W., Ducea, M.N., Singer, B.S., Chesley, J., 2008. Temporal-compositional trends over short and long time-scales in basalts of the Big Pine Volcanic Field, CA: Earth and Planetary Science Letters, v. 269, p. 140-154.
Blondes, M.S., Reiners, P.W., Edwards, B.R., Biscontini, A., 2007. Dating young basalt eruptions by (U-Th)/He on xenolithic zircons: Geology, v. 35, no. 1, p. 17-20.
**Disclaimer: The views expressed in Non-USGS publications are those of the author and do not represent the views of the USGS, Department of the Interior, or the U.S. Government.
U.S. Geological Survey National Produced Waters Geochemical Database (ver. 3.0, December 2023) Viewer
The U.S. Geological Survey National Produced Waters Geochemical Database Viewer (ver. 3.0) provides access to an updated compilation of geochemical and related information for water from oil and gas wells in the United States. The information includes identification and location information, well descriptions, dates, rock properties, physical properties of the water, organic chemistry and more.
CO2assessment R package
The CO2assessment package provides R functions and a Shiny application for CO2 storage resource assessment using 2013 USGS National Assessment of Geologic Carbon Dioxide Storage Resources methodology. Tools to facilitate estimation of CO2 storage resources in geologic formations include volumetric and thermodynamic equations and Monte Carlo simulation. The set of input parameters define probabilit