Mark A Engle (Former Employee)
Science and Products
Geochemistry and microbiology data collected to study the effects of oil and gas wastewater dumping on arid lands in New Mexico
The Permian Basin, straddling New Mexico and Texas, is one of the most productive oil and gas (OG) provinces in the United States. OG production yields large volumes of wastewater that contain elevated concentrations of major ions including salts (also referred to as brines), and trace organic and inorganic constituents. These OG wastewaters pose unknown environmental health risks...
By
Water Resources Mission Area, Energy Resources Program, Environmental Health Program, Columbia Environmental Research Center, Geology, Energy & Minerals Science Center, Eastern Energy and Environmental Laboratory (EEEL), Reston Biogeochemical Processes in Groundwater Laboratory, Reston Microbiology Laboratory
Absorbance and Fluorescence Excitation-Emission Matrix Data for Produced Waters from Oil and Gas Producing Basins in the United States
Waters co-produced during petroleum extraction are normally considered wastes but are also possible resources, especially in water-stressed regions. Produced waters can be chemically complex. High salinity, naturally occurring radioactive materials, and organic substances derived from the producing formation can complicate treatment processes. Rapid screening methods to characterize...
Codebook vectors and predicted rare earth potential from a trained emergent self-organizing map displaying multivariate topology of geochemical and reservoir temperature data from produced and geothermal waters of the United States
This data release consists of three products relating to a 82 x 50 neuron Emergent Self-Organizing Map (ESOM), which describes the multivariate topology of reservoir temperature and geochemical data for 190 samples of produced and geothermal waters from across the United States. Variables included in the ESOM are coordinates derived from reservoir temperature and concentration of Sc, Nd...
Codebook vectors from a trained emergent self-organizing map displaying multivariate topology of geochemical and reservoir temperature data from produced and geothermal waters of the United States
This data matrix contains the codebook vectors for a 82 x 50 neuron Emergent Self-Organizing Map which describes the multivariate topology of reservoir temperature and geochemical data for 190 samples of produced and geothermal waters from across the United States. Variables included are coordinates derived from reservoir temperature and concentration of Sc, Nd, Pr, Tb, Lu, Gd, Tm, Ce...
Chemical and isotopic composition of produced waters from the lower Eagle Ford Group, south-central Texas
This dataset contains chemical and isotopic data from 39 produced water samples collected from sealed separators containing water from horizontal hydrocarbon wells in the lower Eagle Ford Group. The samples were collected from Lavaca and Gonzales counties, Texas in December, 2015. All wells had been in production for longer than 6 months and had produced more than 10,000 barrels (~160...
Data on Produced Water Quality and Quantities from Hydraulically Fractured Williston Basin Oil Wells
This dataset contains compositional data on 17 produced water samples from hydraulically fractured unconventional oil wells completed in the Middle Bakken and Three Forks Formations. The oil wells are located in five different wellfields across the Williston Basin. Specific gravity, conductivity, temperature, pH and oxidation-reduction potential for each sample was measured in the field...
Geochemistry of Utica Shale Play and other Appalachian produced waters
Citation Note: These data were collected as part of a research study published in Environmental Science and Technology. Please reference the following paper when citing these data. Blondes, M.S., Shelton, J.L., Engle, M.A., Trembly, J.P., Doolan, C.A., Jubb, A.M., Chenault, J.M., Rowan, E.L., Haefner, R.J., and Mailot, B.E., 2020, Utica Shale Play Oil and Gas Brines: Geochemistry and...
Geochemistry Data from Samples Collected in 2015-2017 to study an OG wastewater spill in Blacktail Creek, North Dakota
These metadata sets present the comprehensive geochemical composition of solid and water samples from the site of a 11.4ML (million liters) wastewater spill discovered in January, 2015. Analyses of a pipeline sample (analyses of select analytes), supplied by the North Dakota Department of Health are also included. The spill was near Blacktail Creek, north of Williston, ND. The leak was...
Direct Trace Element Determination in Oil and Gas Produced Waters with Inductively Coupled Plasma - Optical Emission Spectrometry (ICP-OES): Advantages of High Salinity Tolerance (2019)
Waters co-produced during petroleum extraction are the largest waste stream from oil and gas development. Reuse or disposal of these waters is difficult due both to their high salinities, which can greatly exceed 35 g/L (seawater equivalent), and also the sheer volume of wastewater generated, which is estimated at nearly 900 billion gallons per year across the United States. Beyond...
U.S. Geological Survey National Produced Waters Geochemical Database v2.3 (superseded by ver. 3.0, December 2023)
Please note: This product is superseded by the ver. 3.0, December 2023 product provided within the 'Data' tab below. During hydrocarbon production, water is typically co-produced from the geologic formations producing oil and gas. Understanding the composition of these produced waters is important to help investigate the regional hydrogeology, the source of the water, the efficacy of...
Site identification, location, temperature, and CO2 flux from diffuse emission measurement at the Tiptop coal mine fire, Kentucky (2009)
The dataset consists of site identification, location, temperature and CO2 flux from diffuse emission measurement at the Tiptop fire. A total of 40 CO2 flux measurements were made at 27 locations, including five points (seven measurements) outside of the active coal fire area.
Filter Total Items: 64
Illegal dumping of oil and gas wastewater alters arid soil microbial communities
The Permian Basin, underlying southeast New Mexico and west Texas, is one of the most productive oil and gas (OG) provinces in the United States. Oil and gas production yields large volumes of wastewater with complex chemistries, and the environmental health risks posed by these OG wastewaters on sensitive desert ecosystems are poorly understood. Starting in November 2017, 39 illegal...
Authors
Mitra Kashani, Mark A Engle, Douglas B. Kent, Terry G. Gregston, Isabelle M. Cozzarelli, Adam Mumford, Matthew S. Varonka, Cassandra Rashan Harris, Denise M. Akob
Dissolved organic matter within oil and gas associated wastewaters from U.S. unconventional petroleum plays: Comparisons and consequences for disposal and reuse
Wastewater generated during petroleum extraction (produced water) may contain high concentrations of dissolved organics due to their intimate association with organic-rich source rocks, expelled petroleum, and organic additives to fluids used for hydraulic fracturing of unconventional (e.g., shale) reservoirs. Dissolved organic matter (DOM) within produced water represents a challenge...
Authors
Bonnie McDevitt, Aaron M. Jubb, Matthew S. Varonka, Madalyn S. Blondes, Mark A Engle, Tanya J. Gallegos, Jenna L. Shelton
Machine learning can assign geologic basin to produced water samples using major ion geochemistry
Understanding the geochemistry of waters produced during petroleum extraction is essential to informing the best treatment and reuse options, which can potentially be optimized for a given geologic basin. Here, we used the US Geological Survey’s National Produced Waters Geochemical Database (PWGD) to determine if major ion chemistry could be used to classify accurately a produced water...
Authors
Jenna L. Shelton, Aaron M. Jubb, Samuel Saxe, Emil D. Attanasi, Alexei Milkov, Mark A Engle, Philip A. Freeman, Christopher Shaffer, Madalyn S. Blondes
Insights on geochemical, isotopic, and volumetric compositions of produced water from hydraulically fractured Williston Basin oil wells
Tracing produced water origins from wells hydraulically fractured with freshwater-based fluids is sometimes predicated on assumptions that (1) each geological formation contains compositionally unique brine and (2) produced water from recently hydraulically fractured wells resembles fresher meteoric water more so than produced water from older wells. These assumptions are not valid in...
Authors
Tanya J. Gallegos, Colin A. Doolan, Rodney R. Caldwell, Mark A Engle, Matthew S. Varonka, Justin E. Birdwell, Glenn D. Jolly, Tyler B. Coplen, Thomas A. Oliver
By
Utica shale play oil and gas brines: Geochemistry and factors influencing wastewater management
The Utica and Marcellus Shale Plays in the Appalachian Basin are the fourth and first largest natural gas producing plays in the United States, respectively. Hydrocarbon production generates large volumes of brine (“produced water”) that must be disposed of, treated, or reused. Though Marcellus brines have been studied extensively, there are few studies from the Utica Shale Play. This...
Authors
Madalyn S. Blondes, Jenna L. Shelton, Mark A Engle, Jason Trembly, Colin A. Doolan, Aaron M. Jubb, Jessica Chenault, Elisabeth L. Rowan, Ralph J. Haefner, Brian E. Mailot
Geochemical and geophysical indicators of oil and gas wastewater can trace potential exposure pathways following releases to surface waters
Releases of oil and gas (OG) wastewaters can have complex effects on stream-water quality and downstream organisms, due to sediment-water interactions and groundwater/surface water exchange. Previously, elevated concentrations of sodium (Na), chloride (Cl), barium (Ba), strontium (Sr), and lithium (Li), and trace hydrocarbons were determined to be key markers of OG wastewater releases...
Authors
Isabelle M. Cozzarelli, Douglas B. Kent, Martin A. Briggs, Mark A Engle, Adam Benthem, Katherine Skalak, Adam Mumford, Jeanne B. Jaeschke, Aida Farag, John W. Lane, Denise M. Akob
Origin and geochemistry of formation waters from the lower Eagle Ford Group, Gulf Coast Basin, south central Texas
The lower Eagle Ford Group (LEFG) is one of the most productive continuous hydrocarbon plays in the United States but few associated produced waters data and minimal interpretation have been published. This effort focuses on results from compositional and isotopic data from 39 produced water samples collected from horizontal wells producing from the LEFG in south central Texas. The depth...
Authors
Mark A Engle, Colin A. Doolan, Janet K. Pitman, Matthew S. Varonka, Jessica Chenault, William H. Orem, Peter B. McMahon, Aaron M. Jubb
Compositional analysis of formation water geochemistry and microbiology of commercial and carbon dioxide-rich wells in the southwestern United States
Studies of naturally occurring subsurface carbon dioxide (CO2) accumulations can provide useful information for potential CO2 injection projects; however, the microbial communities and formation water geochemistry of most reservoirs are understudied. Formation water and microbial biomass were sampled at four CO2-rich reservoir sites: two within Bravo Dome, a commercial CO2 field in New...
Authors
Jenna L. Shelton, Robert S. Andrews, Denise M. Akob, Christina A. DeVera, Adam C. Mumford, Mark Engle, Michelle R. Plampin, Sean T. Brennan
Direct trace element determination in oil and gas produced waters with inductively coupled plasma - Optical emission spectrometry (ICP-OES): Advantages of high salinity tolerance
Waters co-produced during petroleum extraction are the largest waste stream from oil and gas development. Reuse or disposal of these waters is difficult due to their high salinities and the sheer volumes generated. Produced waters may also contain valuable mineral commodities. While an understanding of produced water trace element composition is required for evaluating the associated...
Authors
Aaron M. Jubb, Mark Engle, Jessica Chenault, Madalyn Blondes, Cloelle G. Danforth, Colin Doolan, Tanya Gallegos, Dan Mueller, Jenna Shelton
Chemical composition of formation water in shale and tight reservoirs: A basin-scale perspective
No abstract available.
Authors
Yousif Kharaka, Kathleen Gans, Elisabeth Rowan, James Thordsen, Christopher H. Conaway, Madalyn S. Blondes, Mark A. Engle
Geochemical data for produced waters from conventional and unconventional oil and gas wells: Results from Colorado, USA
Geochemical data for more than 120,000 oil and natural gas wells from the major sedimentary basins in the USA are listed in the USGS National Produced Waters Geochemical Database [1]. In this summary, we report and discuss the geochemical data on produced waters obtained from published literature and the Colorado Oil and Gas Conservation Commission (COGCC) from close to 4,000 new oil and...
Authors
Yousif Kharaka, Kathleen Gans, James Thordsen, Madalyn S. Blondes, Mark A Engle
Self-organizing maps for compositional data: coal combustion products of a Wyoming power plant
A self-organizing map (SOM) is a non-linear projection of a D-dimensional data set, where the distance among observations is approximately preserved on to a lower dimensional space. The SOM arranges multivariate data based on their similarity to each other by allowing pattern recognition leading to easier interpretation of higher dimensional data. The SOM algorithm allows for selection...
Authors
Josep M. Martín-Fernández, Mark A. Engle, Leslie F. Ruppert, Ricardo A. Olea
Science and Products
Geochemistry and microbiology data collected to study the effects of oil and gas wastewater dumping on arid lands in New Mexico
The Permian Basin, straddling New Mexico and Texas, is one of the most productive oil and gas (OG) provinces in the United States. OG production yields large volumes of wastewater that contain elevated concentrations of major ions including salts (also referred to as brines), and trace organic and inorganic constituents. These OG wastewaters pose unknown environmental health risks...
By
Water Resources Mission Area, Energy Resources Program, Environmental Health Program, Columbia Environmental Research Center, Geology, Energy & Minerals Science Center, Eastern Energy and Environmental Laboratory (EEEL), Reston Biogeochemical Processes in Groundwater Laboratory, Reston Microbiology Laboratory
Absorbance and Fluorescence Excitation-Emission Matrix Data for Produced Waters from Oil and Gas Producing Basins in the United States
Waters co-produced during petroleum extraction are normally considered wastes but are also possible resources, especially in water-stressed regions. Produced waters can be chemically complex. High salinity, naturally occurring radioactive materials, and organic substances derived from the producing formation can complicate treatment processes. Rapid screening methods to characterize...
Codebook vectors and predicted rare earth potential from a trained emergent self-organizing map displaying multivariate topology of geochemical and reservoir temperature data from produced and geothermal waters of the United States
This data release consists of three products relating to a 82 x 50 neuron Emergent Self-Organizing Map (ESOM), which describes the multivariate topology of reservoir temperature and geochemical data for 190 samples of produced and geothermal waters from across the United States. Variables included in the ESOM are coordinates derived from reservoir temperature and concentration of Sc, Nd...
Codebook vectors from a trained emergent self-organizing map displaying multivariate topology of geochemical and reservoir temperature data from produced and geothermal waters of the United States
This data matrix contains the codebook vectors for a 82 x 50 neuron Emergent Self-Organizing Map which describes the multivariate topology of reservoir temperature and geochemical data for 190 samples of produced and geothermal waters from across the United States. Variables included are coordinates derived from reservoir temperature and concentration of Sc, Nd, Pr, Tb, Lu, Gd, Tm, Ce...
Chemical and isotopic composition of produced waters from the lower Eagle Ford Group, south-central Texas
This dataset contains chemical and isotopic data from 39 produced water samples collected from sealed separators containing water from horizontal hydrocarbon wells in the lower Eagle Ford Group. The samples were collected from Lavaca and Gonzales counties, Texas in December, 2015. All wells had been in production for longer than 6 months and had produced more than 10,000 barrels (~160...
Data on Produced Water Quality and Quantities from Hydraulically Fractured Williston Basin Oil Wells
This dataset contains compositional data on 17 produced water samples from hydraulically fractured unconventional oil wells completed in the Middle Bakken and Three Forks Formations. The oil wells are located in five different wellfields across the Williston Basin. Specific gravity, conductivity, temperature, pH and oxidation-reduction potential for each sample was measured in the field...
Geochemistry of Utica Shale Play and other Appalachian produced waters
Citation Note: These data were collected as part of a research study published in Environmental Science and Technology. Please reference the following paper when citing these data. Blondes, M.S., Shelton, J.L., Engle, M.A., Trembly, J.P., Doolan, C.A., Jubb, A.M., Chenault, J.M., Rowan, E.L., Haefner, R.J., and Mailot, B.E., 2020, Utica Shale Play Oil and Gas Brines: Geochemistry and...
Geochemistry Data from Samples Collected in 2015-2017 to study an OG wastewater spill in Blacktail Creek, North Dakota
These metadata sets present the comprehensive geochemical composition of solid and water samples from the site of a 11.4ML (million liters) wastewater spill discovered in January, 2015. Analyses of a pipeline sample (analyses of select analytes), supplied by the North Dakota Department of Health are also included. The spill was near Blacktail Creek, north of Williston, ND. The leak was...
Direct Trace Element Determination in Oil and Gas Produced Waters with Inductively Coupled Plasma - Optical Emission Spectrometry (ICP-OES): Advantages of High Salinity Tolerance (2019)
Waters co-produced during petroleum extraction are the largest waste stream from oil and gas development. Reuse or disposal of these waters is difficult due both to their high salinities, which can greatly exceed 35 g/L (seawater equivalent), and also the sheer volume of wastewater generated, which is estimated at nearly 900 billion gallons per year across the United States. Beyond...
U.S. Geological Survey National Produced Waters Geochemical Database v2.3 (superseded by ver. 3.0, December 2023)
Please note: This product is superseded by the ver. 3.0, December 2023 product provided within the 'Data' tab below. During hydrocarbon production, water is typically co-produced from the geologic formations producing oil and gas. Understanding the composition of these produced waters is important to help investigate the regional hydrogeology, the source of the water, the efficacy of...
Site identification, location, temperature, and CO2 flux from diffuse emission measurement at the Tiptop coal mine fire, Kentucky (2009)
The dataset consists of site identification, location, temperature and CO2 flux from diffuse emission measurement at the Tiptop fire. A total of 40 CO2 flux measurements were made at 27 locations, including five points (seven measurements) outside of the active coal fire area.
Filter Total Items: 64
Illegal dumping of oil and gas wastewater alters arid soil microbial communities
The Permian Basin, underlying southeast New Mexico and west Texas, is one of the most productive oil and gas (OG) provinces in the United States. Oil and gas production yields large volumes of wastewater with complex chemistries, and the environmental health risks posed by these OG wastewaters on sensitive desert ecosystems are poorly understood. Starting in November 2017, 39 illegal...
Authors
Mitra Kashani, Mark A Engle, Douglas B. Kent, Terry G. Gregston, Isabelle M. Cozzarelli, Adam Mumford, Matthew S. Varonka, Cassandra Rashan Harris, Denise M. Akob
Dissolved organic matter within oil and gas associated wastewaters from U.S. unconventional petroleum plays: Comparisons and consequences for disposal and reuse
Wastewater generated during petroleum extraction (produced water) may contain high concentrations of dissolved organics due to their intimate association with organic-rich source rocks, expelled petroleum, and organic additives to fluids used for hydraulic fracturing of unconventional (e.g., shale) reservoirs. Dissolved organic matter (DOM) within produced water represents a challenge...
Authors
Bonnie McDevitt, Aaron M. Jubb, Matthew S. Varonka, Madalyn S. Blondes, Mark A Engle, Tanya J. Gallegos, Jenna L. Shelton
Machine learning can assign geologic basin to produced water samples using major ion geochemistry
Understanding the geochemistry of waters produced during petroleum extraction is essential to informing the best treatment and reuse options, which can potentially be optimized for a given geologic basin. Here, we used the US Geological Survey’s National Produced Waters Geochemical Database (PWGD) to determine if major ion chemistry could be used to classify accurately a produced water...
Authors
Jenna L. Shelton, Aaron M. Jubb, Samuel Saxe, Emil D. Attanasi, Alexei Milkov, Mark A Engle, Philip A. Freeman, Christopher Shaffer, Madalyn S. Blondes
Insights on geochemical, isotopic, and volumetric compositions of produced water from hydraulically fractured Williston Basin oil wells
Tracing produced water origins from wells hydraulically fractured with freshwater-based fluids is sometimes predicated on assumptions that (1) each geological formation contains compositionally unique brine and (2) produced water from recently hydraulically fractured wells resembles fresher meteoric water more so than produced water from older wells. These assumptions are not valid in...
Authors
Tanya J. Gallegos, Colin A. Doolan, Rodney R. Caldwell, Mark A Engle, Matthew S. Varonka, Justin E. Birdwell, Glenn D. Jolly, Tyler B. Coplen, Thomas A. Oliver
By
Utica shale play oil and gas brines: Geochemistry and factors influencing wastewater management
The Utica and Marcellus Shale Plays in the Appalachian Basin are the fourth and first largest natural gas producing plays in the United States, respectively. Hydrocarbon production generates large volumes of brine (“produced water”) that must be disposed of, treated, or reused. Though Marcellus brines have been studied extensively, there are few studies from the Utica Shale Play. This...
Authors
Madalyn S. Blondes, Jenna L. Shelton, Mark A Engle, Jason Trembly, Colin A. Doolan, Aaron M. Jubb, Jessica Chenault, Elisabeth L. Rowan, Ralph J. Haefner, Brian E. Mailot
Geochemical and geophysical indicators of oil and gas wastewater can trace potential exposure pathways following releases to surface waters
Releases of oil and gas (OG) wastewaters can have complex effects on stream-water quality and downstream organisms, due to sediment-water interactions and groundwater/surface water exchange. Previously, elevated concentrations of sodium (Na), chloride (Cl), barium (Ba), strontium (Sr), and lithium (Li), and trace hydrocarbons were determined to be key markers of OG wastewater releases...
Authors
Isabelle M. Cozzarelli, Douglas B. Kent, Martin A. Briggs, Mark A Engle, Adam Benthem, Katherine Skalak, Adam Mumford, Jeanne B. Jaeschke, Aida Farag, John W. Lane, Denise M. Akob
Origin and geochemistry of formation waters from the lower Eagle Ford Group, Gulf Coast Basin, south central Texas
The lower Eagle Ford Group (LEFG) is one of the most productive continuous hydrocarbon plays in the United States but few associated produced waters data and minimal interpretation have been published. This effort focuses on results from compositional and isotopic data from 39 produced water samples collected from horizontal wells producing from the LEFG in south central Texas. The depth...
Authors
Mark A Engle, Colin A. Doolan, Janet K. Pitman, Matthew S. Varonka, Jessica Chenault, William H. Orem, Peter B. McMahon, Aaron M. Jubb
Compositional analysis of formation water geochemistry and microbiology of commercial and carbon dioxide-rich wells in the southwestern United States
Studies of naturally occurring subsurface carbon dioxide (CO2) accumulations can provide useful information for potential CO2 injection projects; however, the microbial communities and formation water geochemistry of most reservoirs are understudied. Formation water and microbial biomass were sampled at four CO2-rich reservoir sites: two within Bravo Dome, a commercial CO2 field in New...
Authors
Jenna L. Shelton, Robert S. Andrews, Denise M. Akob, Christina A. DeVera, Adam C. Mumford, Mark Engle, Michelle R. Plampin, Sean T. Brennan
Direct trace element determination in oil and gas produced waters with inductively coupled plasma - Optical emission spectrometry (ICP-OES): Advantages of high salinity tolerance
Waters co-produced during petroleum extraction are the largest waste stream from oil and gas development. Reuse or disposal of these waters is difficult due to their high salinities and the sheer volumes generated. Produced waters may also contain valuable mineral commodities. While an understanding of produced water trace element composition is required for evaluating the associated...
Authors
Aaron M. Jubb, Mark Engle, Jessica Chenault, Madalyn Blondes, Cloelle G. Danforth, Colin Doolan, Tanya Gallegos, Dan Mueller, Jenna Shelton
Chemical composition of formation water in shale and tight reservoirs: A basin-scale perspective
No abstract available.
Authors
Yousif Kharaka, Kathleen Gans, Elisabeth Rowan, James Thordsen, Christopher H. Conaway, Madalyn S. Blondes, Mark A. Engle
Geochemical data for produced waters from conventional and unconventional oil and gas wells: Results from Colorado, USA
Geochemical data for more than 120,000 oil and natural gas wells from the major sedimentary basins in the USA are listed in the USGS National Produced Waters Geochemical Database [1]. In this summary, we report and discuss the geochemical data on produced waters obtained from published literature and the Colorado Oil and Gas Conservation Commission (COGCC) from close to 4,000 new oil and...
Authors
Yousif Kharaka, Kathleen Gans, James Thordsen, Madalyn S. Blondes, Mark A Engle
Self-organizing maps for compositional data: coal combustion products of a Wyoming power plant
A self-organizing map (SOM) is a non-linear projection of a D-dimensional data set, where the distance among observations is approximately preserved on to a lower dimensional space. The SOM arranges multivariate data based on their similarity to each other by allowing pattern recognition leading to easier interpretation of higher dimensional data. The SOM algorithm allows for selection...
Authors
Josep M. Martín-Fernández, Mark A. Engle, Leslie F. Ruppert, Ricardo A. Olea