Pesticides and Water Quality Active
Pesticides are chemicals designed to kill pests, including insects (insecticides), weeds (herbicides), and fungi (fungicides). The USGS assesses the occurrence and behavior of pesticides in streams, lakes, and groundwater and the potential for pesticides to contaminate our drinking-water supplies or harm aquatic ecosystems.
NOTICE: The USGS agricultural pesticide-use estimates are supported by funding from the USGS National Water Quality Program for the purpose of better understanding pesticides in freshwater and their impact on water availability nationwide. The USGS recently updated its plan to publish pesticide-use estimates. Final annual pesticide-use estimates, for approximately 400 compounds, from 2018-22 will be published in 2025. After that, preliminary estimates will be published annually and later updated with final estimates once the USDA Census of Agriculture is released (every five years). The total number of pesticides included in the analysis will fluctuate annually, based on data availability from our pesticide use survey contract provider. (Updated February 27, 2024)
Pesticides are used in agriculture, in homes and businesses, on lawns and gardens, along roads, in recreational areas, and on pets and livestock. There are hundreds of different pesticide chemicals in use in the United States. In 2007, about 390 million kilograms (430,000 tons) of pesticides, including herbicides, insecticides, and fungicides, were used in the United States. Pesticides released into the environment for agricultural and nonagricultural purposes can contaminate surface water and groundwater, which are critical sources of drinking water.
The USGS, through its National Water Quality Program, researches numerous aspects of pesticides and water quality, and has developed maps, graphics, and tools to aid in understanding where pesticides occur, at what concentrations, and potential consequences.
- Pesticide Use: The tables, maps, and graphs provided on this web site provide estimates of agricultural pesticide use in the conterminous United States for hundreds of pesticides.
- Trends in Pesticide Occurrence in Streams: Use the online tool to view a national maps of trends in pesticide concentrations in streams.
- Concentrations of Pesticides in Water of Potential Human-Health Concern: This searchable online database provides Health-Based Screening Levels (HBSLs) for hundreds of chemicals, including pesticides and degradates.
- Pesticide Toxicity to Aquatic Organisms: The Pesticide Toxicity Index (PTI) can be used to assess the potential toxicity of pesticide mixtures in water to freshwater aquatic organisms. Benchmarks also are available for pesticides in sediment.
- Pesticides and Stream Ecology: The Regional Stream Quality Assessment (RSQA) is assessing how chemical stressors, such as pesticides and nutrients, and physical stressors, such as disturbed streambanks and sedimentation, are affecting the aquatic organisms that live in small streams across the United States.
- Pesticides and Lake Sediment: Many pesticides dissolve in water, but some pesticides, like DDT and chlordane, adhere to sediment and persist for years in the bed sediments of stream and lakes, recording the history of contaminant use in watershed.
Learn more about USGS research on pesticides and related water-quality topics at the web pages below.
Below, you'll find links to data sets developed for investigation of pesticides.
Below, you’ll find the latest in peer-reviewed journal articles and USGS reports on pesticides and water quality. For more publications on this topic, search the USGS Publications Warehouse.
Complex mixtures of dissolved pesticides show potential aquatic toxicity in a synoptic study of Midwestern U.S. streams
Complex mixtures of Pesticides in Midwest U.S. streams indicated by POCIS time-integrating samplers
Similarities and differences in occurrence and temporal fluctuations in glyphosate and atrazine in small Midwestern streams (USA) during the 2013 growing season
Prediction of pesticide toxicity in Midwest streams
Development and application of freshwater sediment-toxicity benchmarks for currently used pesticides
Pesticide Toxicity Index: a tool for assessing potential toxicity of pesticide mixtures to freshwater aquatic organisms
Watershed Regressions for Pesticides (WARP) models for predicting stream concentrations of multiple pesticides
Contaminants in stream sediments from seven United States metropolitan areas: part I: distribution in relation to urbanization
Contaminants in stream sediments from seven United States metropolitan areas: part II—sediment toxicity to the amphipod Hyalella azteca and the midge Chironomus dilutus
Occurrence and potential sources of pyrethroid insecticides in stream sediments from seven U.S. metropolitan areas
Watershed regressions for pesticides (warp) models for predicting atrazine concentrations in Corn Belt streams
USGS Environmental health science strategy: providing environmental health science for a changing world: Public review release
Pesticide science in the news! Read recent highlights.
- Overview
Pesticides are chemicals designed to kill pests, including insects (insecticides), weeds (herbicides), and fungi (fungicides). The USGS assesses the occurrence and behavior of pesticides in streams, lakes, and groundwater and the potential for pesticides to contaminate our drinking-water supplies or harm aquatic ecosystems.
NOTICE: The USGS agricultural pesticide-use estimates are supported by funding from the USGS National Water Quality Program for the purpose of better understanding pesticides in freshwater and their impact on water availability nationwide. The USGS recently updated its plan to publish pesticide-use estimates. Final annual pesticide-use estimates, for approximately 400 compounds, from 2018-22 will be published in 2025. After that, preliminary estimates will be published annually and later updated with final estimates once the USDA Census of Agriculture is released (every five years). The total number of pesticides included in the analysis will fluctuate annually, based on data availability from our pesticide use survey contract provider. (Updated February 27, 2024)
Pesticides are used in agriculture, in homes and businesses, on lawns and gardens, along roads, in recreational areas, and on pets and livestock. There are hundreds of different pesticide chemicals in use in the United States. In 2007, about 390 million kilograms (430,000 tons) of pesticides, including herbicides, insecticides, and fungicides, were used in the United States. Pesticides released into the environment for agricultural and nonagricultural purposes can contaminate surface water and groundwater, which are critical sources of drinking water.
The USGS, through its National Water Quality Program, researches numerous aspects of pesticides and water quality, and has developed maps, graphics, and tools to aid in understanding where pesticides occur, at what concentrations, and potential consequences.
- Pesticide Use: The tables, maps, and graphs provided on this web site provide estimates of agricultural pesticide use in the conterminous United States for hundreds of pesticides.
- Trends in Pesticide Occurrence in Streams: Use the online tool to view a national maps of trends in pesticide concentrations in streams.
- Concentrations of Pesticides in Water of Potential Human-Health Concern: This searchable online database provides Health-Based Screening Levels (HBSLs) for hundreds of chemicals, including pesticides and degradates.
- Pesticide Toxicity to Aquatic Organisms: The Pesticide Toxicity Index (PTI) can be used to assess the potential toxicity of pesticide mixtures in water to freshwater aquatic organisms. Benchmarks also are available for pesticides in sediment.
- Pesticides and Stream Ecology: The Regional Stream Quality Assessment (RSQA) is assessing how chemical stressors, such as pesticides and nutrients, and physical stressors, such as disturbed streambanks and sedimentation, are affecting the aquatic organisms that live in small streams across the United States.
- Pesticides and Lake Sediment: Many pesticides dissolve in water, but some pesticides, like DDT and chlordane, adhere to sediment and persist for years in the bed sediments of stream and lakes, recording the history of contaminant use in watershed.
- Science
Learn more about USGS research on pesticides and related water-quality topics at the web pages below.
- Data
Below, you'll find links to data sets developed for investigation of pesticides.
- Publications
Below, you’ll find the latest in peer-reviewed journal articles and USGS reports on pesticides and water quality. For more publications on this topic, search the USGS Publications Warehouse.
Filter Total Items: 116Complex mixtures of dissolved pesticides show potential aquatic toxicity in a synoptic study of Midwestern U.S. streams
Aquatic organisms in streams are exposed to pesticide mixtures that vary in composition over time in response to changes in flow conditions, pesticide inputs to the stream, and pesticide fate and degradation within the stream. To characterize mixtures of dissolved-phase pesticides and degradates in Midwestern streams, a synoptic study was conducted at 100 streams during May–August 2013. In weeklyAuthorsLisa H. Nowell, Patrick W. Moran, Travis S. Schmidt, Julia E. Norman, Naomi Nakagaki, Megan E. Shoda, Barbara Mahler, Peter C. Van Metre, Wesley W. Stone, Mark W. Sandstrom, Michelle L. HladikComplex mixtures of Pesticides in Midwest U.S. streams indicated by POCIS time-integrating samplers
The Midwest United States is an intensely agricultural region where pesticides in streams pose risks to aquatic biota, but temporal variability in pesticide concentrations makes characterization of their exposure to organisms challenging. To compensate for the effects of temporal variability, we deployed polar organic chemical integrative samplers (POCIS) in 100 small streams across the Midwest foAuthorsPeter C. Van Metre, David Alvarez, Barbara Mahler, Lisa H. Nowell, Mark W. Sandstrom, Patrick W. MoranSimilarities and differences in occurrence and temporal fluctuations in glyphosate and atrazine in small Midwestern streams (USA) during the 2013 growing season
Glyphosate and atrazine are the most intensively used herbicides in the United States. Although there is abundant spatial and temporal information on atrazine occurrence at regional scales, there are far fewer data for glyphosate, and studies that compare the two herbicides are rare. We investigated temporal patterns in glyphosate and atrazine concentrations measured weekly during the 2013 growingAuthorsBarbara Mahler, Peter C. Van Metre, Thomas E. Burley, Keith A. Loftin, Michael T. Meyer, Lisa H. NowellPrediction of pesticide toxicity in Midwest streams
The occurrence of pesticide mixtures is common in stream waters of the United States, and the impact of multiple compounds on aquatic organisms is not well understood. Watershed Regressions for Pesticides (WARP) models were developed to predict Pesticide Toxicity Index (PTI) values in unmonitored streams in the Midwest and are referred to as WARP-PTI models. The PTI is a tool for assessing the relAuthorsMegan E. Shoda, Wesley W. Stone, Lisa H. NowellDevelopment and application of freshwater sediment-toxicity benchmarks for currently used pesticides
Sediment-toxicity benchmarks are needed to interpret the biological significance of currently used pesticides detected in whole sediments. Two types of freshwater sediment benchmarks for pesticides were developed using spiked-sediment bioassay (SSB) data from the literature. These benchmarks can be used to interpret sediment-toxicity data or to assess the potential toxicity of pesticides in wholeAuthorsLisa H. Nowell, Julia E. Norman, Christopher G. Ingersoll, Patrick W. MoranPesticide Toxicity Index: a tool for assessing potential toxicity of pesticide mixtures to freshwater aquatic organisms
Pesticide mixtures are common in streams with agricultural or urban influence in the watershed. The Pesticide Toxicity Index (PTI) is a screening tool to assess potential aquatic toxicity of complex pesticide mixtures by combining measures of pesticide exposure and acute toxicity in an additive toxic-unit model. The PTI is determined separately for fish, cladocerans, and benthic invertebrates. ThiAuthorsLisa H. Nowell, Julia E. Norman, Patrick W. Moran, Jeffrey D. Martin, Wesley W. StoneWatershed Regressions for Pesticides (WARP) models for predicting stream concentrations of multiple pesticides
Watershed Regressions for Pesticides for multiple pesticides (WARP-MP) are statistical models developed to predict concentration statistics for a wide range of pesticides in unmonitored streams. The WARP-MP models use the national atrazine WARP models in conjunction with an adjustment factor for each additional pesticide. The WARP-MP models perform best for pesticides with application timing and mAuthorsWesley W. Stone, Charles G. Crawford, Robert J. GilliomContaminants in stream sediments from seven United States metropolitan areas: part I: distribution in relation to urbanization
Organic contaminants and trace elements were measured in bed sediments collected from streams in seven metropolitan study areas across the United States to assess concentrations in relation to urbanization. Polycyclic aromatic hydrocarbons, polychlorinated biphenyls, organochlorine pesticides, the pyrethroid insecticide bifenthrin, and several trace elements were significantly related to urbanizatAuthorsLisa H. Nowell, Patrick W. Moran, Robert J. Gilliom, Daniel L. Calhoun, Christopher G. Ingersoll, Nile E. Kemble, Kathryn Kuivila, Patrick J. PhillipsContaminants in stream sediments from seven United States metropolitan areas: part II—sediment toxicity to the amphipod Hyalella azteca and the midge Chironomus dilutus
Relationships between sediment toxicity and sediment chemistry were evaluated for 98 samples collected from seven metropolitan study areas across the United States. Sediment-toxicity tests were conducted with the amphipod Hyalella azteca (28 day exposures) and with the midge Chironomus dilutus (10 day exposures). Overall, 33 % of the samples were toxic to amphipods and 12 % of the samples were toAuthorsNile E. Kemble, Douglas K. Hardesty, Christopher G. Ingersoll, James L. Kunz, Paul K. Sibley, Daniel L. Calhoun, Robert J. Gilliom, Kathryn Kuivila, Lisa H. Nowell, Patrick W. MoranOccurrence and potential sources of pyrethroid insecticides in stream sediments from seven U.S. metropolitan areas
A nationally consistent approach was used to assess the occurrence and potential sources of pyrethroid insecticides in stream bed sediments from seven metropolitan areas across the United States. One or more pyrethroids were detected in almost half of the samples, with bifenthrin detected the most frequently (41%) and in each metropolitan area. Cyhalothrin, cypermethrin, permethrin, and resmethrinAuthorsKathryn Kuivila, Michelle Hladik, Christopher G. Ingersoll, Nile E. Kemble, Patrick W. Moran, Daniel L. Calhoun, Lisa H. Nowell, Robert J. GilliomWatershed regressions for pesticides (warp) models for predicting atrazine concentrations in Corn Belt streams
Watershed Regressions for Pesticides (WARP) models, previously developed for atrazine at the national scale, are improved for application to the United States (U.S.) Corn Belt region by developing region-specific models that include watershed characteristics that are influential in predicting atrazine concentration statistics within the Corn Belt. WARP models for the Corn Belt (WARP-CB) were develAuthorsWesley W. Stone, Robert J. GilliomUSGS Environmental health science strategy: providing environmental health science for a changing world: Public review release
America has an abundance of natural resources. We have bountiful clean water, fertile soil, and unrivaled national parks, wildlife refuges, and public lands. These resources enrich our lives and preserve our health and wellbeing. These resources have been maintained because of our history of respect for their value and an enduring commitment to their vigilant protection. Awareness of the social, eAuthorsPatricia R. Bright, Herbert T. Buxton, Laurie S. Balistrieri, Larry B. Barber, Francis H. Chapelle, Paul C. Cross, David P. Krabbenhoft, Geoffrey S. Plumlee, Jonathan M. Sleeman, Donald E. Tillitt, Patricia L. Toccalino, James R. Winton - News
Pesticide science in the news! Read recent highlights.