The U.S. Geological Survey laboratory for the analysis of per- and polyfluoroalkyl substances (PFAS) uses cutting-edge techniques to analyze environmental samples including tissues, plasma, water, and soils to undertake and support research projects across the country.
Andrea Tokranov
Andrea Tokranov is a Research Hydrologist in the New England Water Science Center and a Researcher in the Environmental Health Program of the Ecosystems Mission Area.
Andrea studies the fate, transport, and ecosystem exposure and effects of per- and polyfluoroalkyl substances (PFAS). She also manages the PFAS laboratory for biological matrices, which uses high resolution mass spectrometry for targeted and non-targeted analysis of PFAS.
Professional Experience
Research Hydrologist, U.S. Geological Survey, New England Water Science Center, 2023 to Present
Hydrologist, U.S. Geological Survey, New England Water Science Center, 2019 to 2023
Pathways Student (Hydrology), U.S. Geological Survey, New England Water Science Center, 2017 to 2019
Education and Certifications
Ph.D. Engineering Sciences, Harvard University, 2019
M.S. Engineering Sciences, Harvard University, 2015
B.S. Geological Sciences, A.B. Economics, Brown University, 2012
Science and Products
Research on Per- and Polyfluoroalkyl Substances (PFAS) in the New England Water Science Center
Large Fraction of Unidentified Organofluorine in a Coastal Watershed has Implications for River to Marine Ecosystems
Advanced PFAS Measurement Methods
Pilot Study of Per- and Polyfluoroalkyl Substances (PFAS) Infiltration to Shallow Groundwater Through Selected Soils in New Hampshire, 2023
Concentrations of Per- and Polyfluoroalkyl Substances (PFAS) in Lake-Bottom Sediments of Ashumet Pond on Cape Cod, Massachusetts, 2020 (ver. 2.0, February 2024)
Confirmatory Sampling for Per- and Polyfluoroalkyl Substances (PFAS) in Shallow Soils Across New Hampshire, 2022
Field-scale investigation of per- and polyfluoroalkyl substances (PFAS) leaching from shallow soils to groundwater at two sites in New Hampshire, 2021-2022
Statewide survey of shallow soil concentrations of per- and polyfluoroalkyl substances (PFAS) and related chemical and physical data across New Hampshire, 2021
Concentrations of per- and polyfluoroalkyl substances (PFAS) and related chemical and physical data at and near surface-water/groundwater boundaries on Cape Cod, Massachusetts, 2016-19
Geochemical and Geospatial Data for Per- and Polyfluoroalkyl Substances (PFAS) in Groundwater Used As a Source of Drinking Water in the Eastern United States
Assessment of Endocrine Disruption in the Shenandoah River Watershed - Chemical and Biological Data from Mobile Laboratory Fish Exposures and Other Experiments Conducted during 2014, 2015, and 2016
Poly- and perfluoalkyl substances in contaminated groundwater, Cape Cod, Massachusetts, 2014-2016
The U.S. Geological Survey laboratory for the analysis of per- and polyfluoroalkyl substances (PFAS) uses cutting-edge techniques to analyze environmental samples including tissues, plasma, water, and soils to undertake and support research projects across the country.
USGS scientists sampling groundwater near the top of the water table in a corn field in Concord, New Hampshire.
USGS scientists sampling groundwater near the top of the water table in a corn field in Concord, New Hampshire.
U.S. Geological Survey hydrologic technician collects a sample of soil affected by Per- and Polyfluoroalkyl Substances (PFAS).
U.S. Geological Survey hydrologic technician collects a sample of soil affected by Per- and Polyfluoroalkyl Substances (PFAS).
USGS scientist standing near the high-resolution mass spectrometer at the U.S. Geological Survey Eastern Ecological Science Center. The instrument will be used for analyses of PFAS in plasma and tissue samples. Any display of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government.
USGS scientist standing near the high-resolution mass spectrometer at the U.S. Geological Survey Eastern Ecological Science Center. The instrument will be used for analyses of PFAS in plasma and tissue samples. Any display of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government.
Perfluoroalkyl and polyfluoroalkyl substances in groundwater used as a source of drinking water in the eastern United States
In 2019, 254 samples were collected from five aquifer systems to evaluate per- and polyfluoroalkyl substance (PFAS) occurrence in groundwater used as a source of drinking water in the eastern United States. The samples were analyzed for 24 PFAS, major ions, nutrients, trace elements, dissolved organic carbon (DOC), volatile organic compounds (VOCs), pharmaceuticals, and tritium. Fourteen of the 24
Integrated science for the study of perfluoroalkyl and polyfluoroalkyl substances (PFAS) in the environment—A strategic science vision for the U.S. Geological Survey
Surface-water/groundwater boundaries affect seasonal PFAS concentrations and PFAA precursor transformations
Elevated concentrations of per- and polyfluoroalkyl substances (PFAS) in drinking-water supplies are a major concern for human health. It is therefore essential to understand factors that affect PFAS concentrations in surface water and groundwater and the transformation of perfluoroalkyl acid (PFAA) precursors that degrade into terminal compounds. Surface-water/groundwater exchange can occur along
Per- and polyfluoroalkyl substances (PFAS) in New Hampshire soils and biosolids
The U.S. Geological Survey, in cooperation with the New Hampshire Department of Environmental Services, is undertaking a study on per- and polyfluoroalkyl substances (PFAS) in soils and biosolids. The study will characterize PFAS concentrations in shallow soil and selected biosolids throughout the State of New Hampshire, conduct laboratory experiments to improve understanding of how mobile PFAS ar
Isolating the AFFF signature in coastal watersheds using oxidizable PFAS precursors and unexplained organofluorine
Water supplies for millions of U.S. individuals exceed maximum contaminant levels for per- and polyfluoroalkyl substances (PFAS). Contemporary and legacy use of aqueous film forming foams (AFFF) is a major contamination source. However, diverse PFAS sources are present within watersheds, making it difficult to isolate their predominant origins. Here we examine PFAS source signatures among six adja
Hillslope groundwater discharges provide localized ecosystem buffers from regional PFAS contamination in a gaining coastal stream
Emerging groundwater contaminants such as per- and polyfluoroalkyl substances (PFAS) may impact surface-water quality and groundwater-dependent ecosystems of gaining streams. Although complex near-surface hydrogeology of stream corridors challenges sampling efforts, recent advances in heat tracing of discharge zones enable efficient and informed data collection. For this study we used a combinatio
Geochemical and hydrologic factors controlling subsurface transport of poly- and perfluoroalkyl substances, Cape Cod, Massachusetts
Growing evidence that certain poly- and perfluoroalkyl substances (PFASs) are associated with negative human health effects prompted the U.S. Environmental Protection Agency to issue lifetime drinking water health advisories for perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) in 2016. Given that groundwater is a major source of drinking water, the main objective of this work was
Non-USGS Publications**
**Disclaimer: The views expressed in Non-USGS publications are those of the author and do not represent the views of the USGS, Department of the Interior, or the U.S. Government.
Science and Products
- Science
Research on Per- and Polyfluoroalkyl Substances (PFAS) in the New England Water Science Center
Per- and polyfluoroalkyl substances (PFAS) are a diverse group of over 4,000 different compounds. Since the 1940s, PFAS have been manufactured and used around the globe, including in the United States. PFAS are resistant to chemical and thermal breakdown and impart stain and water-resistance properties, making them useful for a variety of commercial applications, but also persistent in the...Large Fraction of Unidentified Organofluorine in a Coastal Watershed has Implications for River to Marine Ecosystems
A group of scientists investigated per- and polyfluoroalkyl substances (PFAS) in watersheds on Cape Cod and identified a unique signature for aqueous film forming foams (AFFF) from legacy firefighting and fire training. A combination of statistical modeling and laboratory measurements indicates that unidentified organofluorine constitutes a large fraction of PFAS in the river systems that...Advanced PFAS Measurement Methods
Environmental Health Program scientists, in collaboration with other USGS scientists, are developing complementary field and laboratory methods and capabilities to detect and quantify a range of target and nontarget per- and polyfluoroalkyl substances (PFAS) and indicator compounds at low levels (parts per trillion) in a variety of environmental matrices. The PFAS Integrated Science Team is... - Data
Pilot Study of Per- and Polyfluoroalkyl Substances (PFAS) Infiltration to Shallow Groundwater Through Selected Soils in New Hampshire, 2023
In a study conducted by the U.S. Geological Survey (USGS) and the New Hampshire Department of Environmental Services, detectable concentrations of per- and polyfluoroalkyl substances (PFAS) were found in the soil at every site despite targeting locations with no known PFAS sources (Santangelo and others, 2022). The widespread distribution of PFAS concentrations in New Hampshire has since sparked cConcentrations of Per- and Polyfluoroalkyl Substances (PFAS) in Lake-Bottom Sediments of Ashumet Pond on Cape Cod, Massachusetts, 2020 (ver. 2.0, February 2024)
Lake-bottom sediment and associated quality-control samples were collected in August 2020 from one coring location (U.S. Geological Survey station 413756070321301, ASHUMET POND, MASHPEE MI-ASHPD-0011) in Ashumet Pond downgradient from a former fire-training area on Cape Cod, Massachusetts. The core was collected to determine if per- and polyfluoroalkyl substances (PFAS) were present in the bottomConfirmatory Sampling for Per- and Polyfluoroalkyl Substances (PFAS) in Shallow Soils Across New Hampshire, 2022
Data for per- and polyfluoroalkyl substances (PFAS) and related chemical and physical characteristics are presented from 30 soil sampling locations within the State of New Hampshire. A total of 15 sites were chosen based on the results of sampling efforts published in Santangelo and others(2022). Sites with relatively high concentrations of PFAS observed during the first study were selected for reField-scale investigation of per- and polyfluoroalkyl substances (PFAS) leaching from shallow soils to groundwater at two sites in New Hampshire, 2021-2022
Per- and polyfluoroalkyl substances (PFAS) and related chemical and physical data are presented from shallow soil and groundwater at two sites in New Hampshire. The two sites, the former Brentwood Fire Training Area and White Farm, were selected because materials known to contain PFAS were used at each site. White Farm is an active farm where biosolids have been applied for several years. At the fStatewide survey of shallow soil concentrations of per- and polyfluoroalkyl substances (PFAS) and related chemical and physical data across New Hampshire, 2021
Per- and polyfluoroalkyl substances (PFAS) and related chemical and physical data are presented from 100 shallow soil sampling locations within the State of New Hampshire. Sites were randomly determined through an equal-area grid approach (Scott, 1990) targeting undisturbed areas, which included lands classified by the 2016 National Land Cover Database (Dewitz, 2019) as forested, shrubland, scrublConcentrations of per- and polyfluoroalkyl substances (PFAS) and related chemical and physical data at and near surface-water/groundwater boundaries on Cape Cod, Massachusetts, 2016-19
Groundwater, surface-water, sediment, and associated quality-control samples were collected downgradient from a former fire training area and wastewater infiltration beds on Cape Cod, Massachusetts and analyzed for per- and polyfluoroalkyl substances (PFAS). Samples were collected between July 2016 and February 2019 following U.S. Geological Survey protocols. Field parameters reported include tempGeochemical and Geospatial Data for Per- and Polyfluoroalkyl Substances (PFAS) in Groundwater Used As a Source of Drinking Water in the Eastern United States
Concentrations of inorganic constituents, dissolved organic carbon (DOC), tritium, per- and polyfluoroalkyl substances (PFAS), volatile organic compounds (VOCs), and pharmaceuticals were measured in groundwater samples collected from 254 wells in 2019 and 2020. Concentrations of inorganic constituents, DOC, VOCs, and pharmaceuticals were measured at the U.S. Geological Survey (USGS) National WateAssessment of Endocrine Disruption in the Shenandoah River Watershed - Chemical and Biological Data from Mobile Laboratory Fish Exposures and Other Experiments Conducted during 2014, 2015, and 2016
This data release presents chemical and biological results from investigations of water quality, fish endocrine disruption, and emergent insects in the Shenandoah River Watershed (Virginia and West Virginia, USA) conducted during 2014, 2015, and 2016. Multiple sampling campaigns were conducted at sites located throughout the Shenandoah River Watershed (Table 1). The complex inorganic and organic cPoly- and perfluoalkyl substances in contaminated groundwater, Cape Cod, Massachusetts, 2014-2016
Drinking water health advisories for perfluorooctanoate (PFOA) and perfluorooctane sulfonate (PFOS), were issued by the U.S. Environmental Protection Agency in 2016 in response to growing evidence associated with negative human health effects. PFOA and PFOS are often associated with other poly- and perfluorinated alkyl substances (PFAS). There has been increasing concern for groundwater quality o - Multimedia
USGS Laboratory for the Analysis of Per- and Polyfluoroalkyl Substances (PFAS)USGS Laboratory for the Analysis of Per- and Polyfluoroalkyl Substances (PFAS)USGS Laboratory for the Analysis of Per- and Polyfluoroalkyl Substances (PFAS)
The U.S. Geological Survey laboratory for the analysis of per- and polyfluoroalkyl substances (PFAS) uses cutting-edge techniques to analyze environmental samples including tissues, plasma, water, and soils to undertake and support research projects across the country.
The U.S. Geological Survey laboratory for the analysis of per- and polyfluoroalkyl substances (PFAS) uses cutting-edge techniques to analyze environmental samples including tissues, plasma, water, and soils to undertake and support research projects across the country.
Groundwater sampling for PFASUSGS scientists sampling groundwater near the top of the water table in a corn field in Concord, New Hampshire.
USGS scientists sampling groundwater near the top of the water table in a corn field in Concord, New Hampshire.
Collecting a sample of soil affected by Per- and Polyfluoroalkyl Substances (PFAS)Collecting a sample of soil affected by Per- and Polyfluoroalkyl Substances (PFAS)U.S. Geological Survey hydrologic technician collects a sample of soil affected by Per- and Polyfluoroalkyl Substances (PFAS).
U.S. Geological Survey hydrologic technician collects a sample of soil affected by Per- and Polyfluoroalkyl Substances (PFAS).
Scientist standing near a high resolution mass spectrometerScientist standing near a high resolution mass spectrometerUSGS scientist standing near the high-resolution mass spectrometer at the U.S. Geological Survey Eastern Ecological Science Center. The instrument will be used for analyses of PFAS in plasma and tissue samples. Any display of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government.
USGS scientist standing near the high-resolution mass spectrometer at the U.S. Geological Survey Eastern Ecological Science Center. The instrument will be used for analyses of PFAS in plasma and tissue samples. Any display of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government.
- Publications
Perfluoroalkyl and polyfluoroalkyl substances in groundwater used as a source of drinking water in the eastern United States
In 2019, 254 samples were collected from five aquifer systems to evaluate per- and polyfluoroalkyl substance (PFAS) occurrence in groundwater used as a source of drinking water in the eastern United States. The samples were analyzed for 24 PFAS, major ions, nutrients, trace elements, dissolved organic carbon (DOC), volatile organic compounds (VOCs), pharmaceuticals, and tritium. Fourteen of the 24
AuthorsPeter B. McMahon, Andrea K. Tokranov, Laura M. Bexfield, Bruce D. Lindsey, Tyler D. Johnson, Melissa Lombard, Elise WatsonIntegrated science for the study of perfluoroalkyl and polyfluoroalkyl substances (PFAS) in the environment—A strategic science vision for the U.S. Geological Survey
Concerns related to perfluoroalkyl and polyfluoroalkyl substances (PFAS) in sources of drinking water and in natural and engineered environments have captured national attention over the last few decades. This report provides an overview of the science gaps that exist in the fields of study related to PFAS that are relevant to the U.S. Geological Survey mission and identifies opportunities where tAuthorsAndrea K. Tokranov, Paul M. Bradley, Michael J. Focazio, Douglas B. Kent, Denis R. LeBlanc, Jeff W. McCoy, Kelly L. Smalling, Jeffery A. Steevens, Patricia L. ToccalinoSurface-water/groundwater boundaries affect seasonal PFAS concentrations and PFAA precursor transformations
Elevated concentrations of per- and polyfluoroalkyl substances (PFAS) in drinking-water supplies are a major concern for human health. It is therefore essential to understand factors that affect PFAS concentrations in surface water and groundwater and the transformation of perfluoroalkyl acid (PFAA) precursors that degrade into terminal compounds. Surface-water/groundwater exchange can occur along
AuthorsAndrea K. Tokranov, Denis R. LeBlanc, Heidi M. Pickard, Bridger J. Ruyle, Larry Barber, Robert B. Hull, Elsie M. Sunderland, Chad D. VecitisPer- and polyfluoroalkyl substances (PFAS) in New Hampshire soils and biosolids
The U.S. Geological Survey, in cooperation with the New Hampshire Department of Environmental Services, is undertaking a study on per- and polyfluoroalkyl substances (PFAS) in soils and biosolids. The study will characterize PFAS concentrations in shallow soil and selected biosolids throughout the State of New Hampshire, conduct laboratory experiments to improve understanding of how mobile PFAS ar
AuthorsAndrea K. Tokranov, Kate Emma A. Schlosser, Jeffrey M. Marts, Anthony F. Drouin, Leah M. Santangelo, Sydney M. WelchIsolating the AFFF signature in coastal watersheds using oxidizable PFAS precursors and unexplained organofluorine
Water supplies for millions of U.S. individuals exceed maximum contaminant levels for per- and polyfluoroalkyl substances (PFAS). Contemporary and legacy use of aqueous film forming foams (AFFF) is a major contamination source. However, diverse PFAS sources are present within watersheds, making it difficult to isolate their predominant origins. Here we examine PFAS source signatures among six adja
AuthorsBridger J. Ruyle, Heidi M. Pickard, Denis R. LeBlanc, Andrea K. Tokranov, Colin P. Thackray, Xindi C. Hu, Chad D. Vecitis, Elsie M. SunderlandHillslope groundwater discharges provide localized ecosystem buffers from regional PFAS contamination in a gaining coastal stream
Emerging groundwater contaminants such as per- and polyfluoroalkyl substances (PFAS) may impact surface-water quality and groundwater-dependent ecosystems of gaining streams. Although complex near-surface hydrogeology of stream corridors challenges sampling efforts, recent advances in heat tracing of discharge zones enable efficient and informed data collection. For this study we used a combinatio
AuthorsMartin A. Briggs, Andrea K. Tokranov, Robert B. Hull, Denis R. LeBlanc, A. Haynes, John W. LaneGeochemical and hydrologic factors controlling subsurface transport of poly- and perfluoroalkyl substances, Cape Cod, Massachusetts
Growing evidence that certain poly- and perfluoroalkyl substances (PFASs) are associated with negative human health effects prompted the U.S. Environmental Protection Agency to issue lifetime drinking water health advisories for perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) in 2016. Given that groundwater is a major source of drinking water, the main objective of this work was
AuthorsAndrea K. Weber, Larry B. Barber, Denis R. LeBlanc, Elsie M. Sunderland, Chad D. VecitisNon-USGS Publications**
How Do We Measure Poly- and Perfluoroalkyl Substances (PFASs) at the Surface of Consumer Products?, https://pubs.acs.org/doi/full/10.1021/acs.estlett.8b00600**Disclaimer: The views expressed in Non-USGS publications are those of the author and do not represent the views of the USGS, Department of the Interior, or the U.S. Government.