National Research Program
12201 Sunrise Valley Dr
Reston, VA 20192
I am a research chemist studying methods of groundwater age determination. I am generally interested in the relationships between atmospheric gases and groundwater, as mediated by the interactions in the vadose zone, the layer of the ground that water must pass through before it enters an aquifer.
I have a background in experimental atmospheric chemistry, having worked with several groups on topics including ocean fertilization, biogeochemical impacts to atmospheric chemisty, oceanic emissions of halocarbons to the atmosphere, insturment validation studies, long term observations, anthropogenic emissions, and air quality measurements.
Dissolved Gases are important chemical tracers in groundwater systems. They provide information about groundwater age, aquifer mixing, and the climate conditions when water entered the aquifer. This information can be used to study issue of groundwater availability, quality, and quantity. Additionally direct measurements of these properties can be used to validate groundwater model output and improve model algorithms, allowing more accurate assessment of aquifer systems. Currently, I am developing a mass spectrometer to measure dissolved fixed gases (O2, N2, He, Ne, Ar, Kr, and Xe) to assess groundwater recharge temperatures more accurately, and I am studying the behavior of various anthropogenic compounds in the groundwater system.
In persuit of these research goals, several instruments are currently being developed: a quadrupole based noble gas mass spectrometer, and new GC AED system to quantify groundwater age tracers.
Orcid Profile: https://orcid.org/0000-0002-6897-6494
Research Gate: https://www.researchgate.net/profile/Karl_Haase2
Haase, K. B. Busenberg, E. Groundwater Dating With Atmospheric Halogenated Compounds. In Encyclopedia of Dating Methods, Rink, W.J.; Thompson J., Eds. Springer Netherlands: 2014; pp 1-17
Haase, K.B., Busenberg, E., Plummer, L.N., Casile, G., Sanford, W.E., 2014. Measurements of HFC-134a and HCFC-22 in groundwater and unsaturated-zone air: Implications for HFCs and HCFCs as dating tracers. Chemical Geology 2014, 385: 117-128.
Haase, K. B., Keene, W.C., Pszenny, A. A. P., Mayne, H. R., Talbot, R. W., and Sive, B. C. Calibration and intercomparison of acetic acid measurements using proton-transfer-reaction mass spectrometry (PTR-MS). Atmospheric Measurement Techniques. 2012. 5,2739-2750
Ambrose, J. L., Zhou, Y., Haase, K. B., Mayne H.R., Talbot, R., and Sive, B. C. A gas chromatographic instrument for measurement of hydrogen cyanide in the lower atmosphere. Atmospheric Measurement Techniques. 2012, 5, 1229-1240
Haase, K. B., Jordan, C., Mentis, E. Cottrell, L., Mayne, H.R., Talbot, R., and Sive, B. C. Changes in monoterpene mixing ratios during summer storms in rural New Hampshire (USA). Atmospheric Chemistry and Physics. 2011, 11, 11465-11476
Talbot, R., Mao, H., Feddersen, D., Smith, M., Kim, S. Y., Sive, B., Haase, K., Ambrose, J., Zhou, Y., and Russo, R.: Comparison of Particulate Mercury Measured with Manual and Automated Methods, Atmosphere, 2011, 2, 1-20.
Ambrose, J. L., Haase, K., Russo, R. S., Zhou, Y., White, M. L., Frinak, E. K., Jordan, C., Mayne, H. R., Talbot, R., and Sive, B. C.: A comparison of GC-FID and PTR-MS toluene measurements in ambient air under conditions of enhanced monoterpene loading, Atmos. Meas. Tech. 2010, 3, 959-980, 10.5194/amt-3-959-2010.
R. S. Russo, Y. Zhou, K. B. Haase, O. W. Wingenter, E. K. Frinak, H. Mao, R. W. Talbot, and B. C. Sive. Temporal variability, sources, and sinks of C1-C5 alkyl nitrates in Coastal New England. Atmos. Chem. Phys. 2010, 10, (4), 1865-1883.
C. Jordan, E. Fitz, T. Hagan, B. Sive, E. Frinak, K. Haase, L. Cottrell, S. Buckley, and R. Talbot. Long-term study of VOCs measured with PTR-MS at a rural site in New Hampshire with urban influences. Atmos. Chem. Phys. 2009, 9, 4677-4697.
M. L. White, R. S. Russo, Y. Zhou, J. L. Ambrose, K. Haase, E. K. Frinak, R. K. Varner, O. W. Wingenter, H. Mao, R. Talbot, and B. C. Sive. Are biogenic emissions a significant source of summertime atmospheric toluene in the rural Northeastern United States? Atmos. Chem. Phys. 2009, 9, 81-92.
M. L. White, R.S. Russo, Y. Zhou, H. Mao, R.K. Varner, J. Ambrose, P. Veres, O.W. Wingenter, K. Haase, J. Stutz, R. Talbot, and B. C. Sive, Volatile organic compounds in northern New England marine and continental environments during the ICARTT 2004 campaign. J. Geophys. Res. 2008, 113, D08S90. doi:10.1029/2007JD009161
Zhou, Y., H. Mao, R. S. Russo, D. R. Blake, O. W. Wingenter, K. B. Haase, J. Ambrose, R. K. Varner, R. Talbot, and B. C. Sive. Bromoform and dibromomethane measurements in the seacoast region of New Hampshire, 2002–2004, J. Geophys. Res. 2008, 113, D08305. doi:10.1029/2007JD009103
O. W. Wingenter, K. B. Haase, M. Ziegler, D. R. Blake, F. S. Rowland, B. C. Sive, A. Paulino, R. Thyrhaug, A. Larsen, K. Schulz, M. Meyerhöfer, and U. Riebesell. Unexpected consequences of increasing CO and ocean acidity on marine production of DMS and CH2ClI: Potential climate impacts, Geophys. Res. Lett. 2007, 34, L05710. doi:10.1029/2006GL028139
Y. Zhou, R. K. Varner, R. S. Russo, O. W. Wingenter, K. B. Haase, R. Talbot, and B. C. Sive, Coastal water source of shortlived halocarbons in New England. J. Geophys. Res. 2005, 110, D21. doi:10.1029/2004JD005603
O. W. Wingenter, K. B. Haase, P. Strutton, G. Friedrich, S. Meinardi, D. R. Blake, and F. S. Rowland. Changing concentrations of CO, CH4, C5H8, CH3Br, CH3I, and dimethyl sulfide during the Southern Ocean Iron Enrichment Experiments. PNAS. 2004, 101, 223, 8537-8541. doi: 10.1073/pnas.0402744101.