Pb-Pb and U-Pb dating of cassiterite by in situ LA-ICPMS: Examples spanning ~1.85 Ga to ~100 Ma in Russia and implications for dating Proterozoic to Phanerozoic tin deposits.

This paper investigates applicability of cassiterite to dating ore deposits in a wide age range. We report in situ LA-ICPMS U-Pb and Pb-Pb dating results (n = 15) of cassiterite from six ore deposits in Russia ranging in age from ~1.85 Ga to 93 Ma. The two oldest deposits dated at ~1.83–1.86 Ga are rare metal Vishnyakovskoe located in the East Sayan pegmatite belt and tin deposits within the Tuyukan ore region in the Baikal folded region. Rare metal skarn deposits of Pitkäranta ore field in the Ladoga region, Fennoscandian Shield are dated at ~1.54 Ga. Cassiterite from the Mokhovoe porphyry tin deposit located in western Transbaikalia is 810 ± 20 Ma. The youngest cassiterite was dated from the deposits Valkumei (Russian North East, 108 ± 2 Ma) and Merek (Russian Far East, 93 ± 2 Ma). Three methods of age calculations, including ²⁰⁸Pb/²⁰⁶Pb-²⁰⁷Pb/²⁰⁶Pb inverse isochron age, Tera-Wasserburg Concordia lower intercept age, and ²⁰⁷Pb-corrected ²⁰⁶Pb*/²³⁸U age were used and the comparison of the results is discussed. In all cases, the dated cassiterite from the ore deposits agreed, within error, with the established period of magmatism of the associated granitic rock