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Atomic displacements in ferroelectric trigonal and orthorhombic boracite structures

January 1, 1972

New crystal-structure refinements of Pca21 boracite, Mg3ClB7O13, and Rϵc ericaite, Fe2.4Mg0.6ClB7O13, show that some boron and oxygen atoms are involved in the ‘ferro’ transitions as well as the metal and halogen atoms. The atomic displacements associated with the polarity changes are as large as 0.6Å.


Publication Year 1972
Title Atomic displacements in ferroelectric trigonal and orthorhombic boracite structures
DOI 10.1016/0038-1098(72)90063-4
Authors Eric Dowty, J.R. Clark
Publication Type Article
Publication Subtype Journal Article
Series Title Solid State Communications
Index ID 70010263
Record Source USGS Publications Warehouse
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