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Boron-oxygen polyanion in the crystal structure of tunellite

January 1, 1963

The crystal structure of tunellite, SrO·3B2O3·4H2O, with infinite sheets of composition n[B6O9(OH)2]2-, has cations and water molecules in the spaces within the sheets. Adjacent sheets are held together by hydrogen bonding through the water molecules. The boron-oxygen polyanions provide the first example in hydrated borate crystals of one oxygen linked to three borons.

Publication Year 1963
Title Boron-oxygen polyanion in the crystal structure of tunellite
DOI 10.1126/science.141.3586.1178
Authors J. R. Clark
Publication Type Article
Publication Subtype Journal Article
Series Title Science
Index ID 70010787
Record Source USGS Publications Warehouse