Helium isotope studies in the Mojave Desert, California: Implications for groundwater chronology and regional seismicity

We report helium isotope and concentration results for groundwaters from the western Mojave River Basin (MRB), 130 km east of Los Angeles, CA. The basin lies adjacent to the NW-SE trending San Andreas Fault (SAF) system. Samples were collected along two groundwater flowpaths that originate in the San Gabriel Mountains and discharge to the Mojave River located ???32 km to the northeast. Additional groundwater samples were collected from Mojave River Deposits underlying the Mojave River. The primary objective of this study is to identify and quantify crustal and mantle helium contributions to the regional groundwater system. A total of 27 groundwaters, sampled previously for chemistry and isotope systematics (including 14C activity) have measured helium concentrations that increase along flowpaths from 9.9??10-8 to 1.0??10-4 cm3 STP g-1 H2O. Concomitantly, 3He/4He ratios decrease from 0.84RA to 0.11RA (RA equals the 3He/4He ratio in air=1.4??10-6). We did not record 3He/4He ratios equivalent to crustal-production values (???0.02RA) in any sample. Dissolved helium concentrations were resolved into components associated with solubility equilibration, air entrainment, mantle-derivation, in-situ production within the aquifer, and extraneous crustal fluxes. All samples contained the first four components, but only older samples had the superimposed effects of helium derived from a crustal flux. The radiogenic He component has chronological significance, and good concordance between 4He and 14C ages for younger groundwaters (