Platinum-group element resources in podiform chromitites from California and Oregon

Rock samples from about 280 podiform chromite deposits in California and Oregon were analyzed for Pt, Pd, Rh, and Ir by fire assay-atomic absorption and spectrographic techniques to estimate by-product platinum-group element potential of chromite mining. These deposits include ophiolites from the Sierra Nevada, Klamath Mountains, Coast Ranges, and the Canyon Mountain Complex; the deposits vary from Paleozoic to Mesozoic age and vary in size, shape, texture, and degree of metamorphism. The maximum platinum-group element contents (in ppm) measured for chromitites are: Pt, 2.53; Pd, 0.2; Rh, 0.14; Ru, 4.93; and Ir, 2.93.Correlations between Pt and Rh (0.60), Rh and Ir (0.64), Rh and Ru (0.71), and Ir and Ru (0.85) are significant at the 1 percent level. Relatively small but significant differences in platinum-group element content exist between geologic terranes. Chromite production from California and Oregon amounts to about 692,000 metric tons (1914-1985); the mean contained platinum-group element amounts in troy ounces are: Pt, 850; Pd, 100; Rh, 260; Ru, 4200; and Ir, 1,700, using estimated grades. Previous investigators have suggested that relatively few samples can represent the platinum-group element content of a podiform chromite deposit; therefore, these analyses are assumed to approximate "grades." Total world resources of platinum-group elements in podiform chromite deposits are estimated in troy ounces to be: Pt, 210,000; Pd, 25,000; Rh, 64,000; Ru, 1,000,000; and Ir, 420,000.