Explosive summit collapse of Kīlauea Volcano in 1924 preceded by a decade of crustal contamination and anomalous Pb isotope ratios

A geochemical time-series analysis of lavas from frequently active basaltic volcanoes has the potential to reveal the enigmatic mantle controls on volcanic behavior and hazards. In May 1924, the century-long lava lake within Halemaʻumaʻu pit crater at the summit of Kīlauea Volcano drained and the floor of Halemaʻumaʻu collapsed, triggering ∼3 weeks of phreatic explosions due to the interaction of groundwater with hot rock. For the next three decades, eruptions at Kīlauea were sporadic (the longest hiatus was from 1934 to 1952), small in volume, and short (typically 10 km). The Pb isotopic heterogeneity of the samples on short length (hand specimen to lava flow) and time (∼1–4 yr) scales can be explained by inefficient mixing as small batches of contaminated magma were delivered to the remnants of Kīlauea’s summit magma storage reservoir. Our results confirm that the Pb isotope ratios of basalts from ocean-island volcanoes may be significantly modified by assimilation of materials from the underlying oceanic crust. In particular, the ²⁰⁷Pb/²⁰⁴Pb ratio may be a sensitive tracer of such crustal contamination at Hawaiian shield volcanoes. Mauna Loa lavas display a factor of ∼5 more scatter towards higher ²⁰⁷Pb/²⁰⁴Pb at a given ²⁰⁶Pb/²⁰⁴Pb ratio than most Kīlauea lavas (excluding the samples from 1912 to 1954). This might be caused by more pervasive crustal contamination at Mauna Loa due to its lower magma supply rate over the last ∼4 kyr.