High-frequency data reveal deicing salts drive elevated specific conductance and chloride along with pervasive and frequent exceedances of the U.S. Environmental Protection Agency aquatic life criteria for chloride in urban streams

Increasing specific conductance (SC) and chloride concentrations [Cl] negatively affect many stream ecosystems. We characterized spatial variability in SC, [Cl], and exceedances of Environmental Protection Agency [Cl] criteria using nearly 30 million high-frequency observations (2–15 min intervals) for SC and modeled [Cl] from 93 sites across three regions in the eastern United States: Southeast, Mid-Atlantic, and New England. SC and [Cl] increase substantially from south to north and within regions with impervious surface cover (ISC). In the Southeast, [Cl] weakly correlates with ISC, no [Cl] exceedances occur, and [Cl] concentrations are constant with time. In the Mid-Atlantic and New England, [Cl] and [Cl] exceedances strongly correlate with ISC. [Cl] criteria are frequently exceeded at sites with greater than 9–10% ISC and median [Cl] higher than 30–80 mg/L. Tens to hundreds of [Cl] exceedances observed annually at most of these sites help explain previous research where stream ecosystems showed changes at (primarily nonwinter) [Cl] as low as 30–40 mg/L. Mid-Atlantic chronic [Cl] exceedances occur primarily in December–March. In New England, exceedances are common in nonwinter months. [Cl] is increasing at nearly all Mid-Atlantic and New England sites with the largest increases at sites with higher [Cl].