Prolonged cooling of andesitic-dacitic lava flows produces optimal groundmass material for 40Ar/39Ar dating

Organizing the eruptive histories and petrogenetic models that underpin hazard assessments at active volcanoes typically requires high-precision ages for late Pleistocene to Holocene lava flows. In this study, features of an existing 40Ar/39Ar dataset for andesitic-dacitic rocks from Ruapehu volcano, Aotearoa New Zealand, were interrogated with new microanalytical data to identify the optimal groundmass material for age determination. To understand the behavior of K and Ar within the cooling melt of lavas during their emplacement, we examined and compared the petrological features of samples from the ice-chilled margin and interior of a lava flow. The groundmass of the rapidly cooled sample comprises non-vesicular rhyolitic glass and microlites of plagioclase, orthopyroxene, and magnetite. The sample from the flow interior has minimal amounts of groundmass glass, and interstices are instead occupied by sanidine and tridymite. Modelling supports the interpretation that sanidine crystallized as a stable groundmass phase during slow cooling of degassed melt in the interior zones of lavas that were insulated behind their glassy margins. Our evaluation of the age data shows that sanidine contributed high yields of radiogenic argon during step-heating experiments for samples collected from lava interiors, which enabled high-precision 40Ar/39Ar ages to be determined. Using Ruapehu as an example of an arc volcano affected by lava-ice interaction, we provide a basic field guide for identifying lava flows that contain groundmass sanidine at the expense of glass. Target outcrops also offer opportunities for reconstructing geomagnetic dynamics and volcano–climate relationships during the Pleistocene and Holocene.