Helium isotopes carry messages from the mantle

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Scientists who work at Yellowstone are interested in finding physical and chemical signals from the deep magmatic system, both to better understand the nature of the system and also to monitor for possible changes. Helium is an inert gas that is an excellent tracer of magmatic processes.

Yellowstone Caldera Chronicles is a weekly column written by scientists and collaborators of the Yellowstone Volcano Observatory. This week's contribution is from Deborah Bergfeld, research geologist with the U.S. Geological Survey.

Guardian Geyser and Norris Geyser Basin, Yellowstone National Park

Guardian Geyser and Norris Geyser Basin, Yellowstone National Park. (Credit: Deborah Bergfeld, USGS. Public domain.)

Rock outcrops and other landforms around Yellowstone National Park provide records of three cycles of explosive volcanism that occurred over the past 2.1 million years. Although no magmatic eruptions have occurred for 70,000 years, visitors today can still see evidence of Yellowstone's volcanic nature in the geysers, hot springs, and areas of steaming ground that are part of Yellowstone's modern hydrothermal systems. These features are visible evidence for the large amount of heat stored deep in the subsurface.

Scientists who work at Yellowstone are interested in finding physical and chemical signals from the deep magmatic system, both to better understand the nature of the system and also to monitor for possible changes. Some of that research involves collection and analyses of gas and water from thermal areas to look for chemical tracers that can be directly linked to the magma.

Map of Yellowstone National Park showing helium isotope values

Color-coded map showing the range of helium isotope values across Yellowstone National Park. BC = Boundary Creek, GGB = Gibbon Geyser Basin, MHS = Mammoth Hot Springs. (Public domain.)

Helium is an inert gas that is an excellent tracer of magmatic processes. There are two important isotopes of helium, helium-3 (3He), which is stored deep in the earth's mantle where it was trapped during formation of the earth, and helium-4 (4He), which is produced during radioactive decay of uranium and thorium, two elements commonly found in earth's crust. 3He is very rare at the earth's surface; for example, the 3He/4He ratio in air is 1.4 x 10-6, or about one 3He for every million 4He atoms. However, magma rising from the mantle transports some of the trapped 3He to the surface.

We use the air ratio (RA) as a basis for comparison when we discuss the ratios in samples of gas. If gas has been stored for a long time in the earth's crust, it will likely have very high concentrations of 4He relative to 3He, and the 3He/4He ratio will be low, giving it a smaller RA value. In contrast, a gas sample collected from an erupting volcano will likely have more 3He relative to 4He, and the ratio will be high, meaning a larger RA value. To simplify things, we express the RA value of air as 1. Values much greater than 1 indicate that there is a greater proportion of 3He (more mantle component) than what is found in air.

To put it simply, a high RA means that the gas has a magmatic origin. A low RA means there is not a magmatic source.

Years of study of Yellowstone's thermal areas have shown that gas at several areas is closely linked to the magmatic system. Gas from a fumarole at Mud Geyser in the Mud Volcano thermal area has the highest 3He/4He ratio of any feature at Yellowstone, up to 17 RA, and nearby thermal areas have degassing features with RA values >15. Likewise, the 3He/4He ratios in gas from several features in the Gibbon Geyser Basin, on the margin of Yellowstone's caldera, are also very high, but here the maximum RA value is ~12.6. The waters in both of these thermal areas tend to be acidic with high concentrations of sulfur, and both areas have super-heated fumaroles, where the temperature of the gas exiting the ground is higher than the temperature of boiling water.

Relatively high RA values are also found in gas outside of the caldera boundary. The thermal areas at Mammoth Hot Springs in the north part of the park and Boundary Creek in the southwest corner of the park differ greatly from the Mud Volcano area. Temperatures of the thermal features do not exceed boiling and the pH of the hot springs are close to neutral. In spite of the cooler nature of these areas and the distance from the main upflow of magmatic gas there is a strong signal from the magmatic system.

The RA values of thermal areas around Yellowstone Lake and other thermal features in the southeast part of the park are generally low (less than 5). These low ratios indicate more 4He, which is the isotope of the gas that is stored in the rocks of the crust. Heating caused by the Yellowstone magma system has caused this form of helium to be released from the crust in abundant quantities, but the source of this gas is not the magma itself.

Helium is an exceptional indicator of magmatic activity beneath the surface, but isotopes matter! Knowing whether the gas is 3He or 4He tells the story of its origin: from the mantle and transported to the surface by magma, or from billion-year-old crustal rocks where the gas has formed by the process of radioactive decay. Yellowstone displays both forms of helium, so measuring the ratio of the two isotopes is critical to understanding its source!

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Date published: January 29, 2018

Yellowstone gas emissions—an extreme chemistry playset!

If you've visited Yellowstone, you've probably noticed that some thermal areas have a distinctive smell. This is due to the gas that discharges from features such as geysers, mud pots, roiling pools and fumaroles.