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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 4097

Hydrologic and geochemical effects on oxygen uptake in bottom sediments of an effluent-dominated river Hydrologic and geochemical effects on oxygen uptake in bottom sediments of an effluent-dominated river

More than 95% of the water in the South Platte River downstream from the largest wastewater treatment plant serving the metropolitan Denver, Colorado, area consists of treated effluent during some periods of low flow. Fluctuations in effluent-discharge rates caused daily changes in river stage that promoted exchange of water between the river and bottom sediments. Groundwater discharge
Authors
P.B. McMahon, J.A. Tindall, J.A. Collins, K.J. Lull, J.R. Nuttle

Geometry of sorbed arsenate on ferrihydrite and crystalline FeOOH: Re-evaluation of EXAFS results and topological factors in predicting sorbate geometry, and evidence for monodentate complexes Geometry of sorbed arsenate on ferrihydrite and crystalline FeOOH: Re-evaluation of EXAFS results and topological factors in predicting sorbate geometry, and evidence for monodentate complexes

Manceau's (1995) reinterpretation of some of our EXAFS results (Waychunas et al., 1993) has been analyzed using both old and newly collected data in an attempt to clarify the nature of proposed monodentate and edge-sharing bidentate arsenate complexes on the ferrihydrite surface. It is shown that EXAFS analysis utilizing data with sufficient k-range does indicate the presence of...
Authors
Glenn A. Waychunas, James A. Davis, Christopher C. Fuller

Combined use of groundwater dating, chemical, and isotopic analyses to resolve the history and fate of nitrate contamination in two agricultural watersheds, Atlantic coastal plain, Maryland Combined use of groundwater dating, chemical, and isotopic analyses to resolve the history and fate of nitrate contamination in two agricultural watersheds, Atlantic coastal plain, Maryland

The history and fate of groundwater nitrate (NO3−) contamination were compared in 2 small adjacent agricultural watersheds in the Atlantic coastal plain by combined use of chronologic (CCl2F2, 3H), chemical (dissolved solids, gases), and isotopic (δ15N,δ13C, δ34S) analyses of recharging groundwaters, discharging groundwaters, and surface waters. The results demonstrate the interactive...
Authors
J.K. Böhlke, J. M. Denver

Methane production and consumption monitored by stable H and C isotope ratios at a crude oil spill site, Bemidji, Minnesota Methane production and consumption monitored by stable H and C isotope ratios at a crude oil spill site, Bemidji, Minnesota

Stable isotopic ratios of C and H in dissolved CH4 and C in dissolved inorganic C in the ground water of a crude-oil spill near Bemidji, Minnesota, support the concept of CH4production by acetate fermentation with a contemporaneous increase in HCO3−concentration. Methane concentrations in the saturated zone decrease from 20.6 mg L−1 to less than 0.001 mg L−1 along the investigated flow...
Authors
Kinga Revesz, Tyler B. Coplen, Mary J. Baedecker, Pierre D. Glynn

State-dependent anisotrophy: Comparison of quasi-analytical solutions with stochastic results for steady gravity drainage State-dependent anisotrophy: Comparison of quasi-analytical solutions with stochastic results for steady gravity drainage

Anisotropy in large-scale unsaturated hydraulic conductivity of layered soils changes with the moisture state. Here, state-dependent anisotropy is computed under conditions of large-scale gravity drainage. Soils represented by Gardner's exponential function are perfectly stratified, periodic, and inclined. Analytical integration of Darcy’s law across each layer results in a system of...
Authors
Timothy R. Green, David L. Freyberg

Estimating 14C groundwater ages in a methanogenic aquifer Estimating 14C groundwater ages in a methanogenic aquifer

This paper addresses the problem of 14C age dating of groundwaters in a confined regional aquifer affected by methanogenesis. Increasing CH4 concentrations along the groundwater flow system and 13C and 14C isotopic data for dissolved inorganic carbon, dissolved organic carbon, and CH4 clearly show the effect of methanogenesis on groundwater chemistry. Inverse reaction path modeling using...
Authors
Ramon Aravena, Leonard I Wassenaar, Niel Plummer

Gross-beta activity in ground water: natural sources and artifacts of sampling and laboratory analysis Gross-beta activity in ground water: natural sources and artifacts of sampling and laboratory analysis

Gross-beta activity has been used as an indicator of beta-emitting isotopes in water since at least the early 1950s. Originally designed for detection of radioactive releases from nuclear facilities and weapons tests, analysis of gross-beta activity is widely used in studies of naturally occurring radioactivity in ground water. Analyses of about 800 samples from 5 ground-water regions of...
Authors
Alan H. Welch, Zoltan Szabo, David L. Parkhurst, Peter C. Van Metre, Ann H. Mullin

Supporting data for hydrologic studies in San Francisco Bay, California: Meteorological measurements at the Port of Redwood City during 1992-1994 Supporting data for hydrologic studies in San Francisco Bay, California: Meteorological measurements at the Port of Redwood City during 1992-1994

Meteorological data were collected during 1992-94 at the Port of Redwood City, California, to support hydrologic studies in southern San Francisco Bay. The meteorological variables that were measured were air temperature, atmospheric pressure, quantum flux (insolation), and four parameters of wind speed and direction: scalar mean horizontal wind speed, (vector) resultant horizontal wind...
Authors
Laurence E. Schemel
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