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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 4097

Modeling transport in transient ground-water flow: An unacknowledged approximation Modeling transport in transient ground-water flow: An unacknowledged approximation

During unsteady or transient ground-water flow, the fluid mass per unit volume of aquifer changes as the potentiometric head changes, and solute transport is affected by this change in fluid storage. Three widely applied numerical models of two-dimensional transport partially account for the effects of transient flow by removing terms corresponding to the fluid continuity equation from...
Authors
Daniel J. Goode

Importance of methane-oxidizing bacteria in the methane budget as revealed by the use of a specific inhibitor Importance of methane-oxidizing bacteria in the methane budget as revealed by the use of a specific inhibitor

METHANE is a greenhouse gas whose concentration in the atmosphere is increasing. Much of this methane is derived from the metabolism of methane-generating (methanogenic) bacteria and over the past two decades much has been learned about the ecology of methanogens; specific inhibitors of methanogenesis, such as 2-bromoethanesulphonic acid, have proved useful in this regard. In contrast...
Authors
Ronald S. Oremland, Charles W. Culbertson

Hydrous pyrolysis of crude oil in gold-plated reactors Hydrous pyrolysis of crude oil in gold-plated reactors

Crude oils from Iraq and California have been pyrolyzed under hydrous conditions at 200 and 300°C for time periods up to 210 days, in gold-plated reactors. Elemental (vanadium, nickel), stable isotopic (carbon), and molecular (n-alkanes, acyclic isoprenoids, steranes, terpanes and aromatic steroid hydrocarbons) analyses were made on the original and pyrolyzed oils. Various conventional...
Authors
J.A. Curiale, P.D. Lundegard, Y.K. Kharaka

The aqueous photolysis of α-pinene in solution with humic acid The aqueous photolysis of α-pinene in solution with humic acid

Terpenes are produced abundantly by environmental processes but are found in very low concentrations in natural waters. Aqueous photolysis of solutions containing α-pinene, a representative terpene, in the presence of humic acid resulted in degradation of the pinene. Comparison of this reaction to photolysis of α-pinene in the presence of methylene blue leads to the conclusion that the...
Authors
Marvin C. Goldberg, Kirkwood M. Cunningham, George R. Aiken, Eugene R. Weiner

Identification of persistent anionic surfactant-derived chemicals in sewage effluent and groundwater Identification of persistent anionic surfactant-derived chemicals in sewage effluent and groundwater

Preparative isolation and fractionation procedures coupled with spectrometric analyses were used to identify surfactant-derived contaminants in sewage effluent and sewage-contaminated groundwater from a site located on Cape Cod, Massachusetts. Anionic surfactants and their biodegradation intermediates were isolated from field samples by ion exchange and fractionated by solvent extraction...
Authors
Jennifer A. Field, Jerry A. Leenheer, Kevin A. Thorn, Larry B. Barber, Colleen Rostad, Donald L. Macalady, Stephen R. Daniel

Isolation of hydrophilic organic acids from water using nonionic macroporous resins Isolation of hydrophilic organic acids from water using nonionic macroporous resins

A method has been developed for the isolation of hydrophilic organic acids from aquatic environments using Amberlite∗ XAD-4 resin. The method uses a two column array of XAD-8 and XAD-4 resins in series. The hydrophobic organic acids, composed primarily of aquatic fulvic acid, are removed from the sample on XAD-8, followed by the isolation of the more hydrophilic organic acids on XAD-4...
Authors
G. R. Aiken, Diane M. McKnight, K. A. Thorn, E.M. Thurman

D4Z: A new renumbering for iterative solution of ground-water flow and solute-transport equations D4Z: A new renumbering for iterative solution of ground-water flow and solute-transport equations

D4 zig-zag (D4Z) is a new renumbering scheme for producing a reduced matrix to be solved by an incomplete LU preconditioned, restarted conjugate-gradient iterative solver. By renumbering alternate diagonals in a zig-zag fashion, a very low sensitivity of convergence rate to renumbering direction is obtained. For two demonstration problems involving groundwater flow and solute transport...
Authors
K.L. Kipp, T.F. Russell, J.S. Otto
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