Flameless atomic absorption determination of bismuth in soils and rocks

Recent advances in flameless atomic absorption allow determinations of bismuth in concentrations as small as 50 ppb in 0.2 g of rock or soil sample. The sample is fused with sodium bisulfate and the fusion product is leached with hot 2 M hydrochloric acid and treated with ammonium citrate, (ethylenedinitrilo) tetraacetic acid disodium salt, and finally with ammonium 1-pyrrolidinedithiocarbamate to form a complex which is extracted into methyl isobutyl ketone. Aliquots of the latter are pipetted into a graphite furnace and then subjected to an established and automated program of drying, charring, and atomizing. Recorded peak heights provide a measure of the amount of bismuth present.