Geochemical and fluid zonation in the skarn environment at the tomboy-minnie gold deposits, Lander County, Nevada

The Tomboy—Minnie gold deposits are related to the middle Tertiary porphyry copper system centered at Copper Canyon. Gold-silver ores in the deposits occur mostly in a pyrrhotite- and pyrite-rich basal 30-m-thick sequence of altered calcareous conglomerate belonging to the Middle Pennsylvanian Battle Formation. The entire mineralized system contained at least 3.3 million troy oz gold before large-scale mining operations began. Alteration in the Tomboy—Minnie deposits includes actinolite- and chlorite-dominant assemblages, in marked contrast to the skarn, potassic, and phyllic assemblages characterizing the copper-gold-silver deposits of the system. Introduction of gold occurred penecontemporaneously with replacement of early diopside-alteration assemblages by actinolite and chlorite. Metals are zoned strongly in the Copper Canyon system: the West and East ore bodies occur in a copper-gold-silver zone that is followed outward by a gold-silver zone which includes the Tomboy deposit and in turn, is succeeded by a lead-zinc-silver zone. Locations of drill holes that have Au/Ag assay ratios of ⩾ 1 clearly outline the Tomboy—Minnie deposits within an area of rocks with Au/Ag ratios of ≈ 0.5. Fluid-inclusion studies suggest wide variations in temperature and chemistry prevailed in the fluids associated with mineralization at the Tomboy. Early fluids associated with diopsidequartz assemblages probably were dominantly CaCl₂-rich brines and were boiling at temperatures higher than 500°C. These fluids were progressively enriched in sodium and potassium over time, and during the hydrosilicate stages, temperatures probably ranged from 320 to 500°C at the time actinolite formed, and from 220 to 320°C at the time chlorite was dominant. Sulfur isotopic data suggest that sulfur, mostly from a magmatic or deep-seated crustal source, was transported by hydrothermal fluids as aqueous H₂S with a δ ³⁴S of about .4 ± 1‰">