Geochemistry of Mercury and other trace elements in fluvial tailings upstream of Daguerre Point Dam, Yuba River, California, August 2001

This study was designed to characterize the particle-size distribution and the concentrations of total mercury (HgT), methylmercury (MeHg), and other constituents in sediments trapped behind Daguerre Point Dam, a 28-foot-high structure on the lower Yuba River in California. The results of the study will assist other agencies in evaluating potential environmental impacts from mobilization of sediments if Daguerre Point Dam is modified or removed to improve the passage of anadromous fish. Methylmercury is of particular concern owing to its toxicity and propensity to bioaccumulate. A limited amount of recent work on hydraulic and dredge tailings in other watersheds has indicated that mercury and MeHg concentrations may be elevated in the fine-grained fractions of placer mining debris, particularly clay and silt. Mercury associated with tailings from placer gold mines is a source of continued contamination in Sierra Nevada watersheds and downstream water bodies, including the Sacramento?San Joaquin Delta and the San Francisco Bay of northern California. Churn drilling was used to recover sediments and heavy minerals at 5-foot intervals from six locations upstream of Daguerre Point Dam. Maximum depth of penetration ranged from 17.5 to 35 feet below land surface, resulting in 31 discreet drilled intervals. Drilling in permeable, unconsolidated sediments below the streambed of the Yuba River released a significant volume of water along with the sediment, which complicated the sampling and characterization effort. Overflow of a silty fraction sampled at the drill site contained suspended sediment consisting predominantly of silt and clay, with HgT concentration ranging from 33 to 1,100 ng/g (nanogram per gram) dry weight. A sandy fraction, collected after sieving sediment through a 2-millimeter vibratory screen, contained from 14 to 82 percent sand and 1 to 29 percent silt plus clay, and had HgT concentrations ranging from 6.8 to 81 ng/g dry weight. A clay-silt fraction, sampled from material remaining in suspension after the sandy fraction settled for 15-20 minutes, contained mercury concentrations from 23 to 370 ng/g dry weight. Concentrations of MeHg were less than the detection limit (