Manganese complexes with bi-carbonate and sulfate in natural water
January 1, 1963
The association constant for the dissolved species MnHCO3+ was experimentally determined to be 63. From this value and a published constant for the species MNSO4 aq., a diagram was prepared showing per cent of dissolved manganese complexed in the presence of 10 to 10,000 p.p.m. bicarbonate and 1.0 to 10,000 p.p.m. sulfate. The rate of oxidation of Mn+2 in aerated water is greatly increased by increasing pH, and is retarded when SO4-2 and HCO3- are present.
Citation Information
| Publication Year | 1963 |
|---|---|
| Title | Manganese complexes with bi-carbonate and sulfate in natural water |
| DOI | 10.1021/je60016a029 |
| Authors | J.D. Hem |
| Publication Type | Article |
| Publication Subtype | Journal Article |
| Series Title | Journal of Chemical and Engineering Data |
| Index ID | 70010788 |
| Record Source | USGS Publications Warehouse |