Phosphatic zone in the lower part of the Maquoketa Shale in northeastern Iowa

The basal beds of the Maquoketa Shale in northeastern Iowa include a basal silty phosphorite layer that is thickest near Dubuque. In Clayton County, Iowa, the bed averages about 1 foot thick (30 centimeters) and contains 22.5 percent P₂0₅ . Phosphatic dolomite that is 8 10 feet (2.4 3 meters) thick and occurs higher in the Maquoketa was observed only in Dubuque County. The thickest and most phosphatic rock in the Maquoketa appears to be coextensive with dark-brown shale, which also occurs mainly in Dubuque County. Rare-earth content of the phosphatic rock decreases southeastward across the area, ranging from 2,000 to about 120 parts per million. The thin low-grade phosphorite is typical of the platform-type phosphorite facies and may be' genetically related to the emergence of the Ozark uplift as an island late in the Ordovician period.