Porphyry copper and other intrusion-related mineralization in Mexico

Intrusion-related copper-bearing ore deposits in Mexico span a wide-range of deposit types and geological settings and formed from the mid-Mesozoic through the Holocene. These deposits include world-class copper porphyry and skarn deposits as well as a continuum of similar skarn, porphyry, vein, and replacement deposits that contain variable quantities of molybdenum, zinc, silver, lead, iron, gold, tungsten, tin, fluorine, and beryllium. Based on a new compilation, this paper reviews data on the full spectrum of intrusion-related deposits, concentrating on copper-rich systems, and attempts to place them in a generalized geological and petrological context.

In Mexico, intrusion-related mineral deposits are primarily Mesozoic to middle Tertiary in age. Three broad periods are prominent in the mineralization record: the late Mesozoic, the Laramide, and the middle Tertiary. Jurassic to Late Cretaceous calc-alkalic batholiths with sparse volcanic rocks occur along the Pacific margin mainly on eugeoclinal crust, although locally on continental crust (for example, in Sonora). Latest Cretaceous to Early Tertiary ('Laramide') calc-alkalic batholithic, subvolcanic, and volcanic centers occur in an overlapping but somewhat more easterly band that extends with diminished intensity and somewhat younger ages into the Sierra Madre Oriental. Mid-Tertiary volcanism and local intrusive centers are widely developed, with the greatest abundance of calcalkalic felsic volcanics in the Sierra Madre Occidental and more mafic middle to late Tertiary arc volcanics in the Sierra Madre del Sur in southern Mexico and as a fringe of alkalic volcanic' and sub volcanic centers in northeastern Mexico.

Over 600 copper-rich intrusion-related systems can be inferred from the literature; about 100 can be documented with some confidence. Copper-rich deposits occur with both intermediate (dioritic) and felsic (granodioritic) intrusive centers and show a corresponding variety of associated metals and alteration types. Styles include porphyry-type disseminated or stockwork mineralization, skarn, breccia pipes, and pegmatites. Multiple styles commonly occur in the same district. Porphyry copper deposits are best developed in association with the Laramide intrusive centers of northern Mexico and the mid-Tertiary intrusions in southern Mexico. Other intrusion-related deposit types occur within the same magmatic framework, but they have different temporal and spatial correlations related to their igneous composition and exposure level.

The continuum of intrusion-related mineralization in Mexico can be divided by geological associations, metal contents, and styles of alteration. Although more than 1,500 intrusion-associated mineral deposits are known, the scarcity of data requires a simplified approach focusing on major districts. We distinguish the following overlapping groups of deposits based on their metal contents and igneous compositions: (1) porphyry or skarn Cu(-Mo-Zn) associated with intermediate to felsic granitoids, (2) porphyry or skarn Cu (-Au-Fe) associated with intermediate intrusions, (3) greisen, skarn, or pegmatite W(-Mo) associated with intermediate to felsic granitoids, (4) replacement or skarn Zn-Pb-Ag(-Cu-F) deposits associated with felsic intrusions, (5) volcanic-hosted vein Ag-Au(-Zn-F-Sn) deposits associated with hypabyssal felsic intrusions, (6) vein ± replacement Ag-Au(-Cu-Zn-Pb) deposits associated with intermediate stocks, (7) volcanichosted Au-Ag(-Cu) systems, (8) rhyolite-related F(-Sn-Be) deposits, (9) diorite-related Fe(-Au-Cu) skarns, and (9) rhyolite-related Fe deposits.

Some inferences can be drawn from examination of these patterns:

• Igneous compositions vary in time and space in Mexico, but multiple compositions commonly were emplaced at different times in the same region. Temporal variations (as in Sonora) are as important as differences in province (as between Sonora and southern Mexico).

• Alteration and metal differences between alkaline and sub alkaline, felsic and mafic magma suites can be partly rationalized from equilibria among igneous minerals (for example, in terms of aAl₂O₃ vs aCaO [vs aSiO₂ ]), fluid chloride and sulfur contents, and magmatic metal contents which reflect province and process.

• Exposure and preservation filter observed Mexican metallogeny. Erosion of the Mesozoic arc superstructure in the west leaves mainly tungsten-skarns, burial of the Laramide arc in central Mexico interrupts porphyry copper patterns, and minimal exhumation of mid-Tertiary intrusive centers preserves distal vein or replacement systems.

• The superimposed metallogenic patterns in Mexico have parallels with metallogenic patterns in the western United States in terms of the effects of preservation, process, and province. Future work should focus on increasing the basic geological data on mineral deposits and igneous rocks. Geochronology, petrology, and geochemistry would help better define the temporal, spatial, and compositional interrelationships between tectonism, magmatism, and mineralization.