Publications

Multiply isotopically substituted molecules (‘clumped’ isotopologues) can be used as geothermometers because their proportions at isotopic equilibrium relative to a random distribution of isotopes amongst all isotopologues are functions of temperature. This has allowed measurements of clumped-isotope abundances to be used to constrain formation temperatures of several natural materials...

No abstract available.

Determining the chemical and mineralogical variability within fine-grained mudrocks poses analytical challenges but is potentially useful for documenting subtle stratigraphic differences in physicochemical environments that may influence petroleum reservoir properties and behavior. In this study, we investigate the utility of combining principal component analysis (PCA) of X-ray...

The U.S. Geological Survey (USGS) has conducted an assessment of water and proppant requirements, and water production volumes, associated with possible future production of undiscovered petroleum resources in the Bakken and Three Forks Formations, Williston Basin, USA. This water and proppant assessment builds directly from the 2013 USGS petroleum assessment for the Bakken and Three...

Basin-wide datasets that provide information on the geochemical properties of petroleum systems, such as source rock quality, product composition, and thermal maturity, are often difficult to come by or assemble from publicly available data. When published studies are available and include these kinds of properties, they generally have few sampling locations and limited numbers and types...

Organic sulfur compounds are ubiquitous in natural oil and gas fields and moderate-low temperature sulfide ore deposits. Previous studies have shown that organic sulfur compounds are important in enhancing the rates of thermochemical sulfate reduction (TSR) reactions, but the details of these reaction mechanisms remain unclear. In order to assess the extent of sulfate reduction in the...

The Eagle Ford shale is a major continuous oil and gas resource play in southcentral Texas and a source for other oil accumulations in the East Texas Basin. As part of the U.S. Geological Survey’s (USGS) petroleum system assessment and research efforts, a coring program to obtain several immature, shallow cores from near the outcrop belt in central Texas has been undertaken. The first of...

Low-temperature hydrous pyrolysis (LTHP) at 300°C (572°F) for 24 h released retained oils from 12- to 20-meshsize samples of mature Niobrara marly chalk and marlstone cores. The released oil accumulated on the water surface of the reactor, and is compositionally similar to oil produced from the same well. The quantities of oil released from the marly chalk and marlstone by LTHP are...

In 2015, the U.S. Geological Survey published an assessment of technically recoverable continuous oil and gas resources of the Mississippian Barnett Shale in the Bend Arch–Fort Worth Basin Province of north-central Texas. Of the two assessment units involved in the overall assessment, one included a roughly equal number of oil wells and gas wells as classified by the U.S. Geological...

Site-specific carbon isotope measurements of organic compounds potentially recover information that is lost in a conventional, ‘bulk’ isotopic analysis. Such measurements are useful because isotopically fractionating processes may have distinct effects at different molecular sites, and thermodynamically equilibrated populations of molecules tend to concentrate heavy isotopes in one...

The Pliocene and Pleistocene sediments at lease block Green Canyon 955 (GC955) in the Gulf of Mexico include sand-rich strata with high saturations of gas hydrate; these gas hydrate accumulations and the associated geology have been characterized over the past decade using conventional industry three-dimensional (3D) seismic data and dedicated logging-while-drilling (LWD) borehole data...

In 2017, the U.S. Geological Survey (USGS) completed an updated assessment of undiscovered, technically recoverable oil and gas resources in the Spraberry Formation of the Midland Basin (Permian Basin Province) in southwestern Texas (Marra and others, 2017). The Spraberry Formation was assessed using both the standard continuous (unconventional) and conventional methodologies established...