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Evaluation of tandem offline and online solid-phase extraction with liquid chromatography/electrospray ionization-mass spectrometry for the analysis of antibiotics in ambient water and comparision to an independent method Evaluation of tandem offline and online solid-phase extraction with liquid chromatography/electrospray ionization-mass spectrometry for the analysis of antibiotics in ambient water and comparision to an independent method

This report describes the performance of an offline tandem solid-phase extraction (SPE) method and an online SPE method that use liquid chromatography/mass spectrometry for the analysis of 23 and 35 antibiotics, respectively, as used in several water-quality surveys conducted since 1999. In the offline tandem SPE method, normalized concentrations for the quinolone, macrolide, and...
Authors
M. T. Meyer, E.A. Lee, G.M. Ferrell, J.E. Bumgarner, Jerry Varns

Water-Level Changes in the High Plains Aquifer, Predevelopment to 2005 and 2003 to 2005 Water-Level Changes in the High Plains Aquifer, Predevelopment to 2005 and 2003 to 2005

The High Plains aquifer underlies 111.4 million acres (174,000 square miles) in parts of eight States-Colorado, Kansas, Nebraska, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming. Water-level declines began in parts of the High Plains aquifer soon after the beginning of extensive ground-water irrigation. This report presents water-level changes in the High Plains aquifer from the...
Authors
V. L. McGuire

Harmful algal blooms Harmful algal blooms

What are Harmful Algal Blooms (HABs)? Freshwater and marine harmful algal blooms (HABs) can occur anytime water use is impaired due to excessive accumulations of algae. HAB occurrence is affected by a complex set of physical, chemical, biological, hydrological, and meteorological conditions making it difficult to isolate specific causative environmental factors. Potential impairments...
Authors
Jennifer L. Graham

Evidence for a physical linkage between galactic cosmic rays and regional climate time series Evidence for a physical linkage between galactic cosmic rays and regional climate time series

The effects of solar variability on regional climate time series were examined using a sequence of physical connections between total solar irradiance (TSI) modulated by galactic cosmic rays (GCRs), and ocean and atmospheric patterns that affect precipitation and streamflow. The solar energy reaching the Earth's surface and its oceans is thought to be controlled through an interaction...
Authors
C. A. Perry

Significant findings from a water-quality study on Prairie Band Potawatomi Reservation, northeastern Kansas, June 1996 through August 2006 Significant findings from a water-quality study on Prairie Band Potawatomi Reservation, northeastern Kansas, June 1996 through August 2006

Water-quality samples were collected from surface- (stream-) and ground-water sites on and near the Prairie Band Potawatomi Reservation in northeastern Kansas (fig. 1) from June 1996 through August 2006 as part of a cooperative study between the U.S. Geological Survey (USGS) and the Prairie Band Potawatomi Nation (Schmidt and others, 2007). Surface- and ground-water quality were...
Authors
Heidi E. Mehl, Heather C. Ross Schmidt, Larry M. Pope

Water quality on the Prairie Band Potawatomi Reservation, northeastern Kansas, June 1996 through August 2006 Water quality on the Prairie Band Potawatomi Reservation, northeastern Kansas, June 1996 through August 2006

This report describes surface- and ground-water-quality data collected on the Prairie Band Potawatomi Reservation in northeastern Kansas from November 2003 through August 2006 (hereinafter referred to as the "current study period"). Data from this study period are compared to results from June 1996 through August 2003, which are published in previous reports as part of a multiyear...
Authors
Heather C. Ross Schmidt, Heidi E. Mehl, Larry M. Pope

Warming may create substantial water supply shortages in the Colorado River basin Warming may create substantial water supply shortages in the Colorado River basin

The high demand for water, the recent multiyear drought (1999-2007), and projections of global warming have raised questions about the long-term sustainability of water supply in the southwestern United States. In this study, the potential effects of specific levels of atmospheric warming on water-year streamflow in the Colorado River basin are evaluated using a water-balance model, and...
Authors
G.J. McCabe, D.M. Wolock

Persistence of pharmaceuticals and other organic compounds in chlorinated drinking water as a function of time Persistence of pharmaceuticals and other organic compounds in chlorinated drinking water as a function of time

Ninety eight pharmaceuticals and other organic compounds (POOCs) that were amended to samples of chlorinated drinking-water were extracted and analyzed 1, 3, 6, 8, and 10 days after amendment to determine whether the total chlorine residual reacted with the amended POOCs in drinking water in a time frame similar to the residence time of drinking water in a water distribution system...
Authors
Jacob Gibs, Paul E. Stackelberg, Edward T. Furlong, Michael T. Meyer, Steven D. Zaugg, R.L. Lippincott

Microcystin distribution in physical size class separations of natural plankton communities Microcystin distribution in physical size class separations of natural plankton communities

Phytoplankton communities in 30 northern Missouri and Iowa lakes were physically separated into 5 size classes (>100 µm, 53-100 µm, 35-53 µm, 10-35 µm, 1-10 µm) during 15-21 August 2004 to determine the distribution of microcystin (MC) in size fractionated lake samples and assess how net collections influence estimates of MC concentration. MC was detected in whole water (total) from 83%...
Authors
J.L. Graham, J.R. Jones

Trace analysis of trimethoprim and sulfonamide, macrolide, quinolone, and tetracycline antibiotics in chlorinated drinking water using liquid chromatography electrospray tandem mass spectrometry Trace analysis of trimethoprim and sulfonamide, macrolide, quinolone, and tetracycline antibiotics in chlorinated drinking water using liquid chromatography electrospray tandem mass spectrometry

A multirun analytical method has been developed and validated for trace determination of 24 antibiotics including 7 sulfonamides, 3 macrolides, 7 quinolones, 6 tetracyclines, and trimethoprim in chlorine-disinfected drinking water using a single solid-phase extraction method coupled to liquid chromatography with positive electrospray tandem mass spectrometry detection. The analytes were...
Authors
Z. Ye, H.S. Weinberg, M. T. Meyer

Occurrence of Agricultural Chemicals in Shallow Ground Water and the Unsaturated Zone, Northeast Nebraska Glacial Till, 2002-04 Occurrence of Agricultural Chemicals in Shallow Ground Water and the Unsaturated Zone, Northeast Nebraska Glacial Till, 2002-04

Agricultural chemicals applied at the land surface in northeast Nebraska can move downward, past the crop root zone, to ground water. Because agricultural chemicals applied at the land surface are more likely to be observed in the shallowest part of an aquifer, an assessment of shallow ground-water and unsaturated zone quality in the northeast Nebraska glacial till was completed between...
Authors
Jennifer S. Stanton, Gregory V. Steele, Jason R. Vogel

Factors influencing ground-water recharge in the eastern United States Factors influencing ground-water recharge in the eastern United States

Ground-water recharge estimates for selected locations in the eastern half of the United States were obtained by Darcian and chloride-tracer methods and compared using statistical analyses. Recharge estimates derived from unsaturated-zone (RUZC) and saturated-zone (RSZC) chloride mass balance methods are less variable (interquartile ranges or IQRs are 9.5 and 16.1 cm/yr, respectively)...
Authors
B. T. Nolan, R. W. Healy, P.E. Taber, K. Perkins, K.J. Hitt, D.M. Wolock
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