Isotopic geochemistry of Panama rivers

River water samples collected from 78 watersheds rivers along a 500-km transect across a Late Cretaceous-Tertiary andesitic volcanic arc terrane in west-central Panama provide a synoptic overview of riverine geochemistry, chemical denudation, and CO₂ consumption in the tropics. D/H and ¹⁸O/¹⁶O relationships indicate that bedrock dissolution of andesitic arc crust in Panama is driven by water-rock interaction with meteoric precipitation as it passes through the critical zone, with no evidence of a geothermal or hydrothermal input. Sr-isotope relationships suggest a geochemical evolution for Panama riverine waters that involves mixing of bedrock pore water with water having ⁸⁷Sr/⁸⁶Sr ratios between 0.7037-0.7043 and relatively high Sr-contents with waters of low Sr content that enriched in radiogenic Sr that are diluted by infiltrating rainfall to variable extents.