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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 4098

Fate of acetone in an outdoor model stream with a nitrate supplement, southern Mississippi, U.S.A. Fate of acetone in an outdoor model stream with a nitrate supplement, southern Mississippi, U.S.A.

The fate of acetone in an outdoor model stream to which nitrate was added as a nutrient supplement was determined. The stream, in southern Mississippi, U.S.A. was 234 m long. Water was supplied to the stream by an artesian well at about 1.21 s−1, resulting in a mean water velocity of about 0.5 m min−1. Acetone was injected continuously for 26 days resulting in concentrations of 20–40 mg...
Authors
R. E. Rathbun, D. W. Stephens, D. Y. Tai

Electron transport in the dissimilatory iron reducer, GS-15 Electron transport in the dissimilatory iron reducer, GS-15

Mechanisms for electron transport to Fe(III) were investigated in GS-15, a novel anaerobic microorganism which can obtain energy for growth hy coupling the complete oxidation of organic acids or aromatic compounds to the reduction of Fe(III) to Fe(II). The results indicate that Fe(III) reduction proceeds through a type b cytochrome and a membrane-bound Fe(III) reductase which is distinct...
Authors
Y.A. Gorby, Derek R. Lovley

Methylmercury decomposition in sediments and bacterial cultures: Involvement of methanogens and sulfate reducers in oxidative demethylation Methylmercury decomposition in sediments and bacterial cultures: Involvement of methanogens and sulfate reducers in oxidative demethylation

Demethylation of monomethylmercury in freshwater and estuarine sediments and in bacterial cultures was investigated with 14CH3HgI. Under anaerobiosis, results with inhibitors indicated partial involvement of both sulfate reducers and methanogens, the former dominating estuarine sediments, while both were active in freshwaters. Aerobes were the most significant demethylators in estuarine...
Authors
R.S. Oremland, C.W. Culbertson, M.R. Winfrey

Importance of closely spaced vertical sampling in delineating chemical and microbiological gradients in groundwater studies Importance of closely spaced vertical sampling in delineating chemical and microbiological gradients in groundwater studies

Vertical gradients of selected chemical constituents, bacterial populations, bacterial activity and electron acceptors were investigated for an unconfined aquifer contaminated with nitrate and organic compounds on Cape Cod, Massachusetts, U.S.A. Fifteen-port multilevel sampling devices (MLS's) were installed within the contaminant plume at the source of the contamination, and at 250 and...
Authors
R. L. Smith, R.W. Harvey, D.R. LeBlanc

Denitrification in nitrate-contaminated groundwater: Occurrence in steep vertical geochemical gradients Denitrification in nitrate-contaminated groundwater: Occurrence in steep vertical geochemical gradients

A relatively narrow vertical zone (5–6 m thick) of NO3− containing groundwater was identified using multilevel sampling devices in a sand and gravel aquifer on Cape Cod, MA, USA. The aquifer has been chronically contaminated by surface disposal of treated sewage 0.3 km upgradient from the study area. The NO3− zone was anoxic and contained high concentrations of N2O (16.5 μM), suggesting...
Authors
R. L. Smith, B.L. Howes, J.H. Duff

MBSSAS: A code for the computation of margules parameters and equilibrium relations in binary solid-solution aqueous-solution systems MBSSAS: A code for the computation of margules parameters and equilibrium relations in binary solid-solution aqueous-solution systems

The computer code MBSSAS uses two-parameter Margules-type excess-free-energy of mixing equations to calculate thermodynamic equilibrium, pure-phase saturation, and stoichiometric saturation states in binary solid-solution aqueous-solution (SSAS) systems. Lippmann phase diagrams, Roozeboom diagrams, and distribution-coefficient diagrams can be constructed from the output data files, and...
Authors
P. D. Glynn

Brine evolution and mineral deposition in hydrologically open evaporite basins Brine evolution and mineral deposition in hydrologically open evaporite basins

A lumped-parameter, solute mass-balance model is developed to define the role of water outflow from a well-mixed basin. A mass-balance model is analyzed with a geochemical model designed for waters with high ionic strengths. Two typical waters, seawater and a Na-HCO3 ground water, are analyzed to illustrate the control that the leakage ratio (or hydrologic openness of the basin) has on...
Authors
W. E. Sanford, W.W. Wood

Large-scale distribution of metal contamination in the fine-grained sediments of the Clark Fork River, Montana, U.S.A. Large-scale distribution of metal contamination in the fine-grained sediments of the Clark Fork River, Montana, U.S.A.

Historic discharges from the mining and smelting complex at the head-waters of the Clark Fork River have resulted in elevated Ag, Cd, Cu, Pb and Zn concentrations in the
Authors
E.V. Axtmann, S. N. Luoma
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