Publications
Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).
Filter Total Items: 3785
Groundwater flow with energy transport and water-ice phase change: Numerical simulations, benchmarks, and application to freezing in peat bogs Groundwater flow with energy transport and water-ice phase change: Numerical simulations, benchmarks, and application to freezing in peat bogs
In northern peatlands, subsurface ice formation is an important process that can control heat transport, groundwater flow, and biological activity. Temperature was measured over one and a half years in a vertical profile in the Red Lake Bog, Minnesota. To successfully simulate the transport of heat within the peat profile, the U.S. Geological Survey's SUTRA computer code was modified...
Authors
J.M. McKenzie, Clifford I. Voss, D. I. Siegel
Centimeter-scale characterization of biogeochemical gradients at a wetland-aquifer interface using capillary electrophoresis Centimeter-scale characterization of biogeochemical gradients at a wetland-aquifer interface using capillary electrophoresis
Steep biogeochemical gradients were measured at mixing interfaces in a wetland-aquifer system impacted by landfill leachate in Norman, Oklahoma. The system lies within a reworked alluvial plain and is characterized by layered low hydraulic conductivity wetland sediments interbedded with sandy aquifer material. Using cm-scale passive diffusion samplers, "peepers", water samples were...
Authors
S. Baez-Cazull, J.T. McGuire, Isabelle M. Cozzarelli, A. Raymond, L. Welsh
Effects of flow diversions on water and habitat quality: Examples from California's highly manipulated Sacramento–San Joaquin Delta Effects of flow diversions on water and habitat quality: Examples from California's highly manipulated Sacramento–San Joaquin Delta
We use selected monitoring data to illustrate how localized water diversions from seasonal barriers, gate operations, and export pumps alter water quality across the Sacramento-San Joaquin Delta (California). Dynamics of water-quality variability are complex because the Delta is a mixing zone of water from the Sacramento and San Joaquin Rivers, agricultural return water, and the San...
Authors
Nancy E. Monsen, James E. Cloern, Jon R. Burau
Separation of copper, iron, and zinc from complex aqueous solutions for isotopic measurement Separation of copper, iron, and zinc from complex aqueous solutions for isotopic measurement
The measurement of Cu, Fe, and Zn isotopes in natural samples may provide valuable information about biogeochemical processes in the environment. However, the widespread application of stable Cu, Fe, and Zn isotope chemistry to natural water systems remains limited by our ability to efficiently separate these trace elements from the greater concentrations of matrix elements. In this...
Authors
David M. Borrok, Richard B. Wanty, William I. Ridley, Ruth E. Wolf, Paul J. Lamothe, M. Adams
Contaminated salmon and the public's trust Contaminated salmon and the public's trust
Scientific uncertainties often make it difficult for environmental policy makers to determine how to communicate risks to the public. A constructive, holistic, multisectoral dialogue about an issue can improve understanding of uncertainties from different perspectives and clarify options for risk communication. Many environmental issues could benefit from explicit promotion of such a...
Authors
Samuel N. Luoma, Ragnar E. Lofstedt
A simulation-based approach for estimating premining water quality: Red Mountain Creek, Colorado A simulation-based approach for estimating premining water quality: Red Mountain Creek, Colorado
Regulatory agencies are often charged with the task of setting site-specific numeric water quality standards for impaired streams. This task is particularly difficult for streams draining highly mineralized watersheds with past mining activity. Baseline water quality data obtained prior to mining are often non-existent and application of generic water quality standards developed for...
Authors
Robert L. Runkel, Briant A Kimball, Katherine Walton-Day, Philip L. Verplanck
Accumulation of dechlorination daughter products: A valid metric of chloroethene biodegradation Accumulation of dechlorination daughter products: A valid metric of chloroethene biodegradation
In situ reductive dechlorination of perchloroethene (PCE) and trichloroethene (TCE) generates characteristic chlorinated (cis-dichloroethene [cis-DCE] and vinyl chloride [VC]) and nonchlorinated (ethene and ethane) products. The accumulation of these daughter products is commonly used as a metric for ongoing biodegradation at field sites. However, this interpretation assumes that...
Authors
Paul M. Bradley, Frank H. Chapelle
Hydrology and subsurface transport of oil-field brine at the U.S. Geological Survey OSPER site "A", Osage County, Oklahoma Hydrology and subsurface transport of oil-field brine at the U.S. Geological Survey OSPER site "A", Osage County, Oklahoma
Spillage and improper disposal of saline produced water from oil wells has caused environmental damage at thousands of sites in the United States. In order to improve understanding of the fate and transport of contaminants at these sites, the U.S. Geological Survey carried out multidisciplinary investigations at two oil production sites near Skiatook Lake, Oklahoma. As a part of this...
Authors
William N. Herkelrath, Yousif K. Kharaka, James J. Thordsen, Marvin M. Abbott
Evasion of added isotopic mercury from a northern temperate lake Evasion of added isotopic mercury from a northern temperate lake
Isotopically enriched Hg (90% 202Hg) was added to a small lake in Ontario, Canada, at a rate equivalent to approximately threefold the annual direct atmospheric deposition rate that is typical of the northeastern United States. The Hg spike was thoroughly mixed into the epilimnion in nine separate events at two-week intervals throughout the summer growing season for three consecutive...
Authors
G. Southworth, S. Lindberg, H. Hintelmann, M. Amyot, A. Poulain, M. Bogle, M. Peterson, J. Rudd, R. Harris, K. Sandilands, David P. Krabbenhoft, Mark L. Olsen
Quantification of changes in metal loading from storm runoff, Merse River (Tuscany, Italy) Quantification of changes in metal loading from storm runoff, Merse River (Tuscany, Italy)
The Merse River in Tuscany is affected by mine drainage and the weathering of mine wastes along several kilometres of its catchment. The metal loading to the stream was quantified by defining detailed profiles of discharge and concentration, using tracer-dilution and synoptic-sampling techniques. During the course of a field experiment to evaluate metal loading to the Merse, such data...
Authors
Briant A. Kimball, F. Bianchi, Katherine Walton-Day, Robert L. Runkel, M. Nannucci, A. Salvadori
Effects of sorbate speciation on sorption of selected sulfonamides in three loamy soils Effects of sorbate speciation on sorption of selected sulfonamides in three loamy soils
Sorption of sulfamethazine (SMN) and sulfathiazole (STZ) was investigated in three soils, a North Carolina loamy sand, an Iowa sandy loam, and a Missouri loam, under various pH conditions. A significant increase in the sorption coefficient (KD) was observed in all three soils, as the sulfonamides converted from an anionic form at higher pH to a neutral/cationic form at lower pH. Above pH...
Authors
Sudarshan T. Kurwadkar, Craig D. Adams, Michael T. Meyer, Dana W. Kolpin
Mercury speciation in piscivorous fish from mining-impacted reservoirs Mercury speciation in piscivorous fish from mining-impacted reservoirs
Guadalupe Reservoir (GUA), California, and Lahontan Reservoir (LAH), Nevada, U.S. are both affected either directly or indirectly by the legacy of gold and silver mining in the Sierra Nevada during the nineteenth century. Analysis of total mercury in fish from these lentic systems consistently indicate elevated concentrations (>1 μg·g-1 wet weight; hereinafter, all concentrations are...
Authors
James S. Kuwabara, Yuji Arai, Brent R. Topping, I.J. Pickering, G.N. George