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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3785

Mercury speciation in piscivorous fish from mining-impacted reservoirs Mercury speciation in piscivorous fish from mining-impacted reservoirs

Guadalupe Reservoir (GUA), California, and Lahontan Reservoir (LAH), Nevada, U.S. are both affected either directly or indirectly by the legacy of gold and silver mining in the Sierra Nevada during the nineteenth century. Analysis of total mercury in fish from these lentic systems consistently indicate elevated concentrations (>1 μg·g-1 wet weight; hereinafter, all concentrations are...
Authors
James S. Kuwabara, Yuji Arai, Brent R. Topping, I.J. Pickering, G.N. George

Simple predictions of maximum transport rate in unsaturated soil and rock Simple predictions of maximum transport rate in unsaturated soil and rock

In contrast with the extreme variability expected for water and contaminant fluxes in the unsaturated zone, evidence from 64 field tests of preferential flow indicates that the maximum transport speed Vmax, adjusted for episodicity of infiltration, deviates little from a geometric mean of 13 m/d. A model based on constant‐speed travel during infiltration pulses of actual or estimated...
Authors
John R. Nimmo

Oxygen and chlorine isotopic fractionation during perchlorate biodegradation: Laboratory results and implications for forensics and natural attenuation studies Oxygen and chlorine isotopic fractionation during perchlorate biodegradation: Laboratory results and implications for forensics and natural attenuation studies

Perchlorate is a widespread environmental contaminant having both anthropogenic and natural sources. Stable isotope ratios of O and Cl in a given sample of perchlorate may be used to distinguish its source(s). Isotopic ratios may also be useful for identifying the extent of biodegradation of perchlorate, which is critical for assessing natural attenuation of this contaminant in...
Authors
Neil C. Sturchio, John Karl Bohlke, Abelardo D. Beloso, S.H. Streger, Linnea J. Heraty, Paul B. Hatzinger

Freshwater-saltwater transition zone movement during aquifer storage and recovery cycles in Brooklyn and Queens, New York City, USA Freshwater-saltwater transition zone movement during aquifer storage and recovery cycles in Brooklyn and Queens, New York City, USA

Freshwater storage in deep aquifers of Brooklyn and Queens, New York, USA, is under consideration as an emergency water supply for New York City. The purpose of a New York City storage and recovery system is to provide an emergency water supply during times of drought or other contingencies and would entail longer-term storage phases than a typical annual cycle. There is concern amongst
Authors
Paul E. Misut, Clifford I. Voss

Concentrations of metals in water, sediment, biofilm, benthic macroinvertebrates, and fish in the Boulder River watershed, Montana, and the role of colloids in metal uptake Concentrations of metals in water, sediment, biofilm, benthic macroinvertebrates, and fish in the Boulder River watershed, Montana, and the role of colloids in metal uptake

To characterize the partitioning of metals in a stream ecosystem, concentrations of trace metals including As, Cd, Cu, Pb, and Zn were measured in water, colloids, sediment, biofilm (also referred to as aufwuchs), macroinvertebrates, and fish collected from the Boulder River watershed, Montana. Median concentrations of Cd, Cu, and Zn in water throughout the watershed exceeded the U.S...
Authors
Aida Farag, David A. Nimick, Briant A. Kimball, Stanley E. Church, David D. Harper, William G. Brumbaugh

Reconstructing sediment age profiles from historical bathymetry changes in San Pablo Bay, California Reconstructing sediment age profiles from historical bathymetry changes in San Pablo Bay, California

Sediment age profiles reconstructed from a sequence of historical bathymetry changes are used to investigate the subsurface distribution of historical sediments in a subembayment of the San Francisco Estuary. Profiles are created in a grid-based GIS modeling program that stratifies historical deposition into temporal horizons. The model's reconstructions are supported by comparisons to...
Authors
Shawn A. Higgins, Bruce E. Jaffe, Christopher C. Fuller

Influence of in-stream diel concentration cycles of dissolved trace metals on acute toxicity to one-year-old cutthroat trout (Oncorhynchus clarki lewisi) Influence of in-stream diel concentration cycles of dissolved trace metals on acute toxicity to one-year-old cutthroat trout (Oncorhynchus clarki lewisi)

Extrapolating results of laboratory bioassays to streams is difficult, because conditions such as temperature and dissolved metal concentrations can change substantially on diel time scales. Field bioassays conducted for 96 h in two mining‐affected streams compared the survival of hatchery‐raised, metal‐näive westslope cutthroat trout (Oncorhynchus clarki lewisi) exposed to dissolved (0...
Authors
David A. Nimick, David D. Harper, Aida Farag, Tom Cleasby, Elizabeth MacConnell, D. Skaar

Influence of groundwater pumping on streamflow restoration following upstream dam removal Influence of groundwater pumping on streamflow restoration following upstream dam removal

We compared streamflow in basins under the combined impacts of an upland dam and groundwater pumping withdrawals, by examining streamflow in the presence and absence of each impact. As a qualitative analysis, inter-watershed streamflow comparisons were performed for several rivers flowing into the east side of the Central Valley, CA. Results suggest that, in the absence of upland dams...
Authors
James E. Constantz, Hedeff I. Essaid

Nitrate dynamics within the Pajaro River, a nutrient-rich, losing stream Nitrate dynamics within the Pajaro River, a nutrient-rich, losing stream

The major ion chemistry of water from an 11.42-km reach of the Pajaro River, a losing stream in central coastal California, shows a consistent pattern of higher concentrations during the 2nd (dry) half of the water year. Most solutes are conserved during flow along the reach, but [NO3−] decreases by ~30% and is accompanied by net loss of channel discharge and extensive surface–subsurface...
Authors
C.R. Ruehl, A.T. Fisher, Huertos M. Los, Scott D. Wankel, C.G. Wheat, Carol Kendall, C.E. Hatch, C. Shennan

Characterizing dissolved Cu and Cd uptake in terms of the biotic ligand and biodynamics using enriched stable isotopes Characterizing dissolved Cu and Cd uptake in terms of the biotic ligand and biodynamics using enriched stable isotopes

The biotic ligand model considers the biological and geochemical complexities that affect metal exposure. It relates toxicity to the fraction of physiological active sites impacted by reactive metal species. The biodynamic model is a complementary construct that predicts bioaccumulation and assumes that toxicity occurs when influx rates exceed rates of loss and detoxification. In this...
Authors
Marie Noele Croteau, Samuel N. Luoma

Near infrared spectroscopic examination of charred pine wood, bark, cellulose and lignin: Implications for the quantitative determination of charcoal in soils Near infrared spectroscopic examination of charred pine wood, bark, cellulose and lignin: Implications for the quantitative determination of charcoal in soils

The objective of this research was to investigate the effect of charring on near infrared spectra of materials likely to be present in forest fires in order to determine the feasibility of determining charred carbon in soils. Four materials (cellulose, lignin, pine bark and pine wood) and char from these materials created by charring for various durations (1 to 168 h) and at various...
Authors
James B. Reeves, Gregory W. McCarty, David W. Rutherford, Robert L. Wershaw
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