Publications

The methods documented in this report are utilized by the Wisconsin District Mercury Lab for analysis of total mercury in solids (soils and sediments) and suspended solids (isolated on filters). Separate procedures are required for the different sample types. For solids, samples are prepared by room-temperature acid digestion and oxidation with aqua regia. The samples are brought up to...

Denitrification was measured within a nitrate‐contaminated aquifer on Cape Cod, Massachusetts, using natural gradient tracer tests with 15N nitrate. The aquifer contained zones of relatively high concentrations of nitrite (up to 77 μM) and nitrous oxide (up to 143 μM) and has been the site of previous studies examining ground water denitrification using the acetylene block technique...

Water samples from short-screen monitoring wells installed along a 90-km transect in southwestern Kansas were analyzed for major ions, trace elements, isotopes (H, B, C, N, O, S, Sr), and dissolved gases (He, Ne, N2, Ar, O2, CH4) to evaluate the geochemistry, radiocarbon ages, and paleorecharge conditions in the unconfined central High Plains aquifer. The primary reactions controlling...

Classical treatment of cell attachment by models of filtration or coulombic attraction assumes that attachment of cells to mineral surfaces would be controlled by factors such as response to predation, collision efficiency, or coulombic attraction between the charged groups at the mineral and cell surfaces. In the study reported here, the passive model of attachment was investigated...

Analytical models commonly used to interpret unconfined aquifer tests have been based on upper-boundary (water table) conditions that do not adequately address effects of time-varying drainage from the vadose zone. As a result, measured and simulated drawdown data may not agree and hydraulic parameters may be inaccurately estimated. A 72-hour aquifer test conducted in Cape Cod...

The color theory conceived and commercialized by Albert H. Munsell (1858-1918) has become a universal part of the lexicon of soil science. An American painter noted for his seascapes and portraits, he had a long-standing interest in the description of color. Munsell began studies aimed at standardizing color description, using hue, value, and chroma scales, around 1898. His landmark...

Ground waters from fractured igneous and high‐grade sialic metamorphic rocks frequently have elevated activity of dissolved radon (222Rn). A chemically based model is proposed whereby radium (226Ra) from the decay of uranium (238U) diffuses through the primary porosity of the rock to the water‐transmitting fracture where it is sorbed on weathering products. Sorption of 226Ra on the...

Experimental data for uranium adsorption on a complex weathered rock were simulated by twelve modelling teams from eight countries using surface complexation (SC) models. This intercomparison was part of an international project to evaluate the present capabilities and limitations of SC models in representing sorption by geologic materials. The models were assessed in terms of their...

Bacteria in soil microcosm experiments oxidized elevated levels of methyl chloride (MeCl) and methyl bromide (MeBr), the former compound more rapidly than the latter. MeBr was also removed by chemical reactions while MeCl was not. Chemical degradation dominated the early removal of MeBr and accounted for more than half of its total loss. Fractionation of stable carbon isotopes during...

PRD1, an icosahedra-shaped, 62 nm (diameter), double-stranded DNA bacteriophage with an internal membrane, has emerged as an important model virus for studying the manner in which microorganisms are transported through a variety of groundwater environments. The popularity of this phage for use in transport studies involving geologic media is due, in part, to its relative stability over a...

Cross-hole and surface-to-borehole radar and conventional borehole geophysical logs were used to monitor subsurface injections of vegetable oil emulsion conducted as part of a field-scale biostimulation pilot project at the Anoka County Riverfront Park (ACP), located downgradient of the Naval Industrial Reserve Ordnance Plant (NIROP), in Fridley, Minnesota. The pilot project was...

The U.S. Geological Survey Reconstructed Trends National Synthesis study collected sediment cores from 56 lakes and reservoirs between 1992 and 2001 across the United States. Most of the sampling was conducted as part of the National Water-Quality Assessment (NAWQA) Program. The primary objective of the study was to determine trends in particle-associated contaminants in response to...