Publications

Many published studies have used visual comparison of the timing of peak breakthrough of colloids versus conservative dissolved tracers (hereafter referred to as dissolved tracers or tracers) in subsurface media to determine whether they are advected differently, and to elucidate the mechanisms of differential advection. This purely visual approach of determining differential advection...

The concentration and distribution of inorganic Hg was measured using cold-vapor atomic fluorescence spectrometry in samples collected at selected sites on the Sacramento River from below Shasta Dam to Freeport, CA, at six separate times between 1996 and 1997. Dissolved (ultrafiltered, 0.005 μm equivalent pore size) Hg concentrations remained relatively constant throughout the system...

Advances in technology have resulted in a new instrument that is designed for in-situ determination of particle size spectra. Such an instrument that can measure undisturbed particle size distributions is much needed for sediment transport studies. The LISST-100 (Laser In-Situ Scattering and Transmissometry) uses the principle of laser diffraction to obtain the size distribution and...

The redox speciation of dissolved iron and the transport of iron in acidic, metal‐enriched streams is controlled by precipitation and dissolution of iron hydroxides, by photoreduction of dissolved ferric iron and hydrous iron oxides, and by oxidation of the resulting dissolved ferrous iron. We examined the pH dependence of these processes in an acidic mine‐drainage stream, St Kevin Gulch...

A laboratory bioassay determined the relative contribution of various pathways of Ag, Cd and Zn bioaccumulation in the marine polychaete Neanthes arenaceodentata exposed to moderately contaminated sediments. Juvenile worms were exposed for 25 d to experimental sediments containing 5 different reactive sulfide (acid volatile sulfides, AVS) concentrations (1 to 30 ??mol g-1), but with...

Current and historical data show that nitrogen concentrations and flux in the Mississippi River Basin have increased significantly during the past 100 years. Most of the increase observed in the lower Mississippi River has occurred since the early 1970s and is due almost entirely to an increase in nitrate. The current (1980-99) average annual nitrogen (N) flux from the Mississippi Basin...

Riverine particulate organic matter (POM) samples were collected bi‐weekly to monthly from 40 sites in the Mississippi, Colorado, Rio Grande, and Columbia River Basins (USA) in 1996–97 and analysed for carbon and nitrogen stable isotopic compositions. These isotopic compositions and C : N ratios were used to identify four endmember sources of POM: plankton, fresh terrestrial plant...

Three pilot studies were performed to assess application of the eddy covariance micrometeorological method in the measurement of carbon dioxide (CO2) flux of volcanic origin. The selected study area is one of high diffuse CO2 emission on Mammoth Mountain, CA. Because terrain and source characteristics make this a complex setting for this type of measurement, added consideration was given...

We studied the chemical and optical changes inthe dissolved organic matter (DOM) from twofreshwater lakes and a Sphagnum bog afterexposure to solar radiation. Stable carbonisotopes and solid-state 13C-NMR spectraof DOM were used together with optical andchemical data to interpret results fromexperimental exposures of DOM to sunlight andfrom seasonal observations of two lakes...

An evaluation of over 75 pesticides by high-performance liquid chromatography/mass spectrometry (HPLC/MS) clearly shows that different classes of pesticides are more sensitive using either atmospheric pressure chemical ionization (APCI) or electrospray ionization (ESI). For example, neutral and basic pesticides (phenylureas, triazines) are more sensitive using APCI (especially positive...

Negatively charged functional groups of fulvic acid compete with inorganic sulfide ion for mercury ion binding. This competition is evaluated here by using a discrete site-electrostatic model to calculate mercury solution speciation in the presence of fulvic acid. Model calculated species distributions are used to estimate a mercury-fulvic acid apparent binding constant to quantify...

Recharge areas of spring systems can be hard to identify, but they can be critically important for protection of a spring resource. A recharge area for a spring complex in southern Wisconsin was delineated using a variety of complementary techniques. A telescopic mesh refinement (TMR) model was constructed from an existing regional-scale ground water flow model. This TMR model was...