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Publications

Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).

Filter Total Items: 3785

A log-normal distribution model for the molecular weight of aquatic fulvic acids A log-normal distribution model for the molecular weight of aquatic fulvic acids

The molecular weight of humic substances influences their proton and metal binding, organic pollutant partitioning, adsorption onto minerals and activated carbon, and behavior during water treatment. We propose a lognormal model for the molecular weight distribution in aquatic fulvic acids to provide a conceptual framework for studying these size effects. The normal curve mean and...
Authors
S.E. Cabaniss, Q. Zhou, P.A. Maurice, Y.-P. Chin, G. R. Aiken

Age of irrigation water in ground water from the Eastern Snake River Plain Aquifer, south-central Idaho Age of irrigation water in ground water from the Eastern Snake River Plain Aquifer, south-central Idaho

Stable isotope data (2H and 18O) were used in conjunction with chlorofluorocarbon (CFC) and tritium/helium-3 (3H/3He) data to determine the fraction and age of irrigation water in ground water mixtures from farmed parts of the Eastern Snake River Plain (ESRP) Aquifer in south-central Idaho. Two groups of waters were recognized: (1) regional background water, unaffected by irrigation and...
Authors
Niel Plummer, M.G. Rupert, E. Busenberg, P. Schlosser

Pesticides in the atmosphere of the Mississippi River Valley, part II: Air Pesticides in the atmosphere of the Mississippi River Valley, part II: Air

Weekly composite air samples were collected from early April through to mid-September 1995 at three paired urban and agricultural sites along the Mississippi River region of the Midwestern United States. The paired sampling sites were located in Mississippi, Iowa, and Minnesota. A background site, removed from dense urban and agricultural areas, was located on the shore of Lake Superior...
Authors
W.T. Foreman, M.S. Majewski, D. A. Goolsby, F.W. Wiebe, R.H. Coupe

Ion exchange separation of chromium from natural water matrix for stable isotope mass spectrometric analysis Ion exchange separation of chromium from natural water matrix for stable isotope mass spectrometric analysis

A method has been developed for separating the Cr dissolved in natural water from matrix elements and determination of its stable isotope ratios using solid-source thermal-ionization mass spectrometry (TIMS). The separation method takes advantage of the existence of the oxidized form of Cr as an oxyanion to separate it from interfering cations using anion-exchange chromatography, and of...
Authors
J.W. Ball, R.L. Bassett

Occurrence of sulfonylurea, sulfonamide, imidazolinone, and other herbicides in rivers, reservoirs and ground water in the Midwestern United States, 1998 Occurrence of sulfonylurea, sulfonamide, imidazolinone, and other herbicides in rivers, reservoirs and ground water in the Midwestern United States, 1998

Sulfonylurea (SU), sulfonamide (SA), and imidazolinone (IMI) herbicides are relatively new classes of chemical compounds that function by inhibiting the action of a plant enzyme, stopping plant growth, and eventually killing the plant. These compounds generally have low mammalian toxicity, but plants demonstrate a wide range in sensitivity to SUs, SAs, and IMIs with over a 10 000-fold...
Authors
W.A. Battaglin, E. T. Furlong, M.R. Burkhardt, C.J. Peter

Occurrence of cotton herbicides and insecticides in playa lakes of the High Plains of West Texas Occurrence of cotton herbicides and insecticides in playa lakes of the High Plains of West Texas

During the summer of 1997, water samples were collected and analyzed for pesticides from 32 playa lakes of the High Plains that receive drainage from both cotton and corn agriculture in West Texas. The major cotton herbicides detected in the water samples were diuron, fluometuron, metolachlor, norflurazon, and prometryn. Atrazine and propazine, corn and sorghum herbicides, were also...
Authors
E.M. Thurman, K.C. Bastian, T. Mollhagen

Changes in herbicide concentrations in Midwestern streams in relation to changes in use, 1989-1998 Changes in herbicide concentrations in Midwestern streams in relation to changes in use, 1989-1998

Water samples were collected from Midwestern streams in 1994–1995 and 1998 as part of a study to help determine if changes in herbicide use resulted in changes in herbicide concentrations since a previous reconnaissance study in 1989–1990. Sites were sampled during the first significant runoff period after the application of pre-emergent herbicides in 1989–1990, 1994–1995, and 1998...
Authors
E.A. Scribner, W.A. Battaglin, D. A. Goolsby, E.M. Thurman

Negative pH and extremely acidic mine waters from Iron Mountain, California Negative pH and extremely acidic mine waters from Iron Mountain, California

Extremely acidic mine waters with pH values as low as -3.6, total dissolved metal concentrations as high as 200 g/L, and sulfate concentrations as high as 760 g/L, have been encountered underground in the Richmond Mine at Iron Mountain, CA. These are the most acidic waters known. The pH measurements were obtained by using the Pitzer method to define pH for calibration of glass membrane...
Authors
D. Kirk Nordstrom, Charles N. Alpers, C.J. Ptacek, D.W. Blowes

Metal exposure in a benthic macroinvertebrate, Hydropsyche californica, related to mine drainage in the Sacramento River Metal exposure in a benthic macroinvertebrate, Hydropsyche californica, related to mine drainage in the Sacramento River

A biomonitoring technique was employed to complement studies of metal transport in the upper Sacramento River affected by acid mine drainage. Metals (Al, Cd, Cu, Fe, Hg, Pb, and Zn) were determined in a resident invertebrate, Hydropsyche californica (Insecta: Trichoptera), and streambed sediments (
Authors
Daniel J. Cain, James L. Carter, Steven V. Fend, Samuel N. Luoma, Charles N. Alpers, Howard E. Taylor

Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida

In an area of mixed agricultural land use in Suwannee and Lafayette Counties of northern Florida, water samples were collected monthly from 14 wells tapping the Upper Floridan aquifer during July 1998 through June 1999 to assess hydrologic and land-use factors affecting the variability in nitrate concentrations in ground water. Unusually high amounts of rainfall in September and October...
Authors
Brian G. Katz, J.K. Böhlke
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