Analysis of groundwater geochemistry in the Lansing, Michigan, area

Groundwater resources in the Lansing, Michigan, area are protected by a wellhead protection plan, but previous studies have indicated that groundwater in this area may be susceptible to surface contamination. The U.S. Geological Survey, in cooperation with the Lansing Board of Water & Light, analyzed geochemical and aquifer characteristics to assess the potential for contamination of groundwater resources. Recharge age categories were determined from tritium concentrations for some wells, and by using ternary diagrams and principal component analysis for other wells. These age classifications, combined with hydrogeologic and geochemical data, were analyzed by using statistical methods to identify trends that may indicate areas of increased groundwater susceptibility. Wells with modern recharge tended to have higher sodium, chloride, and chloride:bromide ratios than did wells with mixed recharge, suggesting greater surface connectivity and potential influence from anthropogenic sources such as road salt. In contrast, wells in the mixed age category exhibited more stable geochemistry and lower constituent concentrations. Classification and regression tree models identified aquifer geometry—particularly the thickness of the uppermost bedrock unit and presence of confining layers—as key predictors of recharge age and geochemical indicators. The trends identified from these analyses could help to reveal locations in the Lansing area that are among the most susceptible to contamination.