Iron-titanium oxide minerals and magnetic susceptibility anomalies in the Mariano Lake-Lake Valley cores-Constraints on conditions of uranium mineralization in the Morrison Formation, San Juan Basin, New Mexico

Petrographic study of the Mariano Lake-Lake Valley cores reveals three distinct zones of postdepositional alteration of detrital Fe-Ti (iron-titanium) oxide minerals in the Westwater Canyon Member of the Upper Jurassic Morrison Formation. In the uranium-bearing and adjacent portions of the Westwater Canyon, these detrital Fe-Ti oxide minerals have been thoroughly altered by leaching of iron. Stratigraphically lower parts of the Westwater Canyon and the underlying Recapture Member are characterized by preservation of Fe-Ti oxide grains, primarily magnetite and ilmenite, and of hematite, and by an absence of uranium concentrations. Partly destroyed Fe-Ti oxide minerals occupy an interval between the zones of destruction and preservation. Alteration patterns of the Fe-Ti oxide minerals are reflected in bore-hole magnetic susceptibility logs. Magnetic susceptibility response in the upper parts of the Westwater Canyon Member is flat and uniformly < 500 /xSI units, but at greater depths it fluctuates sharply, from <1,000 to nearly 8,000 μSI units. The boundary between uniformly low and high magnetic susceptibility response corresponds closely to the interval that divides the zone of completely altered from the zone of preserved detrital Fe-Ti oxide minerals. The alteration pattern suggests that solutions responsible for destruction of the Fe-Ti oxide minerals originated in the overlying Brushy Basin Member of the Morrison Formation. Previous studies indicate that these solutions were rich in soluble organic matter and perhaps in uranium. Uranium precipitation may have been controlled by a vertically fluctuating interface between organic-rich solutions and geochemically different fluids in which the detrital Fe-Ti oxide minerals were preserved.