Mark Sandstrom, Ph.D. (Former Employee)
Science and Products
Filter Total Items: 53
A field study of selected U.S. Geological Survey analytical methods for measuring pesticides in filtered stream water, June - September 2012
U.S. Geological Survey monitoring programs extensively used two analytical methods, gas chromatography/mass spectrometry and liquid chromatography/mass spectrometry, to measure pesticides in filtered water samples during 1992–2012. In October 2012, the monitoring programs began using direct aqueous-injection liquid chromatography tandem mass spectrometry as a new analytical method for pesticides.
Authors
Jeffrey D. Martin, Julia E. Norman, Mark W. Sandstrom, Claire E. Rose
Complex mixtures of Pesticides in Midwest U.S. streams indicated by POCIS time-integrating samplers
The Midwest United States is an intensely agricultural region where pesticides in streams pose risks to aquatic biota, but temporal variability in pesticide concentrations makes characterization of their exposure to organisms challenging. To compensate for the effects of temporal variability, we deployed polar organic chemical integrative samplers (POCIS) in 100 small streams across the Midwest fo
Authors
Peter C. Van Metre, David Alvarez, Barbara Mahler, Lisa H. Nowell, Mark W. Sandstrom, Patrick W. Moran
Determination of heat purgeable and ambient purgeable volatile organic compounds in water by gas chromatography/mass spectrometry
Two new analytical methods have been developed by the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL) that allow the determination of 37 heat purgeable volatile organic compounds (VOCs) (USGS Method O-4437-16 [NWQL Laboratory Schedule (LS) 4437]) and 49 ambient purgeable VOCs (USGS Method O-4436-16 [NWQL LS 4436]) in unfiltered water. This report documents the procedures and
Authors
Donna L. Rose, Mark W. Sandstrom, Lucinda K. Murtagh
Determination of pesticides and pesticide degradates in filtered water by direct aqueous-injection liquid chromatography-tandem mass spectrometry
A liquid chromatography-tandem mass spectrometry (LC-MS/MS) method was developed for determination of 229 pesticides compounds (113 pesticides and 116 pesticide degradates) in filtered water samples from stream and groundwater sites. The pesticides represent a broad range of chemical classes and were selected based on criteria such as current-use intensity, probability of occurrence in streams and
Authors
Mark W. Sandstrom, Leslie K. Kanagy, Cyrissa A. Anderson, Christopher J. Kanagy
Design, analysis, and interpretation of field quality-control data for water-sampling projects
The process of obtaining and analyzing water samples from the environment includes a number of steps that can affect the reported result. The equipment used to collect and filter samples, the bottles used for specific subsamples, any added preservatives, sample storage in the field, and shipment to the laboratory have the potential to affect how accurately samples represent the environment from wh
Authors
David K. Mueller, Terry L. Schertz, Jeffrey D. Martin, Mark W. Sandstrom
Occurrence of pesticides in groundwater and sediments and mineralogy of sediments and grain coatings underlying the Rutgers Agricultural Research and Extension Center, Upper Deerfield, New Jersey, 2007
Water and sediment samples were collected from June through October 2007 from seven plots at the Rutgers Agricultural Research and Extension Center in Upper Deerfield, New Jersey, and analyzed for a suite of pesticides (including fungicides) and other physical and chemical parameters (including sediment mineralogy) by the U.S. Geological Survey. Plots were selected for inclusion in this study on t
Authors
Timothy J. Reilly, Kelly L. Smalling, Michael T. Meyer, Mark W. Sandstrom, Michelle Hladik, Adam R. Boehlke, Neil S. Fishman, William A. Battaglin, Kathryn Kuivila
Chapter A2. Selection of equipment for water sampling
The National Field Manual for the Collection of Water-Quality Data (National Field Manual) describes protocols and provides guidelines for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation's surface-water and ground-water resources. This chapter of the manual addresses the selection of equipment commonly used by USGS personnel to collect and process
Authors
Franceska D. Wilde, Mark W. Sandstrom, Stanley C. Skrobialowski
Chapter A5. Section 2.2B. Syringe-Filter Procedure for Processing Samples for Analysis of Organic Compounds by DAI LC-MS/MS
This section of chapter 5 of the National Field Manual for the Collection of Water-Quality Data (NFM) describes the field procedures for collecting small-volume samples using a syringe-tip filtration method. The samples are sent to the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL) for analysis of organic compounds by direct aqueous injection high-performance liquid chromat
Authors
Mark W. Sandstrom, Franceska D. Wilde
Chemical contaminants in water and sediment near fish nesting sites in the Potomac River basin: determining potential exposures to smallmouth bass (Micropterus dolomieu)
The Potomac River basin is an area where a high prevalence of abnormalities such as testicular oocytes (TO), skin lesions, and mortality has been observed in smallmouth bass (SMB, Micropterus dolomieu). Previous research documented a variety of chemicals in regional streams, implicating chemical exposure as one plausible explanation for these biological effects. Six stream sites in the Potomac bas
Authors
Dana W. Kolpin, Vicki Blazer, James L. Gray, Michael J. Focazio, John A. Young, David A. Alvarez, Luke R. Iwanowicz, William T. Foreman, Edward T. Furlong, Gary K. Speiran, Steven D. Zaugg, Laura E. Hubbard, Michael T. Meyer, Mark W. Sandstrom, Larry B. Barber
Occurrence and persistence of fungicides in bed sediments and suspended solids from three targeted use areas in the United States
To document the environmental occurrence and persistence of fungicides, a robust and sensitive analytical method was used to measure 34 fungicides and an additional 57 current-use pesticides in bed sediments and suspended solids collected from areas of intense fungicide use within three geographic areas across the United States. Sampling sites were selected near or within agricultural research far
Authors
Kelly L. Smalling, Timothy J. Reilly, Mark W. Sandstrom, Kathryn Kuivila
Persistence and potential effects of complex organic contaminant mixtures in wastewater-impacted streams
Natural and synthetic organic contaminants in municipal wastewater treatment plant (WWTP) effluents can cause ecosystem impacts, raising concerns about their persistence in receiving streams. In this study, Lagrangian sampling, in which the same approximate parcel of water is tracked as it moves downstream, was conducted at Boulder Creek, Colorado and Fourmile Creek, Iowa to determine in-stream tr
Authors
Larry B. Barber, Steffanie H. Keefe, Greg K. Brown, Edward T. Furlong, James L. Gray, Dana W. Kolpin, Michael T. Meyer, Mark W. Sandstrom, Steven D. Zaugg
Simulation of branched serial first-order decay of atrazine and metabolites in adapted and nonadapted soils
In the present study a branched serial first-order decay (BSFOD) model is presented and used to derive transformation rates describing the decay of a common herbicide, atrazine, and its metabolites observed in unsaturated soils adapted to previous atrazine applications and in soils with no history of atrazine applications. Calibration of BSFOD models for soils throughout the country can reduce the
Authors
Richard M. Webb, Mark W. Sandstrom, L. Jason Krutz, Dale L. Shaner
Science and Products
Filter Total Items: 53
A field study of selected U.S. Geological Survey analytical methods for measuring pesticides in filtered stream water, June - September 2012
U.S. Geological Survey monitoring programs extensively used two analytical methods, gas chromatography/mass spectrometry and liquid chromatography/mass spectrometry, to measure pesticides in filtered water samples during 1992–2012. In October 2012, the monitoring programs began using direct aqueous-injection liquid chromatography tandem mass spectrometry as a new analytical method for pesticides.
Authors
Jeffrey D. Martin, Julia E. Norman, Mark W. Sandstrom, Claire E. Rose
Complex mixtures of Pesticides in Midwest U.S. streams indicated by POCIS time-integrating samplers
The Midwest United States is an intensely agricultural region where pesticides in streams pose risks to aquatic biota, but temporal variability in pesticide concentrations makes characterization of their exposure to organisms challenging. To compensate for the effects of temporal variability, we deployed polar organic chemical integrative samplers (POCIS) in 100 small streams across the Midwest fo
Authors
Peter C. Van Metre, David Alvarez, Barbara Mahler, Lisa H. Nowell, Mark W. Sandstrom, Patrick W. Moran
Determination of heat purgeable and ambient purgeable volatile organic compounds in water by gas chromatography/mass spectrometry
Two new analytical methods have been developed by the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL) that allow the determination of 37 heat purgeable volatile organic compounds (VOCs) (USGS Method O-4437-16 [NWQL Laboratory Schedule (LS) 4437]) and 49 ambient purgeable VOCs (USGS Method O-4436-16 [NWQL LS 4436]) in unfiltered water. This report documents the procedures and
Authors
Donna L. Rose, Mark W. Sandstrom, Lucinda K. Murtagh
Determination of pesticides and pesticide degradates in filtered water by direct aqueous-injection liquid chromatography-tandem mass spectrometry
A liquid chromatography-tandem mass spectrometry (LC-MS/MS) method was developed for determination of 229 pesticides compounds (113 pesticides and 116 pesticide degradates) in filtered water samples from stream and groundwater sites. The pesticides represent a broad range of chemical classes and were selected based on criteria such as current-use intensity, probability of occurrence in streams and
Authors
Mark W. Sandstrom, Leslie K. Kanagy, Cyrissa A. Anderson, Christopher J. Kanagy
Design, analysis, and interpretation of field quality-control data for water-sampling projects
The process of obtaining and analyzing water samples from the environment includes a number of steps that can affect the reported result. The equipment used to collect and filter samples, the bottles used for specific subsamples, any added preservatives, sample storage in the field, and shipment to the laboratory have the potential to affect how accurately samples represent the environment from wh
Authors
David K. Mueller, Terry L. Schertz, Jeffrey D. Martin, Mark W. Sandstrom
Occurrence of pesticides in groundwater and sediments and mineralogy of sediments and grain coatings underlying the Rutgers Agricultural Research and Extension Center, Upper Deerfield, New Jersey, 2007
Water and sediment samples were collected from June through October 2007 from seven plots at the Rutgers Agricultural Research and Extension Center in Upper Deerfield, New Jersey, and analyzed for a suite of pesticides (including fungicides) and other physical and chemical parameters (including sediment mineralogy) by the U.S. Geological Survey. Plots were selected for inclusion in this study on t
Authors
Timothy J. Reilly, Kelly L. Smalling, Michael T. Meyer, Mark W. Sandstrom, Michelle Hladik, Adam R. Boehlke, Neil S. Fishman, William A. Battaglin, Kathryn Kuivila
Chapter A2. Selection of equipment for water sampling
The National Field Manual for the Collection of Water-Quality Data (National Field Manual) describes protocols and provides guidelines for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation's surface-water and ground-water resources. This chapter of the manual addresses the selection of equipment commonly used by USGS personnel to collect and process
Authors
Franceska D. Wilde, Mark W. Sandstrom, Stanley C. Skrobialowski
Chapter A5. Section 2.2B. Syringe-Filter Procedure for Processing Samples for Analysis of Organic Compounds by DAI LC-MS/MS
This section of chapter 5 of the National Field Manual for the Collection of Water-Quality Data (NFM) describes the field procedures for collecting small-volume samples using a syringe-tip filtration method. The samples are sent to the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL) for analysis of organic compounds by direct aqueous injection high-performance liquid chromat
Authors
Mark W. Sandstrom, Franceska D. Wilde
Chemical contaminants in water and sediment near fish nesting sites in the Potomac River basin: determining potential exposures to smallmouth bass (Micropterus dolomieu)
The Potomac River basin is an area where a high prevalence of abnormalities such as testicular oocytes (TO), skin lesions, and mortality has been observed in smallmouth bass (SMB, Micropterus dolomieu). Previous research documented a variety of chemicals in regional streams, implicating chemical exposure as one plausible explanation for these biological effects. Six stream sites in the Potomac bas
Authors
Dana W. Kolpin, Vicki Blazer, James L. Gray, Michael J. Focazio, John A. Young, David A. Alvarez, Luke R. Iwanowicz, William T. Foreman, Edward T. Furlong, Gary K. Speiran, Steven D. Zaugg, Laura E. Hubbard, Michael T. Meyer, Mark W. Sandstrom, Larry B. Barber
Occurrence and persistence of fungicides in bed sediments and suspended solids from three targeted use areas in the United States
To document the environmental occurrence and persistence of fungicides, a robust and sensitive analytical method was used to measure 34 fungicides and an additional 57 current-use pesticides in bed sediments and suspended solids collected from areas of intense fungicide use within three geographic areas across the United States. Sampling sites were selected near or within agricultural research far
Authors
Kelly L. Smalling, Timothy J. Reilly, Mark W. Sandstrom, Kathryn Kuivila
Persistence and potential effects of complex organic contaminant mixtures in wastewater-impacted streams
Natural and synthetic organic contaminants in municipal wastewater treatment plant (WWTP) effluents can cause ecosystem impacts, raising concerns about their persistence in receiving streams. In this study, Lagrangian sampling, in which the same approximate parcel of water is tracked as it moves downstream, was conducted at Boulder Creek, Colorado and Fourmile Creek, Iowa to determine in-stream tr
Authors
Larry B. Barber, Steffanie H. Keefe, Greg K. Brown, Edward T. Furlong, James L. Gray, Dana W. Kolpin, Michael T. Meyer, Mark W. Sandstrom, Steven D. Zaugg
Simulation of branched serial first-order decay of atrazine and metabolites in adapted and nonadapted soils
In the present study a branched serial first-order decay (BSFOD) model is presented and used to derive transformation rates describing the decay of a common herbicide, atrazine, and its metabolites observed in unsaturated soils adapted to previous atrazine applications and in soils with no history of atrazine applications. Calibration of BSFOD models for soils throughout the country can reduce the
Authors
Richard M. Webb, Mark W. Sandstrom, L. Jason Krutz, Dale L. Shaner