Deciphering natural and anthropogenic nitrate and recharge sources in arid region groundwater

Recently, the subsoils of ephemeral stream (arroyos) floodplains in the northern Chihuahuan Desert were discovered to contain large naturally occurring NO₃⁻ reservoirs (floodplain: ~38,000 kg NO₃-N/ha; background: ~60 kg NO₃-N/ha). These reservoirs may be mobilized through land use change or natural stream channel migration which makes differentiating between anthropogenic and natural groundwater NO₃⁻ sources challenging. In this study, the fate and sources of NO₃⁻ were investigated in an area with multiple NO₃⁻ sources such as accidental sewer line releases and sewage lagoons as well as natural reservoirs of subsoil NO₃⁻. To differentiate sources, this study used a large suite of geochemical tools including δ¹⁵N[NO₃], δ¹⁸O[NO₃], δ¹⁵N[N₂], δ¹³C[DIC], ¹⁴C, tritium (³H), dissolved gas concentrations, major ion chemistry, and contaminants of emerging concern (CEC) including artificial sweeteners. NO₃⁻ at sites with the highest concentrations (25 to 229 mg/L NO₃-N) were determined to be largely sourced from naturally occurring subsoil NO₃⁻ based on δ¹⁵N[NO₃] (1.5). Anthropogenic NO₃⁻ was deciphered using mass ratios of Cl⁻/Br⁻ (>120) and NO₃⁻/Cl⁻ (8 ‰), and CEC detections. Nitrogen isotope analyses indicated that denitrification is fairly limited in the field area. CEC were detected at 67 % of sites including ³H dead sites (