Corrosivity describes how aggressive water is at corroding pipes and fixtures. Corrosive water can cause lead and copper in pipes to leach into drinking water and can eventually cause leaks in plumbing. Surface water and groundwater, both sources of drinking water, can potentially be corrosive.
► All About Corrosivity - Potential Corrosivity of Untreated Groundwater report and FAQ
Corrosion in water-distribution systems is a costly problem, and controlling corrosion is one of the most important ways that concentrations of lead (Pb) and copper (Cu) can be reduced in tap water. Naturally corrosive water is not dangerous to consume in itself, but it can cause health-related problems by reacting with pipes and plumbing fixtures in homes. If plumbing materials contain lead or copper, corrosive water can cause these metals to leach into the water supply. Signs that corrosive water is causing leaching of metals may include bluish-green stains in sinks, metallic taste of water, and small leaks in plumbing fixtures.
The USGS National Water-Quality Assessment (NAWQA) Project has been studying where and why surface water and groundwater that are sources of drinking water are corrosive. Many factors contribute to corrosivity, including elevated concentrations of chloride, pH out of neutral range, elevated concentrations of dissolved and suspended solids, and lower alkalinity. The potential for water to be corrosive is measured by three different indexes: the Langelier Saturation Index (LSI), the Potential to Promote Galvanic Corrosion (PPGC), and the Larson Ratio (LR).
- The LSI is a measure of the balance between pH and calcium carbonate (CaCO3)—as the LSI value becomes more negative, the water is increasingly under-saturated with CaCO3 and therefore has a greater corrosion potential.
- The PPGC is based on the ratio of chloride to sulfate; the higher the PPGC, the greater the potential for galvanic corrosion of lead in the plumbing system.
- The LR is defined as defined as the sum of equivalents of chloride and sulfate divided by equivalents of bicarbonate. The LR indicates the corrosivity of water to iron and steel.
Surface Water
Chloride, PPGC, and LR have been increasing in urban streams across much of the United States, and especially in the most snowy areas in the study, which are most likely to use road salt. In a study of trends in chloride and indexes of corrosivity, seasonal changes in chloride, CSMR, and LR varied greatly among sites, and site-specific conditions make it difficult to generalize seasonal patterns in corrosivity. However, water-quality monitoring protocols do not emphasize characterization of the seasonal or long-term changes in surface water corrosivity or metal release, and corrosion driven by changes in chloride concentration, CSMR, or LR would not be detected under regulatory requirements or typical voluntary monitoring.
Groundwater
An assessment by the NAWQA Project of more than 20,000 wells nationwide showed that 25 states have groundwater that either has high or very high potential to be corrosive. The states with the largest percentage of wells with potentially corrosive groundwater are located primarily in the Northeast, the Southeast, and the Northwest. About 24 million people in these areas rely upon groundwater from private water systems for their source of drinking water. Read more about the assessment here.
All about corrosivity
Chloride, Salinity, and Dissolved Solids
Metals and Other Trace Elements
Classification of Chloride-to-Sulfate Mass Ratio for U.S. Groundwater With Respect to the Potential to Promote Galvanic Corrosion of Lead, 1991-2015; Water Well Data and Characteristic Values for States
Langelier Saturation Indices Computed for U.S. Groundwater, 1991-2015; Water Well Data and Characteristic Values for States
Want to take a deep dive into the topic of corrosivity? Access the publications below.
Potential corrosivity of untreated groundwater in the United States
Machine learning predictions of pH in the Glacial Aquifer System, Northern USA
Increasing chloride in rivers of the conterminous U.S. and linkages to potential corrosivity and lead action level exceedances in drinking water
Domestic groundwater wells in the eastern and southeastern U.S. at risk of lead contamination
About one-third of more than 8,300 wells tested across the U.S. had groundwater with chemical characteristics that could cause lead, if present in plumbing, to leach into tap water at levels above the EPA Action Level, according to a new study by the U.S. Geological Survey National Water Quality Program. These characteristics are most common in groundwater in the East and Southeast.
- Overview
Corrosivity describes how aggressive water is at corroding pipes and fixtures. Corrosive water can cause lead and copper in pipes to leach into drinking water and can eventually cause leaks in plumbing. Surface water and groundwater, both sources of drinking water, can potentially be corrosive.
Corrosion on water tap ► All About Corrosivity - Potential Corrosivity of Untreated Groundwater report and FAQ
Corrosion in water-distribution systems is a costly problem, and controlling corrosion is one of the most important ways that concentrations of lead (Pb) and copper (Cu) can be reduced in tap water. Naturally corrosive water is not dangerous to consume in itself, but it can cause health-related problems by reacting with pipes and plumbing fixtures in homes. If plumbing materials contain lead or copper, corrosive water can cause these metals to leach into the water supply. Signs that corrosive water is causing leaching of metals may include bluish-green stains in sinks, metallic taste of water, and small leaks in plumbing fixtures.
The USGS National Water-Quality Assessment (NAWQA) Project has been studying where and why surface water and groundwater that are sources of drinking water are corrosive. Many factors contribute to corrosivity, including elevated concentrations of chloride, pH out of neutral range, elevated concentrations of dissolved and suspended solids, and lower alkalinity. The potential for water to be corrosive is measured by three different indexes: the Langelier Saturation Index (LSI), the Potential to Promote Galvanic Corrosion (PPGC), and the Larson Ratio (LR).
- The LSI is a measure of the balance between pH and calcium carbonate (CaCO3)—as the LSI value becomes more negative, the water is increasingly under-saturated with CaCO3 and therefore has a greater corrosion potential.
- The PPGC is based on the ratio of chloride to sulfate; the higher the PPGC, the greater the potential for galvanic corrosion of lead in the plumbing system.
- The LR is defined as defined as the sum of equivalents of chloride and sulfate divided by equivalents of bicarbonate. The LR indicates the corrosivity of water to iron and steel.
See Increasing chloride in rivers of the conterminous U.S. for more information. (Graphic by Edward Stets, USGS) Surface Water
Chloride, PPGC, and LR have been increasing in urban streams across much of the United States, and especially in the most snowy areas in the study, which are most likely to use road salt. In a study of trends in chloride and indexes of corrosivity, seasonal changes in chloride, CSMR, and LR varied greatly among sites, and site-specific conditions make it difficult to generalize seasonal patterns in corrosivity. However, water-quality monitoring protocols do not emphasize characterization of the seasonal or long-term changes in surface water corrosivity or metal release, and corrosion driven by changes in chloride concentration, CSMR, or LR would not be detected under regulatory requirements or typical voluntary monitoring.
Potential for groundwater corrosivity in groundwater wells in all 50 states. (From Potential corrosivity of untreated groundwater in the United States, USGS Scientific Investigations Report 2016-5092.) Groundwater
An assessment by the NAWQA Project of more than 20,000 wells nationwide showed that 25 states have groundwater that either has high or very high potential to be corrosive. The states with the largest percentage of wells with potentially corrosive groundwater are located primarily in the Northeast, the Southeast, and the Northwest. About 24 million people in these areas rely upon groundwater from private water systems for their source of drinking water. Read more about the assessment here.
- Science
All about corrosivity
A U.S. Geological Survey assessment of more than 20,000 wells nationwide shows that untreated groundwater in 25 states has a high prevalence of being potentially corrosive. The states with the largest percentage of wells with potentially corrosive groundwater are located primarily in the Northeast, the Southeast, and the Northwest. These FAQs were written in conjunction with that study. In...Chloride, Salinity, and Dissolved Solids
All natural waters contain some dissolved solids (salinity) from contact with soils, rocks, and other natural materials. Too much, though, and dissolved solids can impair water use. Unpleasant taste, high water-treatment costs, mineral accumulation in plumbing, staining, corrosion, and restricted use for irrigation are among the problems associated with elevated concentrations of dissolved solids.Metals and Other Trace Elements
Metals, metalloids, and radionuclides all are trace elements that occur naturally in the Earth's crust. In small quantities many trace elements are essential for health in all living organisms, but some trace elements can be toxic or cause cancer, and some can bioaccumulate. The USGS investigates where and how trace elements make their way into our Nation's surface water and groundwater. - Data
Classification of Chloride-to-Sulfate Mass Ratio for U.S. Groundwater With Respect to the Potential to Promote Galvanic Corrosion of Lead, 1991-2015; Water Well Data and Characteristic Values for States
Galvanic corrosion of lead in water distribution systems can occur when lead pipe or lead solder is in contact with a dissimilar metal such as copper. If the source water entering those systems has a relatively elevated chloride-to-sulfate mass ratio (CSMR), the potential for galvanic corrosion to occur is elevated (Gregory 1985; Edwards and Triantafyllidou, 2007), especially in water with low valLangelier Saturation Indices Computed for U.S. Groundwater, 1991-2015; Water Well Data and Characteristic Values for States
The occurrence of metals, such as lead and copper, in household drinking supplies can often be a result of the corrosion of pipes and joints in water distribution systems. One measure of the potential for water to cause corrosion is the Langelier Saturation Index (LSI) (Langelier, 1936). The LSI is a measure of the potential for water to deposit a mineral layer (scale) within a water distribution - Multimedia
- Publications
Want to take a deep dive into the topic of corrosivity? Access the publications below.
Potential corrosivity of untreated groundwater in the United States
Corrosive groundwater, if untreated, can dissolve lead and other metals from pipes and other components in water distribution systems. Two indicators of potential corrosivity—the Langelier Saturation Index (LSI) and the Potential to Promote Galvanic Corrosion (PPGC)—were used to identify which areas in the United States might be more susceptible to elevated concentrations of metals in household drAuthorsKenneth Belitz, Bryant C. Jurgens, Tyler D. JohnsonMachine learning predictions of pH in the Glacial Aquifer System, Northern USA
A boosted regression tree model was developed to predict pH conditions in three dimensions throughout the glacial aquifer system of the contiguous United States using pH measurements in samples from 18,386 wells and predictor variables that represent aspects of the hydrogeologic setting. Model results indicate that the carbonate content of soils and aquifer materials strongly controls pH and, whenAuthorsPaul Stackelberg, Kenneth Belitz, Craig J. Brown, Melinda L. Erickson, Sarah M. Elliott, Leon J. Kauffman, Katherine Marie Ransom, James E. ReddyIncreasing chloride in rivers of the conterminous U.S. and linkages to potential corrosivity and lead action level exceedances in drinking water
Corrosion in water-distribution systems is a costly problem and controlling corrosion is a primary focus of efforts to reduce lead (Pb) and copper (Cu) in tap water. High chloride concentrations can increase the tendency of water to cause corrosion in distribution systems. The effects of chloride are also expressed in several indices commonly used to describe the potential corrosivity of water, thAuthorsEdward G. Stets, Casey J. Lee, Darren A. Lytle, Michael R. Schock - News
Domestic groundwater wells in the eastern and southeastern U.S. at risk of lead contamination
About one-third of more than 8,300 wells tested across the U.S. had groundwater with chemical characteristics that could cause lead, if present in plumbing, to leach into tap water at levels above the EPA Action Level, according to a new study by the U.S. Geological Survey National Water Quality Program. These characteristics are most common in groundwater in the East and Southeast.