Publications

Experimental studies demonstrate that structural Fe(II) in magnetite and ilmenite heterogeneously reduce aqueous ferric, cupric, vanadate, and chromate ions at the oxide surfaces over a pH range of 1–7 at 25°C. For an aqueous transition metal m, such reactions are3[Fe2+Fe23+]O4(magnetite)+2/nmz→4[Fe23+]O3(magnetite)+Fe2++2/nmz−n and3[Fe2+Ti]O3(ilmenite)+2/nmz→Fe23+Ti3O9(pseudorutile)+Fe2...

Pulse-chase experiments show that two marine bivalves take optimal advantage of different types of particulate food by varying food retention time in a flexible two-phase digestive system. For example, carbon is efficiently assimilated from bacteria by subjecting nearly all the ingested bacteria to prolonged digestion. Prolonging digestion also enhances assimilation of metals, many of...

This report presents a model, MOC3D, that simulates three-dimensional solute transport in flowing ground water. The model computes changes in concentration of a single dissolved chemical constituent over time that are caused by advective transport, hydrodynamic dispersion (including both mechanical dispersion and diffusion), mixing (or dilution) from fluid sources, and mathematically...

No abstract available.

Spatial and temporal distributions of specific conductance, boron, and phosphorus were determined in a sewage-contaminated sand and gravel aquifer near Ashumet Pond, Cape Cod, Massachusetts. The source of contamination is secondarily treated sewage that has been discharged onto rapid- infiltration sand beds at the Massachusetts Military Reservation since 1936. Contaminated ground water...

Quantitative analysis of geophysical logs in ground-water studies often involves at least as broad a range of applications and variation in lithology as is typically encountered in petroleum exploration, making such logs difficult to calibrate and complicating inversion problem formulation. At the same time, data inversion and analysis depend on inversion model formulation and refinement...

Although water from 20 to 25% of shallow farmstead wells in northern Missouri has concentrations of nitrate (NO3/-) exceeding 10 mg L-1 as nitrogen (N), many potential sources for this NO3/- are usually present. A field experiment was designed to trace and isolate the amount of a single application of N fertilizer lost to a glacial-till aquifer and runoff from a 400 m2 corn (Zea mays L.)...

Irrigated agriculture has a long history in the Western United States, beginning with Native American Indians. After passage of the Reclamation Act of 1902, the United States Government began building and subsidizing irrigation projects to foster settlement and development of the arid and semi-arid areas of the Western United States (National Research Council, 1989). Precipitation in the

Improvements in the field sampling, preservation, and determination of trace metals in natural waters have made many analyses more reliable and less affected by contamination. The speciation of trace metals, however, remains controversial. Chemical model speciation calculations do not necessarily agree with voltammetric, ion exchange, potentiometric, or other analytical speciation...

Ground-water withdrawal from a confined or semiconfined aquifer causes three-dimensional deformation in the pumped aquifer and in adjacent layers (overlying and underlying aquifers and aquitards). In response to the deformation, hydraulic head in the adjacent layers could rise or fall almost immediately after the start of pumping. This deformation-induced effect suggest that an adjacent...

Nonlinear regression is useful in ground-water flow parameter estimation, but problems of parameter insensitivity and correlation often exist given commonly available hydraulic-head and head-dependent flow (for example, stream and lake gain or loss) observations. To address this problem, advective-transport observations are added to the ground-water flow, parameter-estimation model...

Solute transport simulations quantitatively constrained hydrologic and geochemical hypotheses about field observations of a pH modification in an acid mine drainage stream. Carbonate chemistry, the formation of solid phases, and buffering interactions with the stream bed were important factors in explaining the behavior of pH, aluminum, and iron. The precipitation of microcrystalline...