Publications

We exposed 3 benthic invertebrates, the clam Macoma balthica, the polychaete Neanthes arenaceodentataand the amphipod Leptocheirus plumulosus, to Ag-contaminated sediments to evaluate the relative importance of various uptake routes (sediments, porewater or overlying water, and supplementary food) for Ag bioaccumulation. Silver bioaccumulation was evaluated at 4 levels of sediment Ag (0...

The color theory conceived and commercialized by Albert H. Munsell (1858-1918) has become a universal part of the lexicon of soil science. An American painter noted for his seascapes and portraits, he had a long-standing interest in the description of color. Munsell began studies aimed at standardizing color description, using hue, value, and chroma scales, around 1898. His landmark...

Bacteria in soil microcosm experiments oxidized elevated levels of methyl chloride (MeCl) and methyl bromide (MeBr), the former compound more rapidly than the latter. MeBr was also removed by chemical reactions while MeCl was not. Chemical degradation dominated the early removal of MeBr and accounted for more than half of its total loss. Fractionation of stable carbon isotopes during...

Ground waters from fractured igneous and high‐grade sialic metamorphic rocks frequently have elevated activity of dissolved radon (222Rn). A chemically based model is proposed whereby radium (226Ra) from the decay of uranium (238U) diffuses through the primary porosity of the rock to the water‐transmitting fracture where it is sorbed on weathering products. Sorption of 226Ra on the...

The extent to which winter precipitation is orographically enhanced within the Sierra Nevada of California varies from storm to storm, and season to season, from occasions when precipitation rates at low and high altitudes are almost the same to instances when precipitation rates at middle elevations (considered here) can be as much as 30 times more than at the base of the range...

Experimental data for uranium adsorption on a complex weathered rock were simulated by twelve modelling teams from eight countries using surface complexation (SC) models. This intercomparison was part of an international project to evaluate the present capabilities and limitations of SC models in representing sorption by geologic materials. The models were assessed in terms of their...

The computer program PHAST simulates multi-component, reactive solute transport in three-dimensional saturated ground-water flow systems. PHAST is a versatile ground-water flow and solute-transport simulator with capabilities to model a wide range of equilibrium and kinetic geochemical reactions. The flow and transport calculations are based on a modified version of HST3D that is...

Analyses of the benthic community structure of a mudflat in South San Francisco Bay over a 29-year period show that changes in the community have occurred concurrent with reduced concentrations of metals in the sediment and in the tissues of the biosentinal clam Macoma balthica from the same area. The community has shifted from being dominated by several opportunistic species to a...

Suspended-sediment samples were obtained from sites along the Mississippi River and its principal tributaries to determine the presence of halogenated hydrophobic organic compounds on the suspended sediment smaller than 63 micrometers. Sample collection involved pumping discharge-weighted volumes of river water along a cross section of the river into a continuous-flow centrifuge to...

Electrical resistivity tomography (ERT) is examined as a method to provide spatially continuous information about aquifer properties through imaging of tracer flow and transport in an unconfined aquifer. Field data were collected at the Massachusetts Military Reservation, Cape Cod, Massachusetts, during the summer of 2002. High resolution images in both space and time of the movement of...

Crosswell radar tomography methods can be used to dynamically image ground-water flow and mass transport associated with tracer tests, hydraulic tests, and natural physical processes. Dynamic imaging can be used to identify preferential flow paths and to help characterize complex aquifer heterogeneity. Unfortunately, because the raypath coverage of the interwell region is limited by the...

One of the major water-quality problems in the Chesapeake Bay is an overabundance of nutrients from the streams and rivers that discharge to the Bay. Some of these nutrients are from nonpoint sources such as atmospheric deposition, agricultural manure and fertilizer, and septic systems. The effects of efforts to control nonpoint sources, however, can be difficult to quantify because of...