Publications
Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).
Filter Total Items: 3784
Spatial and temporal distribution of specific conductance, boron, and phosphorus in a sewage-contaminated aquifer near Ashumet Pond, Cape Cod, Massachusetts Spatial and temporal distribution of specific conductance, boron, and phosphorus in a sewage-contaminated aquifer near Ashumet Pond, Cape Cod, Massachusetts
Spatial and temporal distributions of specific conductance, boron, and phosphorus were determined in a sewage-contaminated sand and gravel aquifer near Ashumet Pond, Cape Cod, Massachusetts. The source of contamination is secondarily treated sewage that has been discharged onto rapid- infiltration sand beds at the Massachusetts Military Reservation since 1936. Contaminated ground water...
Authors
K.W. Bussey, D. A. Walter
Flexible digestion strategies and trace metal assimilation in marine bivalves Flexible digestion strategies and trace metal assimilation in marine bivalves
Pulse-chase experiments show that two marine bivalves take optimal advantage of different types of particulate food by varying food retention time in a flexible two-phase digestive system. For example, carbon is efficiently assimilated from bacteria by subjecting nearly all the ingested bacteria to prolonged digestion. Prolonging digestion also enhances assimilation of metals, many of...
Authors
Alan W. Decho, Samuel N. Luoma
Reduction of aqueous transition metal species on the surfaces of Fe(II)-containing oxides Reduction of aqueous transition metal species on the surfaces of Fe(II)-containing oxides
Experimental studies demonstrate that structural Fe(II) in magnetite and ilmenite heterogeneously reduce aqueous ferric, cupric, vanadate, and chromate ions at the oxide surfaces over a pH range of 1–7 at 25°C. For an aqueous transition metal m, such reactions are3[Fe2+Fe23+]O4(magnetite)+2/nmz→4[Fe23+]O3(magnetite)+Fe2++2/nmz−n and3[Fe2+Ti]O3(ilmenite)+2/nmz→Fe23+Ti3O9(pseudorutile)+Fe2...
Authors
A. F. White, M. L. Peterson
Movement of nitrate fertilizer to glacial till and runoff from a claypan soil Movement of nitrate fertilizer to glacial till and runoff from a claypan soil
Although water from 20 to 25% of shallow farmstead wells in northern Missouri has concentrations of nitrate (NO3/-) exceeding 10 mg L-1 as nitrogen (N), many potential sources for this NO3/- are usually present. A field experiment was designed to trace and isolate the amount of a single application of N fertilizer lost to a glacial-till aquifer and runoff from a 400 m2 corn (Zea mays L.)...
Authors
D. W. Blevins, D.H. Wilkison, B. P. Kelly, S. R. Silva
Nitrate reduction in sediments of lowland tropical streams draining swamp forest in Costa Rica: An ecosystem perspective Nitrate reduction in sediments of lowland tropical streams draining swamp forest in Costa Rica: An ecosystem perspective
Nitrate reduction and denitrification were measured in swamp forest streams draining lowland rain forest on Costa Rica's Atlantic slope foothills using the C2H2-block assay and sediment-water nutrient fluxes. Denitrification assays using the C2H2-block technique indicated that the full suite of denitrifying enzymes were present in the sediment but that only a small fraction of the...
Authors
J.H. Duff, C. M. Pringle, F.J. Triska
Inferring shallow groundwater flow in saprolite and fractured rock using environmental tracers Inferring shallow groundwater flow in saprolite and fractured rock using environmental tracers
The Ridge and Valley Province of eastern Tennessee is characterized by (1) substantial topographic relief, (2) folded and highly fractured rocks of various lithologies that have low primary permeability and porosity, and (3) a shallow residuum of medium permeability and high total porosity. Conceptual models of shallow groundwater flow and solute transport in this system have been...
Authors
P.G. Cook, D. K. Solomon, W. E. Sanford, E. Busenberg, Niel Plummer, R.J. Poreda
Bacterial dissimilatory reduction of arsenic(V) to arsenic(III) in anoxic sediments Bacterial dissimilatory reduction of arsenic(V) to arsenic(III) in anoxic sediments
Incubation of anoxic salt marsh sediment slurries with 10 mM As(V) resulted in the disappearance over time of the As(V) in conjunction with its recovery as As(III). No As(V) reduction to As(III) occurred in heat- sterilized or formalin-killed controls or in live sediments incubated in air. The rate of As(V) reduction in slurries was enhanced by addition of the electron donor lactate, H2...
Authors
P.R. Dowdle, A.M. Laverman, R.S. Oremland
Water-quality data for nutrients, pesticides, and volatile organic compounds in near-surface aquifers of the midcontinental United States, 1992-1994 Water-quality data for nutrients, pesticides, and volatile organic compounds in near-surface aquifers of the midcontinental United States, 1992-1994
Water samples were collected from 175 wells in 12 Midcontinental States (Illinois, Indiana, Iowa, Kansas, Michigan, Minnesota, Missouri, Nebraska, North Dakota, Ohio, South Dakota, Wisconsin) from 1992 through 1994 to determine the spatial distribution of nutrients, pesticides, and volatile organic compounds in ground water, and to document the potential effects of the historic flooding...
Authors
D.W. Kolpin, K.E. Zichelle, E.M. Thurman
Importance of dissolved sulfides and organic substances in controlling the chemical speciation of heavy metals in San Francisco Bay Importance of dissolved sulfides and organic substances in controlling the chemical speciation of heavy metals in San Francisco Bay
No abstract available.
Authors
J.S. Kuwabara, C.C.Y. Chang, A.I. Khechfe, Y.R. Hunter
Cadmium in the California Current system: Tracer of past and present upwelling Cadmium in the California Current system: Tracer of past and present upwelling
Over 100 samples were collected off the west coast of North America during 1991–1993 to determine the relation between wind‐driven upwelling and nearshore concentrations of dissolved silicate (Si), phosphate (P), and cadmium (Cd). Highly enriched in deep water offshore, these constituents are sensitive indicators of upwelling. Coastal water was sampled from the shore in January and June...
Authors
A. VanGeen, D.M. Husby
Uranium adsorption on ferrihydrite - Effects of phosphate and humic acid Uranium adsorption on ferrihydrite - Effects of phosphate and humic acid
Uranium adsorption on ferrihydrite was studied as a function of pH in systems equilibrated with air, in the presence and absence of added phosphate and humic acid (HA). The objective was to determine the influence of PO43- and HA on uranium uptake. Below pH 7, the sorption of UO22+ typically increases with increasing pH (the 'low pH sorption edge'), with a sharp decrease in sorption...
Authors
T.E. Payne, J.A. Davis, T.D. Waite
Kinetic determinations of trace element bioaccumulation in the mussel Mytilus edulis Kinetic determinations of trace element bioaccumulation in the mussel Mytilus edulis
Laboratory experiments employing radiotracer methodology were conducted to determine the assimilation efficiencies from ingested natural seston, the influx rates from the dissolved phase and the efflux rates of 6 trace elements (Ag, Am, Cd, Co, Se and Zn) in the mussel Mytilus edulis. A kinetic model was then employed to predict trace element concentration in mussel tissues in 2...
Authors
W.-X. Wang, N.S. Fisher, S. N. Luoma