Publications
Dive into our publications and explore the science from the Environmental Health Program (Toxic Substances Hydrology and Contaminant Biology).
Filter Total Items: 3785
Bacteriophage PRD1 and silica colloid transport and recovery in an iron oxide-coated sand aquifer Bacteriophage PRD1 and silica colloid transport and recovery in an iron oxide-coated sand aquifer
Bacteriophage PRD1 and silica colloids were co-injected into sewage-contaminated and uncontaminated zones of an iron oxide-coated sand aquifer on Cape Cod, MA, and their transport was monitored over distances up to 6 m in three arrays. After deposition, the attached PRD1 and silica colloids were mobilized by three different chemical perturbations (elevated pH, anionic surfactant, and...
Authors
J. N. Ryan, M. Elimelech, R.A. Ard, R.W. Harvey, P.R. Johnson
Movement of road salt to a small New Hampshire lake Movement of road salt to a small New Hampshire lake
Runoff of road salt from an interstate highway in New Hampshire has led to contamination of a lake and a stream that flows into the lake, in spite of the construction of a diversion berm to divert road salt runoff out of the lake drainage basin. Chloride concentration in the stream has increased by over an order of magnitude during the 23 yr since the highway was opened, and chloride...
Authors
D.O. Rosenberry, P.A. Bukaveckas, D.C. Buso, G.E. Likens, A.M. Shapiro, T. C. Winter
The relationship between soil heterotrophic activity, soil dissolved organic carbon (DOC) leachate, and catchment-scale DOC export in headwater catchments The relationship between soil heterotrophic activity, soil dissolved organic carbon (DOC) leachate, and catchment-scale DOC export in headwater catchments
Dissolved organic carbon (DOC) from terrestrial sources forms the major component of the annual carbon budget in many headwater streams. In high-elevation catchments in the Rocky Mountains, DOC originates in the upper soil horizons and is flushed to the stream primarily during spring snowmelt. To identify controls on the size of the mobile soil DOC pool available to be transported during...
Authors
P. D. Brooks, Diane M. McKnight, K.E. Bencala
Distribution and transport of selected anthropogenic lipophilic organic compounds associated with Mississippi River suspended sediment, 1989-1990 Distribution and transport of selected anthropogenic lipophilic organic compounds associated with Mississippi River suspended sediment, 1989-1990
In the first study on this scale, distribution and transport of selected hydrophobic halogenated organic compounds associated with suspended sediment from the lower Mississippi River and its principal tributaries were determined during two spring and two summer cruises. Lipophilic organic compounds identified on the suspended sediment included hexachlorobenzene, pentachlorobenzene
Authors
C.E. Rostad, W. E. Pereira, T.J. Leiker
Oxidation of ammonia and methane in an alkaline, saline lake Oxidation of ammonia and methane in an alkaline, saline lake
The oxidation of ammonia (NH3) and methane (CH4) was investigated in an alkaline saline lake, Mono Lake, California (U.S.A.). Ammonia oxidation was examined in April and July 1995 by comparing dark 14CO2 fixation rates in the presence or absence of methyl fluoride (MeF), an inhibitor of NH3 oxidation. Ammonia oxidizer‐mediated dark 14CO2fixation rates were similar in surface (5–7 m) and...
Authors
S.B. Joye, T.L. Connell, L.G. Miller, R.S. Oremland, R.S. Jellison
Evaluation of the atmosphere as a source of volatile organic compounds in shallow groundwater Evaluation of the atmosphere as a source of volatile organic compounds in shallow groundwater
The atmosphere as a source of volatile organic compounds (VOCs) in shallow groundwater was evaluated over an area in southern New Jersey. Chloroform, methyl tertbutyl ether (MTBE), 1,1,1‐trichloroethane, tetrachloroethylene (PCE), and carbon disulfide (not a VOC) were detected frequently at low‐level concentrations in a network of 78 shallow wells in the surficial Kirkwood‐Cohansey...
Authors
Arthur L. Baehr, Paul E. Stackelberg, Ronald J. Baker
Aerobic mineralization of MTBE and tert-butyl alcohol by stream-bed sediment microorganisms Aerobic mineralization of MTBE and tert-butyl alcohol by stream-bed sediment microorganisms
Microorganisms indigenous to the stream-bed sediments at two gasoline- contaminated groundwater sites demonstrated significant mineralization of the fuel oxygenates, methyl tert-butyl ether (MTBE) and tert-butyl alcohol (TBA). Up to 73% of [U-14C]-MTBE and 84% of [U-14C]-TBA were degraded to 14CO2 under mixed aerobic/anaerobic conditions. No significant mineralization was observed under...
Authors
P. M. Bradley, J. E. Landmeyer, F. H. Chapelle
Metolachlor and its metabolites in tile drain and stream runoff in the canajoharie creek watershed Metolachlor and its metabolites in tile drain and stream runoff in the canajoharie creek watershed
Water samples collected during April−November 1997 from tile drains beneath cultivated fields in central New York indicate that two metabolites of the herbicide metolachlormetolachlor ESA (ethanesulfonic acid) and OA (oxanilic acid)can persist in agricultural soils for 4 or more years after application and that fine-grained soils favor the transport of metolachlor ESA over metolachlor...
Authors
P. J. Phillips, G. R. Wall, E.M. Thurman, D. A. Eckhardt, J. Vanhoesen
Historical trends of metals in the sediments of San Francisco Bay, California Historical trends of metals in the sediments of San Francisco Bay, California
Concentrations of Ag, Al, Cr, Cu, Fe, Hg, Mn, Ni, Pb, V and Zn were determined in six sediment cores from San Francisco Bay (SFB) and one sediment core in Tomales Bay (TB), a reference estuary. SFB cores were collected from between the head of the estuary and its mouth (Grizzly Bay, GB; San Pablo Bay, SP; Central Bay, CB; Richardson Bay, RB, respectively) and ranged in length from 150 to...
Authors
Michelle I. Hornberger, S. N. Luoma, A. VanGeen, C. Fuller, R. Anima
Constraints on the sedimentation history of San Francisco Bay from 14C and 10Be Constraints on the sedimentation history of San Francisco Bay from 14C and 10Be
Industrialization and urbanization around San Francisco Bay as well as mining and agriculture in the watersheds of the Sacramento and San Joaquin rivers have profoundly modified sedimentation patterns throughout the estuary. We provide some constraints on the onset of these erosional disturbances with 10Be data for three sediment cores: two from Richardson Bay, a small embayment near the...
Authors
A. VanGeen, N. J. Valette-Silver, S. N. Luoma, C. C. Fuller, M. Baskaran, F. Tera, J. Klein
Quantification of aerobic biodegradation and volatilization rates of gasoline hydrocarbons near the water table under natural attenuation conditions Quantification of aerobic biodegradation and volatilization rates of gasoline hydrocarbons near the water table under natural attenuation conditions
Aerobic biodegradation and volatilization near the water table constitute a coupled pathway that contributes significantly to the natural attenuation of hydrocarbons at gasoline spill sites. Rates of hydrocarbon biodegradation and volatilization were quantified by analyzing vapor transport in the unsaturated zone at a gasoline spill site in Beaufort, South Carolina. Aerobic biodgradation...
Authors
Matthew A. Lahvis, Arthur L. Baehr, Ronald J. Baker
Carbon isotopic constraints on the contribution of plant material to the natural precursors of trihalomethanes Carbon isotopic constraints on the contribution of plant material to the natural precursors of trihalomethanes
The δ13C values of individual trihalomethanes (THM) formed on reaction of chlorine with dissolved organic carbon (DOC) leached from maize (corn; Zea maize L.) and Scirpus acutus(an aquatic bulrush), and with DOC extracted from agricultural drainage waters were determined using purge and trap introduction into a gas chromatograph-combustion-isotope ratio monitoring mass spectrometer. We...
Authors
B.A. Bergamaschi, M.S. Fram, C. Kendall, S. R. Silva, G. R. Aiken, R. Fujii