Origin and geochemistry of formation waters from the lower Eagle Ford Group, Gulf Coast Basin, south central Texas

The lower Eagle Ford Group (LEFG) is one of the most productive continuous hydrocarbon plays in the United States but few associated produced waters data and minimal interpretation have been published. This effort focuses on results from compositional and isotopic data from 39 produced water samples collected from horizontal wells producing from the LEFG in south central Texas. The depth of the LEFG increases by approximately 1 km across the study area, from northwest (2.9 km) to southeast (3.9 km). Associated increases in calculated reservoir temperature (125-165 C), development of reservoir over-pressuring (400-800 bars total pressure), and increased thermal maturity (heavy oil to gas condensate) also occur along this trend. Produced water salinity starts at nearly 100 g/L in the shallowest samples and decreases linearly with depth to