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The precipitation of indium at elevated pH in a stream influenced by acid mine drainage

January 17, 2017

Indium is an increasingly important metal in semiconductors and electronics and has uses in important energy technologies such as photovoltaic cells and light-emitting diodes (LEDs). One significant flux of indium to the environment is from lead, zinc, copper, and tin mining and smelting, but little is known about its aqueous behavior after it is mobilized. In this study, we use Mineral Creek, a headwater stream in southwestern Colorado severely affected by heavy metal contamination as a result of acid mine drainage, as a natural laboratory to study the aqueous behavior of indium. At the existing pH of ~ 3, indium concentrations are 6–29 μg/L (10,000 × those found in natural rivers), and are completely filterable through a 0.45 μm filter. During a pH modification experiment, the pH of the system was raised to > 8, and > 99% of the indium became associated with the suspended solid phase (i.e. does not pass through a 0.45 μm filter). To determine the mechanism of removal of indium from the filterable and likely primarily dissolved phase, we conducted laboratory experiments to determine an upper bound for a sorption constant to iron oxides, and used this, along with other published thermodynamic constants, to model the partitioning of indium in Mineral Creek. Modeling results suggest that the removal of indium from the filterable phase is consistent with precipitation of indium hydroxide from a dissolved phase. This work demonstrates that nonferrous mining processes can be a significant source of indium to the environment, and provides critical information about the aqueous behavior of indium.

Publication Year 2017
Title The precipitation of indium at elevated pH in a stream influenced by acid mine drainage
DOI 10.1016/j.scitotenv.2016.08.136
Authors Sarah Jane O. White, Fatima A. Hussain, Harold F. Hemond, Sarah A. Sacco, James P. Shine, Robert L. Runkel, Katherine Walton-Day, Briant A. Kimball
Publication Type Article
Publication Subtype Journal Article
Series Title Science of the Total Environment
Index ID 70179735
Record Source USGS Publications Warehouse
USGS Organization Colorado Water Science Center; Eastern Mineral and Environmental Resources Science Center