As part of water-quality data collection activities in New England, water samples are analyzed for chloride in monitoring networks and projects across Connecticut, Massachusetts, and Rhode Island. Chloride is of interest because high concentrations may affect aquatic life in streams or affect water quality of reservoirs and aquifers used for drinking water.
Chloride concentrations in streams in forested areas in New England tend to be low, as there are limited geological sources of chloride. However, in recent years U.S. Geological Survey studies have documented increasing chloride concentrations and loads in streams in New England (Savoie and others, 2017; Mullaney, 2016). The increases in chloride concentrations and loads can be attributed to the following sources: deicing salts applied to public roads and private property, and discharges from wastewater treatment facilities and on-site septic systems. Less important sources include atmospheric deposition, the use of salts for water softening, and potassium chloride in agricultural fertilizers (Mullaney and others, 2009). Salt for deicing is the largest end use of salt in the United States (Bolen, 2021).
Recent and historical data for active water-quality monitoring stations on streams in Connecticut, Massachusetts and Rhode Island can be viewed at https://newengland.water.usgs.gov/web_app/chloride/Clmap.html.
References
Bolen, W.P., 2021, 2017 minerals yearbook—Salt [Advance Release]: U.S. Geological Survey, accessed on June 24, 2022 at https://d9-wret.s3.us-west-2.amazonaws.com/assets/palladium/production/s3fs-public/atoms/files/myb1-2017-salt.pdf
Mullaney, J.R., 2016, Nutrient, organic carbon, and chloride concentrations and loads in selected Long Island Sound tributaries—Four decades of change following the passage of the Federal Clean Water Act: U.S. Geological Survey Scientific Investigations Report 2015–5189, 47 p., http://dx.doi.org/10.3133/sir20155189.
Mullaney, J.R., Lorenz, D.L., Arntson, A.D., 2009, Chloride in groundwater and surface water in areas underlain by the glacial aquifer system, northern United States: U.S. Geological Survey Scientific Investigations Report 2009–5086, 41 p., https://pubs.usgs.gov/sir/2009/5086.
Savoie, J.G., Mullaney, J.R., and Bent, G.C., 2017, Analysis of trends of water quality and streamflow in the Blackstone, Branch, Pawtuxet, and Pawcatuck Rivers, Massachusetts, and Rhode Island, 1979 to 2015: U.S. Geological Survey Scientific Investigations Report 2016–5178, 43 p., https://doi.org/10.3133/sir20165178.
Water quality in the Cambridge, Massachusetts, drinking-water source area, 2005-8
Concentration, flux, and the analysis of trends of total and dissolved phosphorus, total nitrogen, and chloride in 18 tributaries to Lake Champlain, Vermont and New York, 1990–2011
Concentrations of chloride and sodium in groundwater in New Hampshire from 1960 through 2011
Quality of water from crystalline rock aquifers in New England, New Jersey, and New York, 1995-2007
Characterization of major-ion chemistry and nutrients in headwater streams along the Appalachian National Scenic Trail and within adjacent watersheds, Maine to Georgia
Surface-water, water-quality, and meteorological data for the Cambridge, Massachusetts, drinking-water source area, water years 2007-08
Effects of Highway Road Salting on the Water Quality of Selected Streams in Chittenden County, Vermont, November 2005-2007
Chloride in Groundwater and Surface Water in Areas Underlain by the Glacial Aquifer System, Northern United States
Estimating Concentrations of Road-Salt Constituents in Highway-Runoff from Measurements of Specific Conductance
- Overview
As part of water-quality data collection activities in New England, water samples are analyzed for chloride in monitoring networks and projects across Connecticut, Massachusetts, and Rhode Island. Chloride is of interest because high concentrations may affect aquatic life in streams or affect water quality of reservoirs and aquifers used for drinking water.
Winter water-quality sample collection at USGS gage 01188000, Bunnell Brook near Burlington, Connecticut. Chloride concentrations in streams in forested areas in New England tend to be low, as there are limited geological sources of chloride. However, in recent years U.S. Geological Survey studies have documented increasing chloride concentrations and loads in streams in New England (Savoie and others, 2017; Mullaney, 2016). The increases in chloride concentrations and loads can be attributed to the following sources: deicing salts applied to public roads and private property, and discharges from wastewater treatment facilities and on-site septic systems. Less important sources include atmospheric deposition, the use of salts for water softening, and potassium chloride in agricultural fertilizers (Mullaney and others, 2009). Salt for deicing is the largest end use of salt in the United States (Bolen, 2021).
Recent and historical data for active water-quality monitoring stations on streams in Connecticut, Massachusetts and Rhode Island can be viewed at https://newengland.water.usgs.gov/web_app/chloride/Clmap.html.
References
Bolen, W.P., 2021, 2017 minerals yearbook—Salt [Advance Release]: U.S. Geological Survey, accessed on June 24, 2022 at https://d9-wret.s3.us-west-2.amazonaws.com/assets/palladium/production/s3fs-public/atoms/files/myb1-2017-salt.pdf
Mullaney, J.R., 2016, Nutrient, organic carbon, and chloride concentrations and loads in selected Long Island Sound tributaries—Four decades of change following the passage of the Federal Clean Water Act: U.S. Geological Survey Scientific Investigations Report 2015–5189, 47 p., http://dx.doi.org/10.3133/sir20155189.
Mullaney, J.R., Lorenz, D.L., Arntson, A.D., 2009, Chloride in groundwater and surface water in areas underlain by the glacial aquifer system, northern United States: U.S. Geological Survey Scientific Investigations Report 2009–5086, 41 p., https://pubs.usgs.gov/sir/2009/5086.
Savoie, J.G., Mullaney, J.R., and Bent, G.C., 2017, Analysis of trends of water quality and streamflow in the Blackstone, Branch, Pawtuxet, and Pawcatuck Rivers, Massachusetts, and Rhode Island, 1979 to 2015: U.S. Geological Survey Scientific Investigations Report 2016–5178, 43 p., https://doi.org/10.3133/sir20165178.
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Water quality in the Cambridge, Massachusetts, drinking-water source area, 2005-8
During 2005-8, the U.S. Geological Survey, in cooperation with the Cambridge, Massachusetts, Water Department, measured concentrations of sodium and chloride, plant nutrients, commonly used pesticides, and caffeine in base-flow and stormwater samples collected from 11 tributaries in the Cambridge drinking-water source area. These data were used to characterize current water-quality conditions, toConcentration, flux, and the analysis of trends of total and dissolved phosphorus, total nitrogen, and chloride in 18 tributaries to Lake Champlain, Vermont and New York, 1990–2011
Annual concentration, flux, and yield for total phosphorus, dissolved phosphorus, total nitrogen, and chloride for 18 tributaries to Lake Champlain were estimated for 1990 through 2011 using a weighted regression method based on time, tributary streamflows (discharges), and seasonal factors. The weighted regression method generated two series of daily estimates of flux and concentration during theConcentrations of chloride and sodium in groundwater in New Hampshire from 1960 through 2011
Several studies from the 1970s and more recently (for example, Hall (1975), Daley and others (2009) and Mullaney (2009)) have found that concentrations of chloride and sodium in groundwater in New Hampshire have increased during the past 50 years. Increases likely are related to road salt and other anthropogenic sources, such as septic systems, wastewater, and contamination from landfills and saltQuality of water from crystalline rock aquifers in New England, New Jersey, and New York, 1995-2007
Crystalline bedrock aquifers in New England and parts of New Jersey and New York (NECR aquifers) are a major source of drinking water. Because the quality of water in these aquifers is highly variable, the U.S. Geological Survey (USGS) statistically analyzed chemical data on samples of untreated groundwater collected from 117 domestic bedrock wells in New England, New York, and New Jersey, and froCharacterization of major-ion chemistry and nutrients in headwater streams along the Appalachian National Scenic Trail and within adjacent watersheds, Maine to Georgia
An inventory of water-quality data on field parameters, major ions, and nutrients provided a summary of water quality in headwater (first- and second-order) streams within watersheds along the Appalachian National Scenic Trail (Appalachian Trail). Data from 1,817 sampling sites in 831 catchments were used for the water-quality summary. Catchment delineations from NHDPlus were used as the fundamentSurface-water, water-quality, and meteorological data for the Cambridge, Massachusetts, drinking-water source area, water years 2007-08
Records of water quantity, water quality, and meteorological parameters were continuously collected from three reservoirs, two primary streams, and five subbasin tributaries in the Cambridge, Massachusetts, drinking-water source area during water years 2007-08 (October 2006 through September 2008). Water samples were collected during base-flow conditions and storms in the Cambridge Reservoir and SEffects of Highway Road Salting on the Water Quality of Selected Streams in Chittenden County, Vermont, November 2005-2007
A study of road-deicing chloride (Cl) concentrations and loads was conducted at three streams in Chittenden County, VT, from November 2005 to 2007. This study was done by the U.S. Geological Survey, in cooperation with the Vermont Agency of Transportation. The streams, Alder Brook, Allen Brook, and Mill Brook, were selected to represent different land uses in the upstream watershed, different roadChloride in Groundwater and Surface Water in Areas Underlain by the Glacial Aquifer System, Northern United States
A study of chloride in groundwater and surface water was conducted for the glacial aquifer system of the northern United States in forested, agricultural, and urban areas by analyzing data collected for the National Water-Quality Assessment Program from 1991 to 2004. Groundwater-quality data from a sampling of 1,329 wells in 19 states were analyzed. Chloride concentrations were greater than theEstimating Concentrations of Road-Salt Constituents in Highway-Runoff from Measurements of Specific Conductance
Discrete or composite samples of highway runoff may not adequately represent in-storm water-quality fluctuations because continuous records of water stage, specific conductance, pH, and temperature of the runoff indicate that these properties fluctuate substantially during a storm. Continuous records of water-quality properties can be used to maximize the information obtained about the stormwater - Web Tools