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Procedures for using the Horiba Scientific Aqualog® fluorometer to measure absorbance and fluorescence from dissolved organic matter

Advances in spectroscopic techniques have led to an increase in the use of optical measurements (absorbance and fluorescence) to assess dissolved organic matter composition and infer sources and processing. Although optical measurements are easy to make, they can be affected by many variables rendering them less comparable, including by inconsistencies in sample collection (for example, filter por
Angela M. Hansen, Jacob Fleck, Tamara E. C. Kraus, Bryan D. Downing, Travis von Dessonneck, Brian A. Bergamaschi

Wetlands receiving water treated with coagulants improve water quality by removing dissolved organic carbon and disinfection byproduct precursors

Constructed wetlands are used worldwide to improve water quality while also providing critical wetland habitat. However, wetlands have the potential to negatively impact drinking water quality by exporting dissolved organic carbon (DOC) that upon disinfection can form disinfection byproducts (DBPs) like trihalomethanes (THMs) and haloacetic acids (HAAs). We used a replicated field-scale study loca
Angela M. Hansen, Tamara E. C. Kraus, Sandra M. Bachand, William R. Horwath, Philip A.M. Bachand

Optical properties of dissolved organic matter (DOM): Effects of biological and photolytic degradation

Advances in spectroscopic techniques have led to an increase in the use of optical properties (absorbance and fluorescence) to assess dissolved organic matter (DOM) composition and infer sources and processing. However, little information is available to assess the impact of biological and photolytic processing on the optical properties of original DOM source materials. We measured changes in comm
Angela Hansen, Tamara E. C. Kraus, Brian Pellerin, Jacob Fleck, Bryan D. Downing, Brian A. Bergamaschi

High-resolution remote sensing of water quality in the San Francisco Bay-Delta Estuary

The San Francisco Bay–Delta Estuary watershed is a major source of freshwater for California and a profoundly human-impacted environment. The water quality monitoring that is critical to the management of this important water resource and ecosystem relies primarily on a system of fixed water-quality monitoring stations, but the limited spatial coverage often hinders understanding. Here, we show ho
Cédric G. Fichot, Bryan D. Downing, Brian A. Bergamaschi, Lisamarie Windham-Myers, Mark C. Marvin-DiPasquale, David R. Thompson, Michelle M. Gierach

Mercury, monomethyl mercury, and dissolved organic carbon concentrations in surface water entering and exiting constructed wetlands treated with metal-based coagulants, Twitchell Island, California

Coagulation with metal-based salts is a practice commonly employed by drinking-water utilities to decrease particle and dissolved organic carbon concentrations in water. In addition to decreasing dissolved organic carbon concentrations, the effectiveness of iron- and aluminum-based coagulants for decreasing dissolved concentrations both of inorganic and monomethyl mercury in water was demonstrated
Elizabeth B. Stumpner, Tamara E.C. Kraus, Jacob A. Fleck, Angela M. Hansen, Sandra M. Bachand, William R. Horwath, John F. DeWild, David P. Krabbenhoft, Philip A.M. Bachand

Concurrent photolytic degradation of aqueous methylmercury and dissolved organic matter

Monomethyl mercury (MeHg) is a potent neurotoxin that threatens ecosystem viability and human health. In aquatic systems, the photolytic degradation of MeHg (photodemethylation) is an important component of the MeHg cycle. Dissolved organic matter (DOM) is also affected by exposure to solar radiation (light exposure) leading to changes in DOM composition that can affect its role in overall mercury
Jacob A. Fleck, Gary W. Gill, Brian A. Bergamaschi, Tamara E.C. Kraus, Bryan D. Downing, Charles N. Alpers

Mercury cycling in agricultural and managed wetlands, Yolo Bypass, California: Spatial and seasonal variations in water quality

The seasonal and spatial variability of water quality, including mercury species, was evaluated in agricultural and managed, non-agricultural wetlands in the Yolo Bypass Wildlife Area, an area managed for multiple beneficial uses including bird habitat and rice farming. The study was conducted during an 11-month period (June 2007 to April 2008) that included a summer growing season and flooded con
Charles N. Alpers, Jacob A. Fleck, Mark C. Marvin-DiPasquale, Craig A. Stricker, Mark Stephenson, Howard E. Taylor

Mercury cycling in agricultural and managed wetlands: a synthesis of methylmercury production, hydrologic export, and bioaccumulation from an integrated field study

With seasonal wetting and drying, and high biological productivity, agricultural wetlands (rice paddies) may enhance the conversion of inorganic mercury (Hg(II)) to methylmercury (MeHg), the more toxic, organic form that biomagnifies through food webs. Yet, the net balance of MeHg sources and sinks in seasonal wetland environments is poorly understood because it requires an annual, integrated asse
Lisamarie Windham-Myers, Jacob A. Fleck, Joshua T. Ackerman, Mark C. Marvin-DiPasquale, Craig A. Stricker, Wesley A. Heim, Philip A.M. Bachand, Collin A. Eagles-Smith, Gary Gill, Mark Stephenson, Charles N. Alpers

Methylmercury production in and export from agricultural wetlands in California, USA: the need to account for physical transport processes into and out of the root zone

Concentration and mass balance analyses were used to quantify methylmercury (MeHg) loads from conventional (white) rice, wild rice, and fallowed fields in northern California's Yolo Bypass. These analyses were standardized against chloride to distinguish transport pathways and net ecosystem production (NEP). During summer, chloride loads were both exported with surface water and moved into the roo
Philip A.M. Bachand, Sandra M. Bachand, Jacob A. Fleck, Charles N. Alpers, Mark Stephenson, Lisamarie Windham-Myers

Mercury dynamics in a San Francisco estuary tidal wetland: assessing dynamics using in situ measurements

We used high-resolution in situ measurements of turbidity and fluorescent dissolved organic matter (FDOM) to quantitatively estimate the tidally driven exchange of mercury (Hg) between the waters of the San Francisco estuary and Browns Island, a tidal wetland. Turbidity and FDOM—representative of particle-associated and filter-passing Hg, respectively—together predicted 94 % of the observed variab
Brian A. Bergamaschi, Jacob A. Fleck, Bryan D. Downing, Emmanuel Boss, Brian A. Pellerin, Neil K. Ganju, David H. Schoellhamer, Amy A. Byington, Wesley A. Heim, Mark Stephenson, Roger Fujii

Seeing the light: the effects of particles, dissolved materials, and temperature on in situ measurements of DOM fluorescence in rivers and streams

Field-deployable sensors designed to continuously measure the fluorescence of colored dissolved organic matter (FDOM) in situ are of growing interest. However, the ability to make FDOM measurements that are comparable across sites and over time requires a clear understanding of how instrument characteristics and environmental conditions affect the measurements. In particular, the effects of water
Bryan D. Downing, Brian A. Pellerin, Brian A. Bergamaschi, John Franco Saraceno, Tamara E.C. Kraus

Methyl mercury dynamics in a tidal wetland quantified using in situ optical measurements

We assessed monomethylmercury (MeHg) dynamics in a tidal wetland over three seasons using a novel method that employs a combination of in situ optical measurements as concentration proxies. MeHg concentrations measured over a single spring tide were extended to a concentration time series using in situ optical measurements. Tidal fluxes were calculated using modeled concentrations and bi-direction
B.A. Bergamaschi, J.A. Fleck, B.D. Downing, E. Boss, B. Pellerin, N. K. Ganju, D. H. Schoellhamer, A.A. Byington, W.A. Heim, M. Stephenson, R. Fujii